Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.     

Mineral assemblages occurring around hydrocarbon vents in the northern Gulf of Mexico

Magnesian calcites are the most abundant authigenic minerals associated with hydrocarbon vents at 25 sites, in water depths ranging from 100 to 600 m in the Green Canyon area and about 2200 m in the Alaminos Canyon area on the Continental Slope of the northern Gulf of Mexico. The most frequently encountered magnesian calcites have 10–15 mol% MgCO₃ and the apparent structural disorder revealed by XRD peak widths increases with Mg substitution. There are no systematic variations in Mg content with respect to water depth or geographic location. The calcite saturation state of the precipitating fluid is primarily determined by the nature of the fluids escaping from the vents, not the ambient seawater.     

Design of a 3D Chirp Sub-bottom Imaging System

Chirp sub-bottom profilers are marine acoustic devices that use a known and repeatable source signature (1–24 kHz) to produce decimetre vertical resolution cross-sections of the sub-seabed. Here the design and development of the first true 3D Chirp system is described. When developing the design, critical factors that had to be considered included spatial aliasing, and precise positioning of sources and receivers. Full 3D numerical modelling of the combined source and receiver directivity was completed to determine optimal source and receiver geometries. The design incorporates four source transducers (1.5–13 kHz) that can be arranged into different configurations, including Maltese Cross, a square and two separated pairs. The receive array comprises 240 hydrophones in 60 groups whose group-centres are separated by 25 cm in both horizontal directions, with each hydrophone group containing four individual elements and a pre-amplifier. After careful consideration, it was concluded that the only way to determine with sufficient accuracy the source–receiver geometry, was to fix the sources and receivers within a rigid array. Positional information for the array is given by a Real Time Kinematic GPS and attitude system incorporating four antennas to give position, heading, pitch and roll. It is shown that this system offers vertical positioning accuracy with a root-mean-square (rms) error less than 2.6 cm, while the horizontal positioning rms error was less than 2.0 cm. The system is configured so that the Chirp source signature can be chosen by software aboard the acquisition vessel. The complete system is described and initial navigational and seismic data results are presented. These data demonstrate that the approach of using fixed source-receiver geometry combined with RTK navigation can provide complete 3D imaging of the sub-surface.     

Drag Coefficient,Dynamic Roughness and Reference Wind Speed

Surface waves are the roughness element of the ocean surface. The parameterization of the drag coefficient of the ocean surface is simplified by referencing to wind speed at an elevation proportional to the characteristic wavelength. The dynamic roughness is analytically related to the drag coefficient. Under the assumption of fetch limited wave growth condition, various empirical functions of the dynamic roughness can be converted to equivalent expressions for comparison. For datasets covering a wide range of the dimensionless frequency (inverse wave age), it is important to account for the variable rate of wave development at different wave ages. As a result, the dependence of the Charnock parameter on wave age is nonmonotonic. Finally, the analysis presented here suggests that the significant wave steepness is a sensitive property of the ocean surface and a single variable normalization of the dynamic roughness using a wavelength or wave height parameter actually produces more robust functions than bi-variable normalizations using wave height and wave slope.     

Sequence stratigraphy of the Mississippi fan (Plio-Pleistocene), Gulf of Mexico

The Mississippi Fan is a large, mud-dominated submarine fan over 4 km thick, deposited in the deep Gulf of Mexico during the late Pliocene and Pleistocene. Analysis of 19,000 km of multifold seismic data defined 17 seismic sequences, each characterized by channel, levee, and associated overbank deposits, as well as mass transport deposits. At the base of nine sequences are a series of seismic facies consisting of mounded, hummocky, chaotic, and subparallel reflections, which constitute 10–20% of the sediments in each the sequences. These facies are externally mounded and occur in two general regions of the fan: (1) in the upper and middle fan they are elongate in shape and mimic the channel's distribution; (2) in the middle fan to lower fan they are characterized by a fan-shaped distribution, increasing in width downfan. These facies are interpreted to have formed as disorganized slides, debris flows, and turbidites (informally called “mass transport complexes”). Overlying this basal interval, characteristic of all sequences, are well-developed channel-levee systems that constitute 80–90% of the fan's sediments. Channels consist of high amplitude, subparallel reflections, whereas the flanking levee sediments appear as subparallel reflections that have high amplitudes at the base changing upward to low amplitude. The vertical change in amplitude may reflect a decrease in grain size and bed thicknesses. Overbank sediments are characterized by interbedded subparallel to hummocky and mounded reflections, suggesting both turbidites from the channel, as well as slides and debris flows derived both locally and from the slope updip.     

Toxicity of Santa Barbara seep oil to starfish embryos: Part 2—the growth bioassay

The asteroid Patiria miniata was used to develop a static bioassay for various crude oil water-soluble fractions (WSF). The criterion used is the size of 48-h exposed embryos. The reasons for choosing this species and the growth criterion are discussed. Experiments show that the body length of 48-h exposed embryos is inversely proportional to hydrocarbon concentration of the WSF and the time of exposure. It is also shown that the toxicity of the WSF decreases with the age of the preparation and that the first 12 h following fertilisation are most sensitive to the effects of WSF.     

Ocean Waves: Half-a-Century of Discovery

While the nature of most ocean waves has long been known and their basic physics understood since the nineteenth century, intense study of ocean waves during the second half of the twentieth century has taken the subject from the realm of mathematical exercises to that of practical engineering. Modern understanding of the generation, propagation and interactions of ocean waves with each other and with oceanic features has advanced to a quantitative level offering predictive capacity. This paper presents a brief qualitative review of advances in knowledge of sound waves, wind waves, tsunamis, tides, internal waves and long-period vorticity waves. The review is aimed at non-specialists who may benefit from an overview of the current state of the subject and access to a bibliography of general-interest references. This revised version was published online in August 2006 with corrections to the Cover Date.     

Impact of Satellite Altimetry on Simulations of Sea Level Variability by an Indian Ocean Model

This article describes the impact of satellite altimeter data on the simulations of sea level variability (SLV) by a nonlinear reduced gravity model of the entire Indian Ocean. The model has been forced by 6-hourly analyzed wind stress data containing SSM/I observations and has been able to produce realistic circulation features. However, SLV values observed by Topex/Poseidon altimeter do not fit these simulations because of imperfect initial data. Hence an attempt has been made to initialize the model using altimeter data. The initialized model-generated SLVvalues have been compared with SLV derived by altimeter for monsoon as well as nonmonsoon months of 1996. Experimental runs have been performed for 10 days, 20 days, and one month. It has been found that the initialized model results on the final day of these experiments are in very good agreement with altimeter data of the same day. It is thus possible, in principle, to hindcast and forecast sea level variations in the time scale of 10 days to one month with the availability of good quality wind data for forcing the model and altimeter observations of sea level for initializing it.     

Comparison of TOPEX/POSEIDON Altimeter Derived Wind Speed and Wave Parameters with Ocean Buoy Data in the North Indian Ocean

Results of comparison exercises carried out between the state-of-the-art TOPEX/POSEIDON altimeter-derived ocean surface wind speed and ocean wave parameters (significant wave height and wave period) and those measured by a set of ocean data buoys in the North Indian Ocean are presented in this article. Altimeter-derived significant wave height values exhibited rms deviation as small as ±0.3 m, and surface wind speed of ±1.6 m/s. These results are found consistent with those found for the Pacific Ocean. For estimation of ocean wave period, the spectral moments-based semiempirical approach, earlier applied on GEOSAT data, was extended to TOPEX/POSEIDON. For this purpose, distributions of first four years of TOPEX/POSEIDON altimeter data and climatology over the North Indian Ocean were analyzed and a new set of coefficients generated for estimation of wave period. It is shown that wave periods thus estimated from TOPEX/POSEIDON data (for the subsequent two years), when compared with independent data set of ocean data buoys deployed in the North Indian Ocean, exhibit improved accuracy (rms ~ ±1.4 nos) over those determined earlier with GEOSAT data.