Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

A non-coherent surface backscattering model for radar observation of planetary bodies and its application to Cassini radar altimeter

Mission and hardware constraints make the Cassini radar altimeter working in the beam limited or pulse limited mode dependent on the radar operative mode (Low and High Resolution, respectively), but never allows work in a condition such that the pulsewidth limited circle is much smaller than the beamwidth limited circle. Unfortunately this latter condition is vital for the application of the so-called Brown model widely and successfully used in Earth (ocean) observation missions where the quoted condition is really met. In the paper a new model is discussed which is based on the same general hypotheses of the Brown model but is worked out by means of a different approach which makes it more general and independent of the specific operative conditions. An extension of the new model to take into account large mispointing angles is considered as well based on a series expansion of the Bessel function and on the analysis of the truncation error. Finally a comparison with the classical Brown model is discussed too.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.     

Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

HYDROLOGIC SERIES CHARACTERISTICSANALYSIS OF THE MAJOR RIVERS AROUNDTHE TAKLIMAKAN DESERT

I.IN~crIOXLocatedinthecoddlepatofTallmBasin,withanareaof33.76X104klnZ,theTaldirnakan~isinthehinterlandofEurasia.Blockedbythehighmountainsaround,vapourofoceancanhardlyreachthedesert.APartfromthis,asthedeSertisinthesinkingcompensationareaoftheascensionalaircurrentaamstheQinghal-XIZangPlateau,itSprecipitationisrareandtheevaporationcapacityisintensealltheyearround.Allthesecontributetotheformationsofthetypifydrydesertclimate.Theacidityindexofthedesertandthearoundregionisashighasmorethan50,w…     

Initial phase of chromospheric evaporation in a solar flare

In this paper we discuss the initial phase of chromospheric evaporation during a solar flare observed with instruments on the Solar Maximum Mission on May 21, 1980 at 20:53 UT. Images of the flaring region taken with the Hard X-Ray Imaging Spectrometer in the energy bands from 3.5 to 8 keV and from 16 to 30 keV show that early in the event both the soft and hard X-ray emissions are localized near the footpoints, while they are weaker from the rest of the flaring loop system. This implies that there is no evidence for heating taking place at the top of the loops, but energy is deposited mainly at their base. The spectral analysis of the soft X-ray emission detected with the Bent Crystal Spectrometer evidences an initial phase of the flare, before the impulsive increase in hard X-ray emission, during which most of the thermal plasma at 10⁷ K was moving toward the observer with a mean velocity of about 80 km s^-1. At this time the plasma was highly turbulent. In a second phase, in coincidence with the impulsive rise in hard X-ray emission during the major burst, high-velocity (370 km s^-1) upward motions were observed. At this time, soft X-rays were still predominantly emitted near the loop footpoints. The energy deposition in the chromosphere by electrons accelerated in the flare region to energies above 25 keV, at the onset of the high-velocity upflows, was of the order of 4 × 10¹⁰ erg s^-1 cm^-2. These observations provide further support for interpreting the plasma upflows as the mechanism responsible for the formation of the soft X-ray flare, identified with chromospheric evaporation. Early in the flare soft X-rays are mainly from evaporating material close to the footpoints, while the magnetically confined coronal region is at lower density. The site where upflows originate is identified with the base of the loop system. Moreover, we can conclude that evaporation occurred in two regimes: an initial slow evaporation, observed as a motion of most of the thermal plasma, followed by a high-speed evaporation lasting as long as the soft X-ray emission of the flare was increasing, that is as long as plasma accumulation was observed in corona.