The crystal structure of bøgvadite (Na2SrBa2Al4F20)

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.     

Study of groundwaters using the environmental tritium and hydrochemical data in the Belgrade region

A study of tritium content and some physicochemical parameters has been performed in order to investigate interconnection between surface and atmospheric waters and underground waters in Belgrade area. Samples of the precipitation at Zeleno Brdo-Belgrade meteorological station, the Danube and the Sava river water, and underground water (Ranney wells and piezometers) have been analyzed. The³H content, the content of dissolved ions, total hardness, and electrical conductivity have been measured. The tritium data show existence of two water strata in the aquifer. The upper stratum (about 16 m thick) contains older water (mean monthly³H concentration of 17 TU) and has weak interaction with the river and the precipitation. Below this stratum lies the principal water bearing stratum, strongly connected with the river with the³H concentration similar to that of surface water (mean monthly³H concentration of 50 TU) and spreading out through the entire aquifer. The contribution of the Sava river water and the two water layers at the Ranney well are calculated starting with the hydrological aquifer model, which supposes that three water components are mixed in the pumped Ranney well water. According to calculation results using the³H concentration and physicochemical characteristics as parameters, more than 70 percent of the water pumped by the Ranney well (in 1983) comes from the Sava with a time delay of less that 15 days.Properties of tritium distribution in precipitation, river waters, and underground water in the Belgrade region are established from the results of measurements of³H concentrations in the period 1976–1983.     

Modelling of atmospheric dispersion of heavy metals in the Celje area,Slovenia

The aim of this research was to determine how fast the level of heavy metal concentrations in the air decreases in relation to increasing distance from the source of pollution and what the influence area is of the zinc smelting plant which existed for 100 years in Celje. In that period it produced approximately 580,000 tons of raw Zn from sphalerite ore by the pyrometallurgical process. The production left behind a heavily contaminated area, where the concentrations of Pb and Zn in the soil can be expressed as a percentage. A model has been made on the basis of the data of concentrations of Zn and Cd in the soil and attic dust regarding the distance and direction from the source of the pollution. Because Celje lies in a basin we chose a linear model, which describes the decreasing of the concentrations of Zn and Cd only in one direction. Sampling has been conducted on the four river valleys which stretch from the source of the pollution in all four directions: north, west, south and east, up to 13 km from the source. The power function with a negative exponent was used. With the solution to the calculated functions according to the distance, we can estimate the theoretical distance when the concentrations drop to the natural background level. The range of influence of the zinc smelting plant has been estimated to be between 14 and 52 km for the presence of anthropogenic Zn in attic dust and between 9 and 14 km for the presence of anthropogenic Zn in the soil, depending on the direction from the plant. Correlations between the measured values and the ones from the model are high: from 0.75 up to 0.98.     

Thermal stability of extended clusters in dravite: a combined EMP,SREF and FTIR study

A dravite from Yemen of near end-member composition was treated in air and hydrogen atmospheres at 600–900 °C to reveal changes in Mg and Al order over the octahedrally coordinated Y and Z sites, and to explore related changes in the characteristic vibrational bands in the principal (OH)-stretching frequency. Relevant information was obtained using electron microprobe analysis (EMPA), structural refinement (SREF) and polarized infrared (IR) single-crystal spectroscopy. Overall, the EMPA, SREF and IR data show that only minor changes occur during thermal treatment up to at least 800 °C, including variations in structural parameters, Mg–Al order–disorder and (OH)-stretching bands, indicating limited hydrogen loss. Untreated and treated dravite samples have very similar long-range and short-range atomic structures, which may be related to the occurrence of stable Al–Mg extended clusters around the O1 (=W) and O3 (=V) sites: ^W(F)–^Y(MgMgMg)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(OH)–^Y(MgMgAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]; ^W(O^2–)–^Y(AlAlAl)–^V(OH)₃–^Z[AlAlAlAlAl(Al,Mg)]. These extended clusters remain stable to temperatures close to the observed start of decomposition (~900 °C).     

Climate Change Impacts and Adaptation Strategies in Spring Barley Production in the Czech Republic

The crop model CERES-Barley was used to assess the impacts of increased concentration of atmospheric CO₂ on growth and development of the most important spring cereal in Central and Western Europe, i.e., spring barley, and to examine possible adaptation strategies. Three experimental regions were selected to compare the climate change impacts in various climatic and pedological conditions. The analysis was based on multi-year crop model simulations run with daily weather series obtained by stochastic weather generator and included two yield levels: stressed yields and potential yields. Four climate change scenarios based on global climate models and representing 2 × CO₂ climate were applied. Results: (i) The crop model is suitable for use in the given environment, e.g., the coefficient of determination between the simulated and experimental yields equals 0.88. (ii) The indirect effect related to changed weather conditions is mostly negative. Its magnitude ranges from ?19% to +5% for the four scenarios applied at the three regions. (iii) The magnitude of the direct effect of doubled CO₂ on the stressed yields for the three test sites is 35–55% in the present climate and 25–65% in the 2 × CO₂ climates. (iv) The stressed yields would increase in 2 × CO₂ conditions by 13–52% when both direct and indirect effects were considered. (v) The impacts of doubled CO₂ on potential yields are more uniform throughout the localities in comparison with the stressed yields. The magnitude of the indirect and direct effects ranges from ?1 to ?9% and from +31 to +33%, respectively. Superposition of both effects results in 19–30% increase of the potential yields. (vi) Application of the earlier planting date (up to 60 days) would result in 15–22% increase of the yields in 2 × CO₂ conditions. (vii) Use of a cultivar with longer vegetation duration would bring 1.5% yield increase per one extra day of the vegetation season. (viii) The initial water content in the soil water profile proved to be one of the key elements determining the spring barley yield. It causes the yields to increase by 54–101 kg.ha^?1 per 1% increase of the available soil water content on the sowing day.     

Tectonic evolution of a continental magmatic arc from transpression in the upper crust to exhumation of mid-crustal orogenic root recorded by episodically emplaced plutons: the Central Bohemian Plutonic Complex (Bohemian Massif)

The Central Bohemian Plutonic Complex (CBPC) consists of episodically emplaced plutons, the internal fabrics of which recorded tectonic evolution of a continental magmatic arc. The ~354–350 Ma calc-alkaline plutons were emplaced by multiple processes into the upper-crustal Teplá-Barrandian Unit, and their magmatic fabrics recorded increments of regional transpression. Multiple fabrics of the younger, ~346 Ma Blatná pluton recorded both regional transpression and the onset of exhumation of mid-crustal orogenic root (Moldanubian Unit). Continuous exhumation-related deformation during pluton cooling resulted in the development of a wide zone of sub-solidus deformation along the SE margin of the CBPC. Finally, syn-exhumation tabular durbachitic pluton of ultrapotassic composition was emplaced atop the intrusive sequence at ~343–340 Ma, and the ultrapotassic Tábor pluton intruded after exhumation of the orogenic root (~337 Ma). We suggest that the emplacement of plutons during regional transpression in the upper crust produced thermally softened domain which then accommodated the exhumation of the mid-crustal orogenic root, and that the complex nature of the Teplá-Barrandian/Moldanubian boundary is a result of regional transpression in the upper crust, the enhancement of regional deformation in overlapping structural aureoles, the subsequent exhumation of the orogenic root domain, and post-emplacement brittle faulting.     

Magmatic stoping as an important emplacement mechanism of Variscan plutons: evidence from roof pendants in the Central Bohemian Plutonic Complex (Bohemian Massif)

The presence of numerous roof pendants, stoped blocks and discordant intrusive contacts suggests that magmatic stoping was a widespread, large-scale process during the final construction of the Central Bohemian Plutonic Complex, Bohemian Massif. The measured total length of the discordant contacts that cut off the regional cleavage and were presumably formed by stoping corresponds to about half of all contacts with the upper-crustal host rocks. In addition, at least some of the straight, cleavage-parallel intrusive contacts may also have recorded complex intrusive histories ending with piecemeal stoping of thin cleavage-bounded host rock blocks into the magma chamber. Based on the above, we argue that the fast strain rates required for emplacement of large plutons of the Central Bohemian Plutonic Complex into brittle upper crustal host rocks over relatively short-time span could not have been accommodated entirely by slow ductile flow or slip along faults. Instead, the emplacement was largely accommodated by much faster thermal cracking and extensive stoping independent of regional tectonic deformation. Finally, we emphasize that magmatic stoping may significantly modify the preserved structural patterns around plutons, may operate as an important mechanism of final construction of upper-crustal plutons and thus may contribute to vertical recycling and downward transport of crustal material within the magma plumbing systems in the crust.     

Simultaneous inversion for velocity structure and hypocenters in Slovenia

We use nearly 2100 P-wave arrival times from 166 local earthquakes to investigate the 3-D compressional velocity structure of the upper crust of Slovenia using the simultaneous inversion algorithm developed by (Michelini and McEvilly, 1991). Remarkable and stable features of the resolved model are the relatively high velocities in western Slovenia and the low velocities in central Slovenia, SE of the Ljubljana basin. The boundary between these two anomalies follows approximately the NNW-SSE direction that coincides with the general strike of the External Dinarides. We interpret this feature as the upper crustal expression caused by the tectonic processes occurring along the active margin of the Adria promontory/microplate.     

Intensive sampling of iodine and nutrient speciation in naturally eutrophicated anchialine pond (Rogoznica Lake) during spring and summer seasons

A study of inorganic iodine speciation in the water column of a naturally eutrophicated anchialine pond (Rogoznica Lake, East Adriatic Coast) was conducted in a period between April and July 2004 to obtain information how close the inorganic iodine system is to that of inorganic nutrients during spring, when phytoplankton activity is at maximum, and how the system changes up to summer, when highly reducible redox-conditions prevail in deep water.