The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Observational estimation of heat budgets on drifting ice and open water over the Arctic Ocean

It is of major scientific interests to determine the parameters of momentum, heat and vapor exchange in the planetary boundary layer in order to study the effects of ocean-ice-atmosphere interactions and their feedback mechanisms on global climate[1]. Lin…     

A comparison of the photospheric and interplanetary magnetic fields during the flight of Mariner IV

The polarity of the interplanetary magnetic field observed by the Mariner IV spacecraft is compared to the polarity of the photospheric magnetic field observed with the solar magnetograph at Mt. Wilson Observatory. Unlike the results obtained from observations during the flight of IMP-I, these polarities are not well correlated when the photospheric polarity is determined from data along a narrow latitudinal strip. It is suggested that the structure of the interplanetary field is often related to major features in the photospheric field that are observed over a broad range of solar latitudes.     

The geometry and petrogenesis of hydrothermal dolomites at Navan, Ireland

The dolomites at Navan, Ireland, formed in Courceyan peritidal and shallow-shelf limestones. The dolomite body has a plume-like geometry, cross-cutting both lithological boundaries and diagenetic barriers generated by sea-floor cementation and emergence. The dolomitizing fluids rose parallel to major faults to diffuse laterally through the succession, controlled by variations in permeability that reflect both facies variation on deposition and pre-dolomitization diagenesis. Cathodoluminescent zones reveal three principal stages of dolomite emplacement, separated by dissolution surfaces, with each stage reflecting several changes in the character of dolomitizing solutions. The predominance of dull zones indicates burial rather than surface conditions. The dolomites formed some time after burial in response to an areally limited hydrothermally-driven flow. Isotope values (σ¹⁸O of — 6σ6 to — 10.4%_δ and σ¹³C of — 0σ2 to +2σ5%_δ PDB), and fluid inclusion data, suggest that these fluids had compositions similar to those of Carboniferous seawater. However, these became hotter with time, with temperature increasing from 60 to 160δC. The Navan dolomites are closely associated with Europe's largest zinc-lead deposit. The distribution of the ores follows the same trend as that of the dolomites and paragenetic relationships indicate that dolomitization and mineralization were temporally and genetically related.     

Pillow talk

Three distinct types of pillows and pillow lava sequences with different modes of origin have been recognized in the extrusive sequences comprising the upper parts of ophiolite complexes that represent the mafic portion of the floor of an Early Cretaceous back-arc basin in southern Chile. One type of pillow formed by non-explosive submarine effusion. A second type formed by magmatic intrusion into pre-existing aquagene tuff formed by explosive eruption. The third type of pillow occurs within dikes, forming pillowed dikes, possibly as a result of vapor streaming within a cooling dike. Where studied in southern Chile, aquagene tuffs and intrusive pillows decrease and water-lain pillows increase in relative abundance from north to south. This variation corresponds with a north-to-south decrease in both the relative volume of extrusives to extensional dikes and the range and volume of differentiated rocks, suggesting a southward increase in rate of extension relative to rate of magma supply within the spreading ridges at which the ophiolites formed. In the northern part of the original basin where the rate of extension was small relative to the rate of magma supply, magma remained in magma chambers longer, resulting in a greater range and volume of differentiated rocks. The larger volume of more differentiated, cooler and more viscous magmas, in conjunction with the likelihood of more violent eruption of volatile-rich differentiates, may have been responsible for the large volume of aquagene tuff in the northern part of the original basin. These observations in southern Chile suggest that ophiolites which contain a great abundance of aquagene tuffs and intrusive pillow lavas formed in tectonic environments in which the rate of extension was small relative to the rate of magma supply (island arcs, embryonic marginal basins). Ophiolites with predominantly water-lain pillowed and massive lavas formed in tectonic environments in which the rate of extension was large relative to the rate of magma supply (mid-ocean ridges, mature back-arc basins). Thus geologic field data may supplement geochemical data as a tool in distinguishing the original igneous-tectonic environments in which ophiolites originate.     

Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.     

TEM study of a special grain boundary in a synthetic K-feldspar bicrystal: Manebach Twin

 A monoclinic KAlSi₃O₈ feldspar Manebach twin boundary was synthesized by diffusion bonding and examined using high-resolution transmission electron microscopy. The sharp (001) twin boundary is straight and free of strain. The boundary width is smaller than d₀₀₁. There is no rigid body shift observed at the twin boundary, and the feldspar structure is arranged symmetrically across (001). The twin boundary structure consists of bridged tetrahedral crankshafts, which are characteristic of the feldspar lattice. The grain boundary structure is in good agreement with the geometrical model of Taylor et al. (1934). The grain boundary composition of K_1/2H_1/2AlSi₃O₈ differs from their model. Received: 13 February 2002 / Accepted: 24 December 2002 Acknowledgements We thank M. Rühle, S. Hutt, J. Mayer, A. Strecker and U. Salzberger at MPI, Stuttgart, for their support and valuable advice in preparing TEM sections of bicrystals.     

Inverse Analysis of Deep Excavation Using Differential Evolution Algorithm

This paper presents the applications of the differential evolution (DE) algorithm in back analysis of soil parameters for deep excavation problems. A computer code, named Python‐based DE, is developed and incorporated into the commercial finite element software ABAQUS, with a parallel computing technique to run an FE analysis for all trail vectors of one generation in DE in multiple cores of a cluster, which dramatically reduces the computational time. A synthetic case and a well‐instrumented real case, that is, the Taipei National Enterprise Center (TNEC) project, are used to demonstrate the capability of the proposed back‐analysis procedure. Results show that multiple soil parameters are well identified by back analysis using a DE optimization algorithm for highly nonlinear problems. For the synthetic excavation case, the back‐analyzed parameters are basically identical to the input parameters that are used to generate synthetic response of wall deflection. For the TNEC case with a total of nine parameters to be back analyzed, the relative errors of wall deflection for the last three stages are 2.2, 1.1, and 1.0%, respectively. Robustness of the back‐estimated parameters is further illustrated by a forward prediction. The wall deflection in the subsequent stages can be satisfactorily predicted using the back‐analyzed soil parameters at early stages. Copyright © 2014 John Wiley & Sons, Ltd.     

Coupled changes in sand grain size and sand transport driven by changes in the upstream supply of sand in the Colorado River: Relative importance of changes in bed-sand grain size and bed-sand area

Sand transport in the Colorado River in Marble and Grand canyons was naturally limited by the upstream supply of sand. Prior to the 1963 closure of Glen Canyon Dam, the river exhibited the following four effects of sand supply limitation: (1) hysteresis in sediment concentration, (2) hysteresis in sediment grain size coupled to the hysteresis in sediment concentration, (3) production of inversely graded flood deposits, and (4) development or modification of a lag between the time of a flood peak and the time of either maximum or minimum (depending on reach geometry) bed elevation. Construction and operation of the dam has enhanced the degree to which the first two of these four effects are evident, and has not affected the degree to which the last two effects of sand supply limitation are evident in the Colorado River in Marble and Grand canyons. The first three of the effects involve coupled changes in suspended-sand concentration and grain size that are controlled by changes in the upstream supply of sand. During tributary floods, sand on the bed of the Colorado River fines; this causes the suspended sand to fine and the suspended-sand concentration to increase, even when the discharge of water remains constant. Subsequently, the bed is winnowed of finer sand, the suspended sand coarsens, and the suspended-sand concentration decreases independently of discharge. Also associated with these changes in sand supply are changes in the fraction of the bed that is covered by sand. Thus, suspended-sand concentration in the Colorado River is likely regulated by both changes in the bed-sand grain size and changes in the bed-sand area. A physically based flow and suspended-sediment transport model is developed, tested, and applied to data from the Colorado River to evaluate the relative importance of changes in the bed-sand grain size and changes in the bed-sand area in regulating suspended-sand concentration. Although the model was developed using approximations for steady, uniform flow, and other simplifications that are not met in the Colorado River, the results nevertheless support the idea that changes in bed-sand grain size are much more important than changes in bed-sand area in regulating the concentration of suspended sand.     

Homology of solar flare-associated radio events

The concept of homology, introduced by Ellison, Mc Kenna, and Rceid (1960) for optical flares, can be extended to flare-associated radio events. Successive flares within the same centre of activity sometimes produce radio events that are remarkably similar. The similarity amounts to the fact that they extend over about the same range(s) in frequency, producing at each frequency responses of comparable intensity and duration. On some occasions the intensity curves at individual frequencies show even detailed resemblance. The occurrence of homologous radio events is commonly restricted to periods of less than 48 hours.Without being homologous, radio events that occur in the same centre of activity may present a common characteristic that is typical for that centre. Two such characteristics are (1) the production of radio responses at centimetric, decimetric and metric frequencies, and (2) the impulsiveness of microwave outbursts. The distribution of time intervals during which such bursts occur is compared with the same distribution for homologous events (Figure 3).