济阳坳陷古近系区域层序地层格架地层特征对比

综合生物地层学、磁性地层学（ESR测年法）、地震地层学及层序地层学等地层学的研究成果,通过对断陷盆地区域等时界面的识别、界面级次和界面性质的分析与对比,以三级层序为基本组构单元建立了济阳坳陷古近系区域等时地层格架系统。通过分析济阳坳陷四大次级凹陷古近系各二级层序和隐蔽油气藏最为发育的重点三级层序的可对比性,认为二级层序完全受构造幕的直接控制,具有很好的可对比性。四个次级凹陷的重点三级层序地层格架的旋回性质具有一致性,标志性沉积物出现于相同或类似的旋回位置。然而,T2(沙一段底)、T4（沙三段上亚段底）和T6(沙三段中亚段底)的三级层序界面性质在不同凹陷间具有明显的差异性。从层序成因动力学角度来解释,这种旋回性质的相似性和界面性质的差异性分别表明了同一层序地层格架中沉积环境对沉积物类型起决定性的影响作用以及渤海湾盆地构造沉降沉积中心的迁移对层序界面性质所起的主要控制作用。     

陆相二叠一三叠系界线划分和事件

我国陆相二叠—三叠系界线的划分主要依据古脊椎动物,孢粉,双壳类、介形虫和古植物等.这些化石组合特征在界线附近都有明显的变化.这种变化不仅可以用来划分界线,而且结合在界线附近其它非生物（沉积物的粒度和颜色等）的异常变化,可以看出在二叠—三叠纪之交曾发生过某种事件.     

准噶尔盆地玛湖凹陷下二叠统风城组含碱层段韵律特征及成因*

准噶尔盆地玛湖凹陷早二叠世风城组沉积时期为典型的碳酸盐型咸化湖盆,湖盆咸化过程中析出大量的碱矿(钠碳酸盐类矿物)。通过含碱层段主量元素、碳氧同位素分析,结合岩心宏观及微观矿物岩石特征,探讨了含碱层段韵律特征及形成机理。研究层段碱矿与沉凝灰岩互层,形成明暗相间的咸化韵律。浅色碱矿层质地较纯,主要为苏打和小苏打,主量元素表现为 Na₂O含量高,CaO、MgO、SiO₂和Al₂O₃含量低;暗色层段主要为含斑点状碳钠钙石的沉凝灰岩,主量元素表现为Na₂O含量低,CaO、MgO、SiO₂和Al₂O₃含量高。浅色碱矿层和暗色沉凝灰岩段碳氧同位素值均为正,表明其沉积水体具高盐度特征。浅色含碱层段具有更高的 δ¹⁸O 值,反映了碱矿层沉积时期强烈蒸发的气候条件。根据δ¹⁸O/δ¹³C值的波动将研究层段划分为炎热干旱和相对湿润的气候条件,并据此解释不同韵律层盐类矿物形成机理。暗色的沉凝灰岩沉积代表地表流水注入量大于蒸发量,沉凝灰岩中盐类矿物含量少或者呈斑点状从颗粒间的卤水中析出;随着蒸发量的增高以及古气候由温暖潮湿转变为干旱炎热,地表流水注入量急剧减少,强烈蒸发控制了碱矿的沉积,形成浅色质地较纯的碱矿层。气候的频繁交替形成了风二段碱矿与沉凝灰岩频繁互层的特征。     

松辽盆地红岗油田白垩系青山口组含片钠铝石砂岩自生矿物共生序列

松辽盆地红岗油田白垩系青山口组发育含片钠铝石砂岩。通过偏光显微镜、扫描电镜、阴极发光 仪、Ｘ射线衍射等多种技术手段,对含片钠铝石砂岩的碎屑成分、胶结物类型及自生矿物共生序列等特征进行 了研究。该区含片钠铝石砂岩为岩屑长石砂岩及长石岩屑砂岩,胶结物有次生加大长石、次生加大石英、自生 石英微晶、黏土矿物、片钠铝石、方解石、铁方解石及铁白云石。方解石的形成分为两期,第１期方解石为原 始生物碎屑颗粒溶蚀溶解的产物,第２期方解石可能与ＣＯ^２ 充注后钙长石及早期碳酸盐矿物的溶蚀溶解有关。 含片钠铝石砂岩的自生矿物共生序列为：次生加大长石、早期次生加大石英-自生石英微晶-早期高岭石、第１ 期方解石、片钠铝石-晚期次生加大石英-晚期高岭石、第２期方解石、铁方解石、铁白云石。其中ＣＯ^２ 注入 后的矿物共生组合为：片钠铝石-晚期次生加大石英-晚期高岭石、第２期方解石、铁方解石、铁白云石。     

A Study of the Rhenium-Osmium Geochronometry of Molybdenites

This study deals with the first application of the isotope dilution - inductively coupled plasma mass spectrometry in the rhenium-osmium geochronometry in China. The chemical separation procedure included decomposition of samples by means of alkali fusion, extraction of rhenium by acetone and extraction of osmium by distillation. The recovery of both elements in the entire process was more than 90% . The blanks of analyses were 0.07 ng for rhenium and 0.01 ng for 187Os. The mineralization ages of molybdenites from four molybdenum deposits in China were determined by using this method, with a precision (2σ)of about ±3% . These results agree satisfactorily with their geological backgrounds. The Re-Os method can directly determine ages of metal deposits and reflect the true ages more reliably than other dating methods that only determine the ages of country rocks from which mineralization ages are inferred. As many hydrothermal sulphide deposits usually contain molybdenites, this method has bright prospe     

Re–Os geochronology of Cu and W–Mo deposits in the Balkhash metallogenic belt, Kazakhstan and its geological significance

The Central Asian metallogenic domain (CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-large porphyritic Cu–Mo deposits and some quartz vein- and greisen-type W–Mo deposits, is a well-known porphyritic Cu–Mo metallogenic belt in the CAMD. In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re–Os compositional analyses and Re–Os isotopic dating. Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W–Mo deposits—East Kounrad, Akshatau and Zhanet—all have relatively high Re contents (2712–2772 μg/g for Borly and 2.267–31.50 μg/g for the other three W–Mo deposits), and lower common Os contents (0.670–2.696 ng/g for Borly and 0.0051–0.056 ng/g for the other three). The molybdenites from the Borly porphyry Cu–Mo deposit and the East Kounrad, Zhanet, and Akshatau quartz vein- and greisen-type W–Mo deposits give average model Re–Os ages of 315.9 Ma, 298.0 Ma, 295.0 Ma, and 289.3 Ma respectively. Meanwhile, molybdenites from the East Kounrad, Zhanet, and Akshatau W–Mo deposits give a Re–Os isochron age of 297.9 Ma, with an MSWD value of 0.97. Re–Os dating of the molybdenites indicates that Cu–W–Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian (315.9–289.3 Ma), while the porphyry Cu–Mo deposits formed at 316 Ma, and the quartz vein-greisen W–Mo deposits formed at 298 Ma. The Re–Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement. Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China, the formation of the Cu–Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively, the large-scale Late Carboniferous porphyry Cu–Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

振动沉管灌注桩缩径原因的分析及预防

通过对镇江开发区某工程振动沉管桩基础施工方法的总结,系统地论述了沉管灌注桩施工中发生缩径的原因,提出了预防措施。     

毛细管离子电泳分离间接紫外光度法测定镍矿石中镍钴铜

研究了以咪唑为背景吸收电解质,α羟基异丁酸为络合剂,毛细管离子电泳分离,间接紫外光度法测定镍矿石中Ｎｉ、Ｃｏ、Ｃｕ含量。考察了背景电解质的ｐＨ值、α羟基异丁酸（αＨＩＢＡ）和咪唑浓度对Ｆｅ３＋、Ｃｏ２＋、Ｎｉ２＋、Ｚｎ２＋、Ｃｕ２＋分离的影响。在优化的条件下,几种离子在８ｍｉｎ内完成分离,检测限低至０．２ｍｇ／Ｌ。以Ｚｎ作内标,改善了方法的精密度,对于２０ｍｇ／Ｌ各离子峰面积的相对标准偏差（ＲＳＤ,ｎ＝９）＜６．５％。采用内标标准曲线法对镍矿样中Ｎｉ、Ｃｏ、Ｃｕ的含量进行了测定,线性范围分别在０．５～８０ｍｇ／ＬＮｉ２＋和Ｃｏ２＋,５～８０ｍｇ／ＬＣｕ２＋,结果与其它方法一致。     

大别山超高压正片麻岩：岩石学及变质演化

大别山超高压片麻岩与正常（中低压）片麻岩呈互层状产生，原岩相当于安山质火山岩。超高压片麻岩的特征矿物组合为石榴子石＋绿辉石＋多硅白云母＋斜黝帘石＋石英／柯石英＋金红石±蓝晶石±纳云母，高压矿物包体、冠状反应结构、假象结构和局部不平衡结构可作为其岩相学鉴别标志。它们经历了与含柯石英榴辉岩可对比的超高压变质（＞2．7GPa、672～725℃）和中低压绿帘角闪岩相退变质（0．3～0．7GPa、450～520℃）两个主要演化阶段，其退变质作用与围岩区域变质作用的一致性有可能说明二者自始至终经历了同一演化过程。