The application of confocal microscopy to the study of stone weathering

Confocal scanning light microscopy is a valuable new method for examining the nature and progress of stone weathering at a level of resolution between optical microscopy and scanning electron microscopy. Not only is it non-destructive, but it can also create three-dimensional images.     

Tertiarisation and socio-spatial differentiation in Wales

Processes of economic restructuring and social recomposition have been proceeding at an accelerated pace in Wales of late. This paper seeks to show that these changes, which began with a redistribution of manufacturing employment initially, but which have more recently been dominated by the restructuring of the tertiary sector, can best be understood as a regional effect of the growing spatial division of labour in the UK and internationally. Of special interest is the manner in which the dual spatial divisions in secondary and tertiary economic activity produce new combinations of spatial and social differentiation at the sub-regional level.     

The effects of hardpan layers on the water chemistry from the leaching of pyrrhotite-rich tailings material

Column leaching experiments were used to determine the effects of an iron-rich hardpan layer, on the rate of tailings oxidation and the composition of leachate waters, from the Renison Bell tailings dams in western Tasmania, Australia. One-meter-long PVC columns, filled with tailings, cover material (Cassiterite Flotation Tailings) and hardpan samples from the tailings dams, were leached over a period of 14 weeks. Under dry cover conditions, when hardpan was present, the solute loads peaked at 21–49 days (Fe at 2,294 ppm and SO ₄ ^2- at 4,700 ppm), and stabilised at much lower concentrations after 9 weeks. In contrast, the solute loads steadily increased over time in the column where hardpan was absent (SO ₄ ^2- from 1,800 to 3,100 ppm, and Fe from 407 to 1,692 ppm). Under saturated cover conditions, the solute concentrations in the leachate also increased with time (SO ₄ ^2-from 1,900 to 17,000 ppm, and Fe from 480 to 8,500 ppm). The presence of a hardpan layer between the reactive tailings and cover material has been found to improve leachate water chemistry and lessen the rate of sulphide oxidation.     

Stone movement on hillslopes in the Mojave Desert,California: A 16-year record

Previous research has shown that either hydraulic action or creep may be the dominant process transporting coarse debris down hillslopes in the American Southwest. This study analyses the movement over 16 years of painted stones on two hillslopes in the central Mojave Desert to ascertain which of these two processes dominate in this region. The distance moved (M) is found to be directly related to length of overland flow (X) and hillslope gradient (S), and inversely related to particle size (D). The fact that M is more highly correlated with X than with S suggests that hydraulic action rather than creep is the dominant process. It is concluded that this is probably the case over most of the Mojave and Sonoran Deserts on slopes up to at least 24°, and that it is only at higher elevations where winters are more severe that creep may become dominant.     

Salt efflorescences and Saline lakes; a distributional analysis

Salt lakes and salt efflorescences are a common phenomenon of many arid zones. Rocks weather rapidly in the presence of saline materials, and the rate of such weathering may be controlled by the mineralogy of the salts concerned. The distribution of the main salt types is presented for the polar deserts of Antarctica and the Arctic, and for the warmer deserts of Australia, North America, South America, Africa and Asia. There is great variety in the types of salts encountered and marked differences between different regions, with, for example, Australia being dominated by sodium chloride (halite) and southern Canada by the sulphates of magnesium and sodium. The possible causes of such variability and its pattern are analysed in terms of the nature of inputs into drainage basins and the various changes that take place within basins. Finally, it is apparent that in those situations when weathering has been observed as an active process there are a great many different salts involved.     

Infrared spectra of polyoxymethylene grains

The optical constantsn andk for polyoxymethylene (POM) have been calculated in the spectral range between 7 and 13 , using transmission measurements and the Kramers-Kronig dispersion relations. These constants may be of use in making detailed comparisons of observational data such as the interstellar 10 band.     

The Origin and Distribution of Salts on Alluvial Fans in The Atacama Desert,Northern Chile

The Atacama Desert has been predominantly hyperarid since the middle Miocene. Combined ionic and X-ray diffraction analysis shows that calcium sulphate is prevalent on three similar alluvial fans in salar basins across a transect of different environments in Antofagasta Province, northern Chile. Differences between the fans were largely due to the effect of local factors on salt input, secondary redistribution and deposit preservation. Thus carbonate was notable in the High Andes (fan C) and Pre-Cordillera (fan B), whereas in the Central Valley (fan A) greater qualities of the more soluble salts (chlorides and nitrates) probably reflect the higher level of aridity and an oceanic source (the camanchaca). Calcium sulphate distribution on the alluvial fans and on adjacent hilltops indicates an aeolian origin. Evidence from the Pre-Cordillera (fan B), however, suggests that salt input may have been episodic, related to changes in conditions within the general aridity and possibly to stone pavement and soil development. Calcium sulphate sources range from an input in Andean precipitation and the camanchaca to abundant regional evaporite deposits. It is probable, however, that products of Andean volcanism constitute the dominant primary source of calcium sulphate, and that the salt has subsequently been distributed widely within the endoreic basins of the region by a combination of groundwater, surface flow and the wind. © 1997 John Wiley & Sons, Ltd.     

Evidence for the silicate source of relict soils on the Edwards Plateau, central Texas

Relict soils provide insights into Quaternary soil formation and erosion on the Edwards Plateau of central Texas and into soil-forming processes in karst terranes. Late Quaternary climate-driven soil erosion produced a mosaic of thick and thin soils on the Edwards Plateau landscape. Thick soils on uplands of the Edwards Plateau are interpreted to be relicts of a formerly more extensive soil cover that was eroded during the late Pleistocene to middle Holocene. The relict, thick soils are silicate-rich and most commonly overlie the relatively silicate-poor Cretaceous Edwards Limestone, which supports the idea that the thick soils did not form from weathering of the underlying limestone. Other potential sources of silicates for the relict soils include dust, alluvial sediments, and the Del Rio Clay, a stratigraphically higher but locally eroded clay-rich unit. Here we investigate the geographic distribution, texture, clay-sized mineralogy, rare earth element geochemistry, and neodymium isotope composition of the relict soils. We have found that the relict, thick soils are deeply weathered soils that occur dominantly over the Edwards Limestone and have a high clay content and a neodymium isotope composition that is similar to that of the Del Rio Clay. Thus, we propose that in situ weathering of the Del Rio Clay, along with partial weathering of the upper portion of the underlying Edwards Limestone produced thick chert- and clay-rich soils over resistant limestone. In areas like the Edwards Plateau, where pure limestones are interbedded with clay-rich strata, the overlying clay-rich strata must be considered as a possible silicate source to soils on pure limestone bedrock.