Diel variation of selenium and arsenic in a wetland of the Great Salt Lake, Utah

Diel (24-h) changes in Se and As concentrations in a freshwater wetland pond bordering the Great Salt Lake (GSL) were examined. Selenium concentrations (filtered and unfiltered) changed on a diel basis, i.e., were depleted during early morning and enriched during daytime over August 17-18. During the May 24-25, 2006 and September 29-30 diel studies, no significant 24-h trends were observed in Se concentrations compared to August, which showed daily maximums up to 59% greater than the daily minimum. Both filtered and unfiltered As concentrations also varied on a diel cycle, with increased concentrations during early morning and decreased concentrations during daytime. Filtered As concentrations increased 110% during the May 24-25, 2006 diel study. Selenium varied in phase with pH, dissolved O₂ (DO), and water temperature (T_w) whereas As varied opposite to Se, pH, DO and T_w. Changes in pH, DO and T_w showed a direct linear correlation (r = 0.74, 0.75, and 0.55, respectively) to filtered Se. Also pH, DO and T_w were inversely correlated to filtered As concentration (r = −0.88, −0.87, and −0.84, respectively). Equilibrium geochemical speciation and sorption models were used to examine the potential oxidation state changes in Se and As, and sorption and desorption reactions corresponding to the observed 24-h variations in pe and pH. In this wetland it was postulated that diel Se variation was driven by sorption and desorption due to photosynthesis-induced changes in pH and redox conditions. Diel variations of As were hypothesized to be linked to pH-driven sorption and desorption as well as co-precipitation and co-dissolution with mineral phases of Mn.     

A 50-year record of NO<Subscript>x</Subscript> and SO<Subscript>2</Subscript> sources in precipitation in the Northern Rocky Mountains,USA

Ice-core samples from Upper Fremont Glacier (UFG), Wyoming, were used as proxy records for the chemical composition of atmospheric deposition. Results of analysis of the ice-core samples for stable isotopes of nitrogen (δ¹⁵N, ) and sulfur (δ³⁴S, ), as well as and deposition rates from the late-1940s thru the early-1990s, were used to enhance and extend existing National Atmospheric Deposition Program/National Trends Network (NADP/NTN) data in western Wyoming. The most enriched δ³⁴S value in the UFG ice-core samples coincided with snow deposited during the 1980 eruption of Mt. St. Helens, Washington. The remaining δ³⁴S values were similar to the isotopic composition of coal from southern Wyoming. The δ¹⁵N values in ice-core samples representing a similar period of snow deposition were negative, ranging from -5.9 to -3.2 ‰ and all fall within the δ¹⁵N values expected from vehicle emissions. Ice-core nitrate and sulfate deposition data reflect the sharply increasing U.S. emissions data from 1950 to the mid-1970s.     

Woodland expansion’s influence on belowground carbon and nitrogen in the Great Basin U.S.

Vegetation changes associated with climate shifts and anthropogenic disturbance can have major impacts on biogeochemical cycling and soils. Much of the Great Basin, U.S. is currently dominated by sagebrush (Artemisia tridentate (Rydb.) Boivin) ecosystems. Sagebrush ecosystems are increasingly influenced by pinyon (Pinus monophylla Torr. & Frém and Pinus edulis Engelm.) and juniper (Juniperus osteosperma Torr. and Juniperus occidentalis Hook.) expansion. Some scientists and policy makers believe that increasing woodland cover in the intermountain western U.S. offers the possibility of increased organic carbon (OC) storage on the landscape; however, little is currently known about the distribution of OC on these landscapes, or the role that nitrogen (N) plays in OC retention. We quantified the relationship between tree cover, belowground OC, and total below ground N in expansion woodlands at 13 sites in Utah, Oregon, Idaho, California, and Nevada, USA. One hundred and twenty nine soil cores were taken using a mechanically driven diamond tipped core drill to a depth of 90 cm. Soil, coarse fragments, and coarse roots were analyzed for OC and total N. Woodland expansion influenced the vertical distribution of root OC by increasing 15-30 cm root OC by 2.6 Mg ha⁻¹ and root N by 0.04 Mg ha⁻¹. Root OC and N increased through the entire profile by 3.8 and 0.06 Mg ha⁻¹ respectively. Woodland expansion influenced the vertical distribution of soil OC by increasing surface soil (0-15 cm) OC by 2.2 Mg ha⁻¹. Woodland expansion also caused a 1.3 Mg ha⁻¹ decrease in coarse fragment associated OC from 75-90 cm. Our data suggests that woodland expansion into sagebrush ecosystems has limited potential to store additional belowground OC, and must be weighed against the risk of increased wildfire and exotic grass invasion.     

Distinguishing lower and upper crustal processes in magmas erupted during the buildup to the 7.7 ka climactic eruption of Mount Mazama, Crater Lake, Oregon, using 238U–230Th disequilibria

Uranium-series isotope ratios determined for 35 volcanic rocks and 4 glass separates erupted from ~36 to 4.8 ka at Mt. Mazama, Crater Lake, Oregon, identify both ²³⁰Th-excess and ²³⁸U-excess components. U–Th isotope compositions cover a wide range, exceeding those previously measured for the Cascade arc. Age-corrected (²³⁰Th/²³²Th) and (²³⁸U/²³²Th) activity ratios range from 1.113 to 1.464 and from 0.878 to 1.572 (44.4 % ²³⁰Th-excess to 8.8 % ²³⁸U-excess), respectively. The most distinctive aspect of the data set is the contrast in U–Th isotope ratios between low and high Sr (LSr, HSr) components that have been previously identified in products of the 7.7 ka caldera-forming climactic eruption and preclimactic rhyodacite lavas. The LSr component exclusively contains ²³⁸U-excess, but the HSr component, as well as more primitive lavas, are marked by ²³⁰Th-excess. ²³⁰Th-excesses such as those recorded at Mt. Mazama are commonly observed in the Cascades. Melting models suggest that high ²³⁰Th-excesses observed in the more primitive lavas evolved through mixing of a mantle melt with a partial melt of a mafic lower crustal composition that contained garnet in the residuum that was produced through dehydration melting of amphibolite that was initially garnet free. Dehydration melting in the lower crust offers a solution to the “hot-slab paradox” of the Cascades, where low volatile contents are predicted due to high slab temperatures, yet higher water contents than expected have been documented in erupted lavas. The ²³⁸U-excess observed at Mt. Mazama is rare in Cascade lavas, but occurs in more than half of the samples analyzed in this study. Traditionally, ²³⁸U-excess in arc magmas is interpreted to reflect slab fluid fluxing. Indeed, ²³⁸U-excess in arcs is common and likely masks ²³⁰Th-excess resulting from lower crustal interaction. Isotopic and trace element data, however, suggest a relatively minor role for slab fluid fluxing in the Cascades. We propose that ²³⁸U-excess reflects melting and assimilation of young, hydrothermally altered upper crust. The processes related to generating ²³⁸U-excess are likely important features at Mt. Mazama that accompanied development of a large-scale silicic magma chamber that led to the caldera-forming eruption.     

The Ledsjö end moraine—a subaquatic push moraine composed of glaciomarine clay in central Sweden

During the Younger Dryas cold event, the Scandinavian ice sheet readvanced in southwest Sweden and formed the Middle Swedish end-moraine zone (MSEMZ). Recent highway construction near Skara has created an exposure through the prominent ridge at Ledsjö. Through sketching and measurement of structural information, we have documented the internal character of the Ledsjö moraine. The moraine consists predominantly of clay with numerous sand pods and lenses, which show undeformed, brittle deformed, or fluidized structures. Based on geomorphology and structural geology, it is clear the moraine was made during two advances. As ice advanced, proglacial marine clay was subglacially mobilized by the ice and extruded at the ice margin forming a ramp of debris-flow sediment. Contemporaneously, subglacial meltwater transported sand to the margin, where the meltwater became a buoyant plume, and sand was deposited near the ice margin by currents moving away from as well as toward the ice margin. These processes resulted in interbedded sand and clay. Continued advance of the ice margin deformed this package and further pushed the assemblage into a ridge form with gravity sliding of portions of the ridge. Prior to the second advance, sand was deposited on the proximal side of the initial ridge. During readvance, this sand was thrust faulted and intruded by mobilized clay. Up ice of the intruded sands, subglacial, extensional deformation created a complex shear zone of faulted sand and clay. The Ledsjö moraine represents a subaerial example of submarine push moraines like the submerged moraines recently documented in Svalbard.     

Neighborhood covenants and restrictions: an examination of fit

Covenants and restrictions (C&Rs) have increased in popularity in recent decades, being commonly applied in new residential developments. Despite the fact that developers are more commonly writing C&Rs for their developments, little research has investigated how well C&Rs actually fit the preferences of residents. Recognizing this gap in the literature, this paper examines the fit of neighborhood C&Rs with resident preferences in Porter County, Indiana, a growing suburban/exurban place in the Chicago Metropolitan Statistical Area. The researcher conducted in-depth interviews with 51 residents to ascertain how well C&Rs fit resident preferences. The majority of interviewees stated that C&Rs match resident preferences because they believed that C&Rs promoted subdivision tidiness and worked to support property values. The minority view was that C&Rs do not fit because they are too strict and residents do not obey C&Rs. Interviewees who perceived a fit were more likely to have a lower level of engagement with C&Rs and were more likely to live in developments with no C&R enforcement attempts by the homeowners’ association (HOA). The results suggest the particular content of C&Rs does not seem to fit resident preference; rather the fact that C&Rs are not enforced fits resident preference. Seemingly, residents are content being unaware of the C&Rs, then they do not know if someone is breaking the rules or not. This may imply that residents would not want to have C&Rs in the first place.     

The bedrock topography of the botany basin,New South Wales

The bedrock topography of the Botany Basin has been determined from seismic‐sparker records made in Botany Bay and Bate Bay, and from seismic‐refraction and gravity measurements on the Kurnell Peninsula. Supplementary information has been obtained from boreholes both on land and in the sea.

The Cooks and Georges Rivers formerly constituted the main drainage of the Basin and flowed generally southeastwards (beneath the present Kurnell Peninsula) and joined the Port Hacking River east of Cronulla. The depth of the bedrock channel of the former Georges River is 75–80 m b.s.l. at Taren Point, 90–95 m beneath the Kurnell Peninsula and 110–115 m at its junction with the Port Hacking River channel. The bedrock channel of the former Cooks River is about 30 m b.s.l. at Kyeemagh, its present entrance to Botany Bay, and it joined the Georges River at a location now 90 m b.s.l. beneath the Kurnell Peninsula.

A second drainage system existed in the north and east of Botany Bay and generated the present mouth beneath which the bedrock is now 110 m b.s.l. This channel followed a southeasterly course parallel to the present northern shore of Botany Bay and was separated from that of the ‘Cooks and Georges Rivers’ by a bedrock ridge which extended from beneath Sydney Airport to the northern extremity of the Kurnell Peninsula. Over much of its length this divide had a depth of about 30 m b.s.l.

The formation of the Kurnell Peninsula tombolo led to the diversion of the ‘Cooks/Georges River’ through the mouth of Botany Bay and subsequently led to the development of the bay. This change in the drainage system occurred when the sea was less than 30 m below the present sea level.     

Tracing and using data lineage for pipeline processing in Astro-WISE

Most workflow systems that support data provenance primarily focus on tracing lineage of data. Data provenance by data lineage provides the derivation history of data including information about services and input data that contributed to the creation of a data product. We show that tracing lineage by means of full backward chaining not only enables users to share, discover and reuse the data, but also supports scientific data processing through storage, retrieval and (re)processing of digitized scientific data. In this paper, we present Astro-WISE, a distributed system for processing, analyzing and disseminating wide field imaging astronomical data. We show how Astro-WISE traces lineage of data and how it facilitates data processing, retrieval, storage and archiving. Particularly we show how it solves issues related to the changing data items typical for the scientific environment, such as physical changes in calibrations, our insight in these changes and improved methods for deriving results.     

Large-scale cold water dispersant effectiveness experiments with Alaskan crude oils and Corexit 9500 and 9527 dispersants

There continues to be reluctance in some jurisdictions to use chemical dispersants as a viable countermeasure for accidental oil spills. One argument used by some opponents to dispersant use is that “chemical dispersants do not work effectively in cold water”. To address this issue, the U.S. Minerals Management Service (MMS) funded and conducted two series of large-scale dispersant experiments in very cold water at Ohmsett - The National Oil Spill Response Test Facility, located in Leonardo, New Jersey in February-March 2006 and January-March 2007. Alaska North Slope, Endicott, Northstar and Pt. McIntyre crude oils and Corexit 9500 and Corexit 9527 dispersants were used in the two test series. The crude oils were tested both when fresh and after weathering. Results demonstrated that both Corexit 9500 and Corexit 9527 dispersants were 85-99% effective in dispersing the fresh and weathered crude oils tested at cold temperatures. The MMS expects that results from these test series will assist government regulators and responders in making science based decisions on the use of dispersants as a response tool for oil spills in the Arctic.