Astrovirtel—From Archival Research to the Astrophysical Virtual Observatory

Given the high cost of modern astronomical observing facilities it is evident that efforts must be made to optimally exploit the data in order to maximize the return on investment. This concept was first implemented on a large scale for the Hubble Space Telescope, and has since been taken over for other space borne and large ground-based facilities. The European HST Science Data Archive is located at the European Southern Observatory (ESO). It has been extended to include data from ESO telescopes and instruments, especially the Very Large Telescope (VLT) and Wide Field Imager (WFI). It was thus natural to design the archive such that queries could be extended across its full content, regardless of the origin of the data. This constituted a first step toward a virtual observatory. The Astrovirtel program, first established in 1999–2000 with funding provided by the European Commission, makes it possible for scientists to use this facility for their investigations. At the same time it allowed us to establish science requirements for archive cross queries, and to define capabilities required for VO's. Recently the European Commission decided to provide the funding for the implementation of the Astrophysical Virtual Observatory (AVO). This will include several European observatories and scientific organizations. It is being developed in close coordination with the US National Virtual Observatory.     

Metallothioneins and trace metals in the dogwhelk Nucella lapillus (L.) collected from Icelandic coasts

Different sizes of the dogwhelk Nucella lapillus were collected from eight locations along the southwest and north coasts of Iceland. Concentrations of total metallothioneins (MTs) and heavy metals (Cd, Cu, Cr, Mn, Ni, and Zn) were analysed using the silver saturation method and inductively coupled plasma-atomic emission spectrometry. The level of tributyltin (TBT) contamination was also assessed using imposex indices, the vas deferens stage index (VDSI) and relative penis size index (RPSI). Gufunes N. lapillus presented the highest values of VDSI (4.0) and RPSI (11.1), followed by Grenivík individuals (VDSI = 3.0; RPSI = 0.9), while the Strandakirkja population showed the lowest VDSI (0.3) and zero RPSI. At a standardised size (0.25 g dry soft-body weight), Grenivík N. lapillus exhibited significantly higher concentrations of all metals whereas overall metal concentrations were significantly lower in individuals from Strandakirkja and Garðskagi compared to other study sites. Partial correlation analyses with size correction indicated that MT concentrations were better correlated with Cd and Cu concentrations than with other metals. At the standard size, the pattern of MT concentrations in N. lapillus from different sites was, however, very different from those of metal profiles. Such discrepancies between the patterns of MT and metals in N. lapillus might be explained by the fact that MT induction could be influenced by various factors such as temperature, dietary metal intake, growth rate and co-existence of other MT-inducing chemicals.     

Partnering between a geography department and a community initiative to provide a wind resource assessment for the Blueskin Bay region,Otago, New Zealand

This paper explores the partnership between a community group and a geography department to assess the wind energy potential of the Blueskin Bay region in southern New Zealand. The partnership has provided opportunities for research and is of strategic importance. Year‐long wind observations and numerical modelling have revealed that the hills surrounding Blueskin Bay show potential for wind energy generation. Despite challenges for both parties, the university–community partnership has allowed a successful research platform to be established.     

Growing up and cleaning up: The environmental Kuznets curve redux

Borrowing from the Kuznets curve literature, researchers have coined the term “environmental Kuznets curve” or EKC to characterize the relationship between pollution levels and income: pollution levels will increase with income but some threshold of income will eventually be reached, beyond which pollution levels will decrease. The link between the original Kuznets curve, which posited a similar relationship between income and inequality, and its pollution-concerned offspring lies primarily with the shape of both curves (an upside-down U) and the central role played by income change. Although the EKC literature has burgeoned over the past several years, few concrete conclusions have been drawn, the main themes of the literature have remained constant, and no consensus has been reached regarding the existence of an environmental Kuznets curve. EKC research has used a variety of types of data and a range of geographical units to examine the effects of income levels on pollution. Changes in pollution levels might also be at least partly explained by countries’ position in the demographic transition and their general population structure, however little research has included this important aspect in the analysis. In addition, few analyses confine themselves to an evaluation for one country of the long-term relationship between income and pollution. Using United States CO₂ emissions as well as demographic, employment, trade and energy price data, this paper seeks to highlight the potential impact of population and economic structure in explaining the relationship between income and pollution levels.     

Climate change and agriculture in computable general equilibrium models: alternative modeling strategies and data needs

Agricultural sectors play a key role in the economics of climate change. Land as an input to agricultural production is one of the most important links between economy and the biosphere, representing a direct projection of human action on the natural environment. Agricultural management practices and cropping patterns exert an enormous effect on biogeochemical cycles, freshwater availability and soil quality. Agriculture also plays an important role in emitting and storing greenhouse gases. To consistently investigate climate policy and future pathways for the economic and natural environment, a realistic representation of agricultural land use is essential. Top—down Computable General Equilibrium (CGE) models have increasingly been used for this purpose. CGE models simulate the simultaneous equilibrium in a set of interdependent markets, and are especially suited to analyze agricultural markets from a global perspective. However, modeling agricultural sectors in CGE models is not a trivial task, mainly because of differences in temporal and geographic aggregation scales. This study surveys some proposed modeling strategies and highlights different tradeoffs involved in the various approaches. Coupling of top-down and bottom-up models is found to be the most applicable for comprehensive analysis of agriculture in prism of climate change. However, linking interdisciplinary data, methods and outputs is still the major obstacle to be solved for wide-scale implementation.     

A study of charge structure sensitivity in simulated thunderstorms

Two different thunderstorms are simulated by two distinct one-dimensional cloud models using four different parameterisations of the non-inductive mechanism of electric charging, based on laboratory studies. The results demonstrate that during the early (pre-lightning) stage of thunderstorm electrification, simulated charge density depends not only on the model charging parameterisation employed, but also on the specific representations of the kinematics and microphysical characteristics of the model itself. Though no conclusions are drawn regarding the physical suitability of the charging parameterisations themselves, the analysis indicates that the most significant differences between the simulated charge structures of the clouds produced in each particular model are the result of different distributions of model cloud characteristics and of the type of parameterisation of the microphysical processes. The study reveals that it is too early to make any conclusion regarding which, if any, of the existing parameterisation schemes are better suited to the realistic simulation of electrical charging in real clouds.     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part II: synthesis of a S-spiro-like dithiolane triterpenoid

A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches.