Abrupt Climatic Changes during the Last Glaciation Based on Pollen Analysis of the Abric Romani, Catalonia, Spain

The Abric Romani continental pollen record provides evidence of abrupt climate variations during the last glaciation. The pollen record reveals a pattern of high-frequency variations similar to that in ice cores as shown by oxygen isotopes or dust content. Analyses of 14 travertine samples yield coherent U-series ages in correct stratigraphic order, ranging from 40,000 to 70,000 yr. According to changes in the composition and structure of the vegetation, five paleoclimatic phases have been differentiated; the oldest, ranging from 70,200 to 65,500 yr ago, records thermophilous taxa which correspond to the last warm events of isotopic stage 5. The next phase, from 65,500 to 56,800 yr, records a cold, humid climate that correlates with isotope stage 4. During the third phase, from 56,800 to 49,500 yr, relatively warm and cold events alternate. The fourth phase, from 49,500 to 46,200 yr, records a cold, dry climate. The fifth phase, ranging from 46,200 to 40,800 yr, records a milder phase that is similar in appearance to the beginning of the Holocene.     

Sources of Phanerozoic granitoids in the transect Bayanhongor–Ulaan Baatar, Mongolia: geochemical and Nd isotopic evidence, and implications for Phanerozoic crustal growth

The Central Asian Orogenic Belt (CAOB) is renowned for massive generation of juvenile crust in the Phanerozoic. Mongolia is the heartland of the CAOB and it has been subject to numerous investigations, particularly in metallogenesis and tectonic evolution. We present new petrographic, geochemical and Sr–Nd isotopic analyses on Phanerozoic granitoids emplaced in west-central Mongolia. The data are used to delineate their source characteristics and to discuss implications for the Phanerozoic crustal growth in Central Asia. Our samples come from a transect from Bayanhongor to Ulaan Baatar, including three tectonic units: the Baydrag cratonic block (late Archean to middle Proterozoic), the Eo-Cambrian Bayanhongor ophiolite complex and the Hangay–Hentey Basin of controversial origin. The intrusive granitoids have ages ranging from ca. 540 to 120 Ma. The majority of the samples are slightly peraluminous and can be classified as granite (s.s.), including monzogranite, syenogranite and alkali feldspar granite. Most of the rocks have initial ⁸⁷Sr/⁸⁶Sr ratios between 0.705 and 0.707. Late Paleozoic to Mesozoic granitoids (≤250 Ma) are characterized by near-zero _Nd(T) values (0 to −2), whereas older granitoids show lower _Nd(T) values (−1.5 to −7). The data confirm the earlier observation of Kovalenko et al. [Geochemistry International 34 (1996) 628] who showed that granitoids emplaced outside of the Pre-Riphean basement rocks are characterized by juvenile positive _Nd(T) values, whereas those within the Pre-Riphean domain and the Baydrag cratonic block, as for the present case, show a significant effect of ‘contamination’ by Precambrian basement rocks. Nevertheless, mass balance calculation suggests that the granitoids were derived from sources composed of at least 80% juvenile mantle-derived component. Despite our small set of new data, the present study reinforces the general scenario of massive juvenile crust production in the CAOB with limited influence of old microcontinents in the genesis of Phanerozoic granitoids.     

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.     

Spillover effect offsets the conservation effort in the Amazon

Diverse conservation efforts have been expanding around the globe, even under the stress of increasing agricultural production. A striking example is the supply-chain agreements put upon the Amazon forest which had reduced deforestation by 80% from the early 2000s (27,772 km²) to 2015 (6207 km²). However, evaluation of these conservation efforts usually focused on the impacts within the Amazon biome only, while the effects that spill over to other areas (e.g., displacement of environmental pressure from one area to another) were rarely considered. Ignoring spillover effects may lead to biased or even wrong conclusions about the effectiveness of these conservation efforts because the hidden cost outside the target area of conservation may offset the achievement within it. It is thus important to assess the spillover effects of these supply-chain agreements. In this study, we used the two supply-chain agreements (i.e., Soy Moratorium and zero-deforestation beef agreement) implemented in the Amazon biome as examples and evaluated their spillover effects to the Cerrado. To achieve a holistic evaluation of the spillover effects, we adopted the telecoupling framework in our analysis. The application of the telecoupling framework includes the interactions between distant systems and extends the analytical boundaries beyond the signatory areas, which fill the gap of previous studies. Our results indicate that the supply-chain agreements have significantly reduced deforestation by half compared to projections within the sending system (i.e., Pará State in the Amazon, which exports soybeans and other agricultural products), but at the cost of increasing deforestation in the spillover system (i.e., a 6.6 time increase in Tocantins State of the Cerrado, where deforestation was affected by interactions between the Amazon and other places). Our study emphasizes that spillover effects should be considered in the evaluation and planning of conservation efforts, for which the telecoupling framework works as a useful tool to do that systematically.     

Oceanographic controls on the carbon isotopic compositions of sinking particles from the Cariaco Basin

This study examined the relationship between carbon isotopic composition of sinking organic matter (OM) and the biological, physical and chemical properties of the surface ocean in the Cariaco Basin. The ¹³C/¹²C ratio of OM (δ¹³C_org) in sinking particles was determined on sediment trap samples from four depths collected from 1996 to 1999 as part of the CArbon Retention In A Colored Ocean time series. Water column properties, including temperature, productivity, chlorophyll and concentration of dissolved CO₂, were concurrently measured on monthly cruises. The δ¹³C_org varied from a high of –17.7‰ to a low of –22.6‰ during the study period. The variation of the δ¹³C_org throughout seasonal cycles was directly proportional to the strength of upwelling and was negatively correlated with temperature (r²=0.64). During the 1996–1997 upwelling event, the strongest during the study period, the δ¹³C_org increased by 4.4‰ whereas during the 1998–1999 upwelling event, the weakest during the study period, the δ¹³C_org only increased by 3.3‰. Contrary to most previous studies, we observed a negative relationship (r²=0.53) between [CO_2 aq] and the estimated isotopic fractionation factor (ε_p). However, there was no correlation between ε_p and the calculated growth rates indicating that there was non-diffusive uptake of carbon into phytoplankton cells. It thus appears that [CO_2 aq] does not control the δ¹³C_org in the water column of the study site. The best explanation for the isotopic enrichment observed is a carbon concentrating mechanism (CCM) in phytoplankton. The existence of a CCM in phytoplankton has major implications for the interpretation of the δ¹³C_org in the Cariaco Basin.