Small-scale, high-precision and high-accuracy determination of Poisson’s ratios in cohesive marine sediments

Poisson’s ratio (static) appears as a parameter in models of soft-sediment geomechanical processes such as gas bubble formation and bioturbation, and in a number of practical applications, including acoustic imaging, but is rarely measured in soft near-surface (upper 20 cm) marine sediments. A new uniaxial apparatus was developed to assess Poisson’s ratios of cylindrical samples of soft cohesive sediments under finite-strain, unconfined, undrained conditions. No constraining membrane around the sample is necessary in the instrument. By monitoring the fluid level in a capillary, changes in sample volume can be determined to high precision (reproducibility). Measurements on reference materials, i.e., gelatine and polyurethane, also indicate high accuracy (veracity). For natural sediments from Nova Scotia, Canada, Poisson’s ratios range from 0.4951 to 0.5 with no indication of anisotropy; therefore, such sediments act as incompressible solids to short-term/small-magnitude stresses, as occur during bubble formation and infaunal movement.     

Hydrothermal Metalliferous Sediments and Waters Off the Lesser Antilles

Abstract

Considerable metal enrichments have been found in hydrothermal fluids and metalliferous sediments off the central Lesser Antilles Volcanic Arc. The elements variably enriched in the fluids as a result of the hydrothermal activity are Fe, Mn, As, Si, B, Li and in the sediments, Fe, P, Mo, As, Sb, Hg, Cu and Pb. Variations in the concentrations of these elements in both fluids and sediments along the arc result from a number of factors, the most important of which is the stage that each island's volcano has reached in its eruptive cycle. Although hydrothermal mineralization on the sea floor off the islands is only low grade, phase separation in the hydrothermal fluids at depth could be leading to higher grade stockwork mineralization below the vent fields or the discharge of metal rich brines on the lower flanks of the volcanic islands.     

Binary Mixtures of Permanganate and Chlorinated Volatile Organic Compounds in Groundwater Samples: Sample Preservation and Analysis

Groundwater samples collected at sites where in situ chemical oxidation (ISCO) has been deployed may contain binary mixtures of groundwater contaminants and permanganate (MnO₄^–), an oxidant injected into the subsurface to destroy the contaminant. Commingling of the oxidant and contaminant in aqueous samples may negatively impact the quality of the sample as well as the analytical instruments used to quantify contaminant concentrations. In this study, binary mixtures comprised of (1) a multicomponent standard with permanganate and (2) groundwater samples collected at two ISCO field sites were preserved with ascorbic acid. Ascorbic acid reacts rapidly with the MnO₄^– and limits the reaction between MnO₄^– and the organic compounds in the mixture. Consequently, most of the compounds in the multicomponent standard were within the control limit for quality assurance. However, despite timely efforts to preserve the samples, the rapid reaction between permanganate and contaminant caused the concentration of several sensitive compounds to fall significantly below the lower control limit. Concentrations of volatile organic compounds in the field‐preserved binary mixture groundwater samples were greater than in samples refrigerated in the field and preserved upon arrival at the laboratory, indicating the time‐dependency and benefit of field preservation. The molar ratio of ascorbic acid required to neutralize KMnO₄ was 1.64 (mol ascorbic acid/mol KMnO₄); this provided a baseline to estimate the volume of ascorbic acid stock solution and/or the weight of crystalline ascorbic acid required to neutralize MnO₄^–. Excess ascorbic acid did not negatively impact the quality of the aqueous samples, or analytical instruments, used in the analyses.     

In situ tensile fracture toughness of surficial cohesive marine sediments

This study reports the first in situ measurements of tensile fracture toughness, K _IC, of soft, surficial, cohesive marine sediments. A newly developed probe continuously measures the stress required to cause tensile failure in sediments to depths of up to 1 m. Probe measurements are in agreement with standard laboratory methods of K _IC measurements in both potter’s clay and natural sediments. The data comprise in situ depth profiles from three field sites in Nova Scotia, Canada. Measured K _IC at two muddy sites (median grain size of 23–50 μm) range from near zero at the sediment surface to >1,800 Pa m^1/2 at 0.2 m depth. These profiles also appear to identify the bioturbated/mixed depth. K _IC for a sandy site (>90% sand) is an order of magnitude lower than for the muddy sediments, and reflects the lack of cohesion/adhesion. A comparison of K _IC, median grain size, and porosity in muddy sediments indicates that consolidation increases fracture strength, whereas inclusion of sand causes weakening; thus, sand-bearing layers can be easily identified in K _IC profiles. K _IC and vane-measured shear strength correlate strongly, which suggests that the vane measurements should perhaps be interpreted as shear fracture toughness, rather than shear strength. Comparison of in situ probe-measured values with K _IC of soils and gelatin shows that sediments have a K _IC range intermediate between denser compacted soils and softer, elastic gelatin.     

Cost Shifting in Australian Local Government: an analysis of the spatial impact of pensioner rate concession rebates in New South Wales,Australia

The problem of cost shifting from higher tiers of government to local councils in Australia is widely recognised and has been investigated by several official inquiries. However, it has thus far been difficult to gather reliable estimates of the magnitude of the problem. Quite apart from the taxing definitional and data problems associated with the phenomenon, these difficulties have been compounded by the fact that very few attempts have been made to measure the impact of specific instances of cost shifting in Australian local government, especially its spatial impact. In an attempt to remedy this neglect, this paper seeks to measure the spatial effects of pensioner rate concession rebates on local councils in New South Wales.     

Biofilm Detection in a Model Well‐Bore Environment Using Low‐Field NMR

This research addresses the challenges of the lack of non‐invasive methods and poor spatiotemporal resolution associated with monitoring biogeochemical activity central to bioremediation of subsurface contaminants. Remediation efforts often include growth of biofilm to contain or degrade chemical contaminants, such as nitrates, hydrocarbons, heavy metals, and some chlorinated solvents. Previous research indicates that nuclear magnetic resonance (NMR) is sensitive to the biogeochemical processes of biofilm accumulation. The current research focuses on developing methods to use low‐cost NMR technology to support in situ monitoring of biofilm growth and geochemical remediation processes in the subsurface. Biofilm was grown in a lab‐scale radial flow bioreactor designed to model the near wellbore subsurface environment. The Vista Clara Javelin NMR logging device, a slim down‐the‐borehole probe, collected NMR measurements over the course of eight days while biofilm was cultivated in the sand‐packed reactor. Measured NMR mean log T₂ relaxation times decreased from approximately 710 to 389 ms, indicating that the pore environment and bulk fluid properties were changing due to biofilm growth. Destructive sampling employing drop plate microbial population analysis and scanning electron and stereoscopic microscopy confirmed biofilm formation. Our findings demonstrate that the NMR logging tool can detect small to moderate changes in T₂ distribution associated with environmentally relevant quantities of biofilm in quartz sand.     

Coupled ‘storm‐flood’ depositional model: Application to the Miocene–Modern Baram Delta Province,north‐west Borneo

The Miocene to Modern Baram Delta Province is a highly efficient source to sink system that has accumulated 9 to 12 km of coastal–deltaic to shelf sediments over the past 15 Myr. Facies analysis based on ca 1 km of total vertical outcrop stratigraphy, combined with subsurface geology and sedimentary processes in the present‐day Baram Delta Province, suggests a ‘storm‐flood’ depositional model comprising two distinct periods: (i) fair‐weather periods are dominated by alongshore sediment reworking and coastal sand accumulation; and (ii) monsoon‐driven storm periods are characterized by increased wave‐energy and offshore‐directed downwelling storm flow that occur simultaneously with peak fluvial discharge caused by storm precipitation (‘storm‐floods’). The modern equivalent environment has the following characteristics: (i) humid‐tropical monsoonal climate; (ii) narrow (ca <100 km) and steep (ca 1°), densely vegetated, coastal plain; (iii) deep tropical weathering of a mudstone‐dominated hinterland; (iv) multiple independent, small to moderate‐sized (10² to 10⁵ km²) drainage basins; (v) predominance of river‐mouth bypassing; and (vi) supply‐dominated shelf. The ancient, proximal part of this system (the onshore Belait Formation) is dominated by strongly cyclical sandier‐upward successions (metre to decametre‐scale) comprising (from bottom to top): (i) finely laminated mudstone with millimetre‐scale silty laminae; (ii) heterolithic sandstone–mudstone alternations (centimetre to metre‐scale); and (iii) sharp‐based, swaley cross‐stratified sandstone beds and bedsets (metre to decimetre‐scale). Gutter casts (decimetre to metre‐scale) are widespread, they are filled with swaley cross‐stratified sandstone and their long axes are oriented perpendicular to the palaeo‐shoreline. The gutter casts and other associated waning‐flow event beds suggest that erosion and deposition was controlled by high‐energy, offshore‐directed, oscillatory‐dominated, sediment‐laden combined flows within a shoreface to delta front setting. The presence of multiple river mouths and exceptionally high rates of accommodation creation (characteristic of the Neogene to Recent Baram Delta Province; up to 3000 m Ma⁻¹), in a ‘storm‐flood’‐dominated environment, resulted in a highly efficient and effective offshore‐directed sediment transport system.