微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷

建立了微波辅助提取-氢化物发生原子荧光光谱法测定土壤中无机砷的分析方法。用正交试验设计结合单因素试验优化了样品粒度、提取温度、提取时间、固液比等微波提取条件，研究了共存离子对无机砷测定的干扰情况。方法的线性范围为0．25～40．0μg/g，无机砷的检出限为0．05μg/g，样品加标回收率为92．9％～105．0％。方法的精密度（RSD，n=11）为0．3％。与水浴提取法相比，微波辅助提取法具有快速、高效的优势。方法已用于分析3个不同产地有代表性土壤中无机砷含量。     

蔚县盆地中更新世哺乳动物化石新发现

1 研究目的(Objective) 蔚县盆地为典型的冀西北山间盆地,与阳原盆地仅一山之隔,二者共同组成了广义的"泥河湾盆地",盆地内广泛出露中更新统郝家台组(Qp2h)河-湖相沉积物.相比阳原盆地,蔚县盆地古生物化石研究程度较低.20世纪80年代,盆地北部(大南沟一带)出土具有上新世—早更新世面貌的小型哺乳动物化石,近...     

Regional accessibility of land traffic network in the Yangtze River Delta

In a given district, the accessibility of any point should be the synthetically evalua-tion of the internal and external accessibilities. Using MapX component and Delphi, the author presents an information system to calculate and analyze regional accessibility according to the shortest travel time, generating thus a mark diffusing figure. Based on land traffic network, this paper assesses the present and the future regional accessibilities of sixteen major cities in the Yangtze River Delta. The result shows that the regional accessibility of the Yangtze River Delta presents a fan with Shanghai as its core. The top two most accessible cities are Shanghai and Jiaxing, and the bottom two ones are Taizhou (Zhejiang province) and Nantong. With the construction of Sutong Bridge, Hangzhouwan Bridge and Zhoushan Bridge, the re-gional internal accessibility of all cities will be improved. Especially for Shaoxing, Ningbo and Taizhou (Jiangsu province), the regional internal accessibility will be decreased by one hour, and other cities will be shortened by about 25 minutes averagely. As the construction of Yangkou Harbor in Nantong, the regional external accessibility of the harbor cities in Jiangsu province will be speeded up by about one hour.     

Garnet-bearing Granulite Facies Rock Xenoliths from Late Mesozoic Volcaniclastic Breccia, Xinyang, Henan Province

This paper presents the primary results of petrologic, mineralogical and petrochemical studies of garnet-bearing granulite facies rock xenoliths from Xinyang, Henan Province. These xenoliths, which are found in a pipe of late Mesozoic volcaniclastic breccia, are of high density (3.13-3.30 g/cm3) and high seismic velocity (Vp = 7.04-7.31 km/s), being products of underplating of basaltic magmas and had experienced granulite facies metamorphism. The underplating and metamorphism took place before the eruption of the host rock. Petrographical studies and equilibrium T-P calculations show that these xenoliths were captured at a 49 km depth and experienced at least a 16 km uplift before they were captured. The dynamics of the uplift could be related to the continent-continent collision between the North China plate and the Yangtze plate during the Triassic.     

The Major Two-stage Shortening Deformation of the Northern Tibet and Tian Shan Area Since the Latest Oligocene

It seems to be progressively recognized that the stress of the India-Asia convergent front can be transferred rapidly through the southern and central Tibetan lithosphere to the northern Tibet, hence leading to the crustal thickening deformation there during or immediately after the onset of the India-Asia collision(ca.55 Ma).This study focuses on the late Cenozoic deformation and tectonic uplift of the northern Tibet and Tian Shan area.Detailed compilations of a variety of proxy data from sediments and bedrocks suggest that the northern Tibet and Tian Shan area underwent one stage of approximately synchronous widespread contractile deformation since 25–20 Ma, which seemed to decrease at circa 18 Ma as revealed by low-temperature thermochronological data.The latest Oligocene-early Miocene was also significant basin-forming episodes when many intermontane subbasins began to receive syntectonic sedimentation in the northeastern Tibet.Subsequently, the other phase of compressional deformation began to encroach more widely into the northern Tibet and Tian Shan area in episodic steps or continuously from 16–12 Ma to present.     

塔里木盆地南缘8.5 ka以来的黄土岩石磁学特征及其磁化率变化机制

黄土岩石磁学参数是古气候研究中的重要指标,其中磁化率应用最为广泛,并在黄土高原地区取得重大进展,其受控于成壤作用的变化机制也被普遍接受.然而在黄土高原外缘的新疆地区,磁化率的变化机制仍不明确,导致磁化率的古气候意义在该区存在较大争议.本文选取塔里木盆地南缘具有精确年代控制的典型黄土剖面（羊场剖面）开展岩石磁学和高分辨率磁化率研究,利用交叉小波分析方法并结合剖面粒度、矿物及元素特征对该地区磁化率变化机制进行初步探讨.结果显示,羊场剖面的岩石磁学性质主要由粗颗粒软磁性矿物所控制,同时也表现出一定的顺磁性特征.根据载磁矿物和磁化率变化特征可将剖面进一步划分为两个阶段：阶段Ⅰ（8.5~2.5 ka）,载磁矿物以亚铁磁性的磁铁矿为主,磁化率值整体较高;阶段Ⅱ（2.5~0.2 ka）,亚铁磁性矿物依然占据主导地位,但硬磁性矿物和以黄铁矿为代表的顺磁性矿物相对增多,磁化率值显著降低.相关性研究和交叉小波分析表明：阶段Ⅰ磁化率与粗颗粒组分的变化具有一致性,符合"风速论"模式;阶段Ⅱ磁化率不仅与粗颗粒组分具有明显的正相关关系,而且与指示成壤作用强度的频率磁化率百分含量呈现出显著的负相关关系,暗示了阶段Ⅱ的磁化率变化可能受到"风速论"和"还原性成壤"模式的共同影响.本文拓宽了对新疆地区黄土岩石磁学特征及其磁化率变化机制的深入理解,也为利用磁化率恢复新疆及中亚地区全新世以来的古气候变化历史提供了新的线索.     

原子荧光光谱法测定铁矿石中的镉

样品经盐酸-硝酸-氢氟酸-高氯酸混合酸溶解,用原子荧光光谱法测定铁矿石中的镉。实验确定了最佳酸度、增感剂镍量、抗坏血酸量和硫脲量,并确定了仪器测定最佳条件,对干扰元素的允许量进行了研究。方法检出限为0.20μg/L,精密度为4.5%,线性范围为0~160μg/L,加标回收率为95.9%~103.7%。方法可应用于铁矿石的快速检测。     

Review of the Study of Nonlinear Atmospheric Dynamics in China （1999-2002）

Researches on nonlinear atmospheric dynamics in China (1999-2002) are briefly surveyed. This review includes the major achievements in the following branches of nonlinear dynamics: nonlinear stability theory,nonlinear blocking dynamics, 3D spiral structure in the atmosphere, traveling wave solution of the nonlinear evolution equation, numerical predictability in a chaotic system, and global analysis of climate dynamics.Some applications of nonlinear methods such as hierarchy structure of climate and scaling invariance, the spatial-temporal series predictive method, the nonlinear inverse problem, and a new difference scheme with multi-time levels are also introduced.     

基于IMU旋转的船用激光导航系统分析与设计

利用惯性测量单元(IMU)旋转技术可以有效调制惯性元件的零位偏置,提高惯性导航系统的长时间导航精度.针对船用惯性导航系统的应用需求,设计了IMU单轴旋转的船用激光陀螺捷联式惯性导航系统.分析了IMU单轴旋转的工作机理,并通过仿真进行了验证.对导航系统的总体方案、原理方案和旋转方案的原理和实现进行了论述,初步的性能试验验证了设计方案的有效性.