安徽铜陵凤凰山夕卡岩型铜矿床中辉钼矿Re-Os同位素年龄及其地质意义

铜陵矿集区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的有色金属基地之一,凤凰山矿床是铜陵矿集区的重要组成部分,为一个典型的夕卡岩型铜矿床。本文利用Re-Os同位素定年方法对凤凰山铜矿床进行了成矿时代测定,获得了辉钼矿的Re-Os同位素模式年龄范围为139.1±2.4～142.0±2.2Ma,等时线年龄为141.1±1.4Ma,与矿区内石英二长闪长岩和花岗闪长岩SHRIMP锆石U-Pb年龄(144.2±2.3Ma)相吻合,也与铜陵地区其他矿田的成矿时代基本一致,可能为岩石圈减薄事件的成矿响应。     

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

Distribution characteristics of delta reservoirs reshaped by bottom currents: A case study from the second member of the Yinggehai Formation in the DF1-1 gas field,Yinggehai Basin,South China Sea

The Dongfang1-1 gas field (DF1-1) in the Yinggehai Basin is currently the largest offshore self-developed gas field in China and is rich in oil and gas resources. The second member of the Pliocene Yinggehai Formation (YGHF) is the main gas-producing formation and is composed of various sedimentary types; however, a clear understanding of the sedimentary types and development patterns is lacking. Here, typical lithofacies, logging facies and seismic facies types and characteristics of the YGHF are identified based on high-precision 3D seismic data combined with drilling, logging, analysis and testing data. Based on 3D seismic interpretation and attribute analysis, the origin of high-amplitude reflections is clarified, and the main types and evolution characteristics of sedimentary facies are identified. Taking gas formation upper II (IIU) as an example, the plane distribution of the delta front and bottom current channel is determined; finally, a comprehensive sedimentary model of the YGHF second member is established. This second member is a shallowly buried “bright spot” gas reservoir with weak compaction. The velocity of sandstone is slightly lower than that of mudstone, and the reflection has medium amplitude when there is no gas. The velocity of sandstone decreases considerably after gas accumulation, resulting in an increase in the wave impedance difference and high-amplitude (bright spot) reflection between sandstone and mudstone; the range of high amplitudes is consistent with that of gas-bearing traps. The distribution of gas reservoirs is obviously controlled by dome-shaped diapir structural traps, and diapir faults are channels through which natural gas from underlying Miocene source rocks can enter traps. The study area is a delta front deposit developed on a shallow sea shelf. The lithologies of the reservoir are mainly composed of very fine sand and coarse silt, and a variety of sedimentary structural types reflect a shallow sea delta environment; upward thickening funnel type, strong toothed bell type and toothed funnel type logging facies are developed. In total, 4 stages of delta front sand bodies (corresponding to progradational reflection seismic facies) derived from the Red River and Blue River in Vietnam have developed in the second member of the YGHF; these sand bodies are dated to 1.5 Ma and correspond to four gas formations. During sedimentation, many bottom current channels (corresponding to channel fill seismic facies) formed, which interacted with the superposed progradational reflections. When the provenance supply was strong in the northwest, the area was dominated by a large set of delta front deposits. In the period of relative sea level rise, surface bottom currents parallel to the coastline were dominant, and undercutting erosion was obvious, forming multistage superimposed erosion troughs. Three large bottom current channels that developed in the late sedimentary period of gas formation IIU are the most typical.     

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The distribution of chlorophyll a and its influencing factors in different regions of the Bering Sea

The distribution of chlorophyll a(Chl a) and its relationships with physical and chemical parameters in different regions of the Bering Sea were discussed in July 2010. The results showed the seawater column Chl a concentrations were 13.41–553.89 mg/m2 and the average value was 118.15 mg/m2 in the study areas. The horizontal distribution of Chl a varied remarkably from basin to shelf in the Bering Sea. The regional order of Chl a concentrations from low to high was basin, slope, outer shelf, inner shelf, and middle shelf. The vertical distribution of Chl a was grouped mainly from single-peak type in basin, slope, outer shelf, and middle shelf, where the deep Chl a maxima(DCM) layer was observed at 25–50 m, 30–35 m, 36–44 m, and 37–47 m, respectively. The vertical distribution of Chl a mainly had three basic patterns: standard single-peak type, surface maximum type, and bottom maximum type in the inner shelf. The analysis also showed that the transportation of ocean currents may control the distribution of Chl a, and the effects were not simple in the basin of the Bering Sea. There was a positive correlation between Chl a and temperature, but no significant correlation between Chl a and nutrients. The Bering Sea slope was an area deeply influenced by slope current. Silicate was the factor that controlled the distribution of Chl a within parts of the water in the slope. Light intensity was an important environmental factor in controlling seawater column Chl a in the shelf, where Chl a was limited by nitrate rather than phosphate within the upper water. Meanwhile, there was a positive relationship between Chl a and salinity. Algal blooms broke out at Sta. B6 of the southwestern St. Lawrence Island and Stas F6 and F11 in the middle of the Bering Strait.     

ENSO indices from sea surface salinity observed by Aquarius and Argo

Analysis of the first 26 months of data from the Aquarius satellite confirms the existence of a sharp sea surface salinity (SSS) front along the equator in the western equatorial Pacific. Following several earlier studies, we use the longitudinal location of the 34.8-psu isohaline as an index, termed Niño-S34.8, to measure the zonal displacement of the SSS front and consequently the eastern edge of the western Pacific warm pool. The on-going collection of the Array for Real-time Geostrophic Oceanography (ARGO) program data shows high correlations between Niño-S34.8 and the existing indices of El Niño, suggesting its potential important role in ENSO evolution. Further analysis of the ARGO data reveals that SSS variability in the southeastern tropical Pacific is crucial to identify the type of El Niño. A new SSS index, termed the southeastern Pacific SSS index (SEPSI), is defined based on the SSS variability in the region (0°–10°S, 150°–90°W). The SEPSI is highly correlated with the El Niño Modoki index, as well as the Trans-Niño index, introduced by previous studies. It has large positive anomalies during central Pacific El Niño or El Niño Modoki events, as a result of enhanced zonal sea surface temperature gradients between the central and eastern tropical Pacific, and can be used to characterize the type of El Niño. The processes that possibly control these SSS indices are also discussed.     

黑龙江七星河含煤盆地古近纪-新近纪沉积相及层序地层特征

黑龙江省东部七星河盆地是一新生代聚煤盆地,其含煤地层为古近系宝泉岭组、新近系富锦组。宝泉岭组由各级砂岩、泥岩、炭质泥岩以及褐煤组成,发育滨浅湖相、深-半深湖相、三角洲平原相,属于湖泊沉积体系、三角洲沉积体系。富锦组主要由泥岩、粉砂岩、中砂岩、含砾粗砂岩及煤层、炭质泥岩、硅藻岩组成,发育滨浅湖相、扇三角洲平原相,分别属于湖泊沉积体系和扇三角洲沉积体系。层序SI相当于宝泉岭组,发育低位体系域、湖侵体系域和高位体系域,煤层主要发育高位体系域中后期,成煤环境以滨浅湖淤积沼泽为主。层序SII相当于富锦组,主要发育湖侵体系域、高位体系域,局部地区发育低位体系域,煤层亦主要发育高位体系域中后期,成煤环境以扇三角洲淤积沼泽和滨浅湖淤积沼泽为主。层序SI、SII的高位体系域中后期,盆地基底沉降速率和物源供给处于相对平衡状态,主要发育了扇三角洲淤积沼泽、滨浅湖和滨浅湖淤积沼泽环境,发育可采煤层。     

Geological characteristics and tectonic signifcance of unconformities in Mesoproterozoic successions in the northern margin of the North China Block

Several stratigraphic breaks and unconformities exist in the Mesoproterozoic successions in the northern margin of the North China Block.Geologic characters and spatial distributions of fve of these unconformities,which have resulted from different geological processes,have been studied.The unconformity beneath the Dahongyu Formation is interpreted as a breakup unconformity,representing the time of transition from continental rift to passive continental margin.The unconformities beneath the Gaoyuzhuang and the Yangzhuang formations are considered to be the consequence of regional eustatic fuctuations,leading to the exposure of highlands in passive margins during low sea-level stands and transgressive deposition on coastal regions during high sea-level stands.The unconformity atop the Tieling Formation might be caused by uplift due to contractional deformation in a back-arc setting,whereas the uplift after the deposition of the Xiamaling Formation might be attributed to a continental collision event.It is assumed that the occurrences of these unconformities in the Mesoproterozoic successions in the northern margin of the North China Block had a close bearing on the assemblage and breakup of the Columbia and Rodinia supercontinents.     

Re–Os isotope and platinum-group element geochemistry of the Pobei Ni–Cu sulfide-bearing mafic–ultramafic complex in the northeastern part of the Tarim Craton

A number of mafic–ultramafic intrusions that host Ni–Cu sulfide mineralization occur in the northeastern Tarim Craton and the eastern Tianshan Orogenic Belt (NW China). The sulfide-mineralized Pobei mafic–ultramafic complex is located in the northeastern part of the Tarim Craton. The complex is composed of gabbro and olivine gabbro, cut by dunite, wehrlite, and melatroctolite of the Poyi and Poshi intrusions. Disseminated Ni–Cu sulfide mineralization is present towards the base of the ultramafic bodies. The sulfide mineralization is typically low grade (<0.5 wt.% Ni and <2 wt.% S) with low platinum-group element (PGE) concentrations (<24.5 ppb Pt and <69 ppb Pd); the abundance of Cu in 100 % sulfide is 1–8 wt.%, and Ni abundance in 100 % sulfide is typically >4 wt.%. Samples from the Pobei complex have εNd (at 280 Ma) values up to +8.1, consistent with the derivation of the magma from an asthenospheric mantle source. Fo 89.5 mol.% olivine from the ultramafic bodies is consistent with a primitive parental magma. Sulfide-bearing dunite and wehrlite have high Cu/Pd ratios ranging from 24,000 to 218,000, indicating a magma that evolved under conditions of sulfide saturation. The grades of Ni, Cu, and PGE in 100 % sulfide show a strong positive correlation. A model for these variations is proposed where the mantle source of the Pobei magma retained ~0.033 wt.% sulfide during the production of a PGE-depleted parental magma. The parental magma migrated from the mantle to the crust and underwent further S saturation to generate the observed mineralization along with its high Cu/Pd ratio at an R-factor varying from 100 to 1,200. The mineralization at Poshi and Poyi has very high γOs (at 280 Ma) values (+30 to +292) that are negatively correlated with the abundance of Os in 100 % sulfide (5.81–271 ppb) and positively correlated with the Re/Os ratios; this indicates that sulfide saturation was triggered by the assimilation of crustal sulfide with both high γOs and Re/Os ratios. When compared to other Permian mafic–ultramafic intrusions with sulfide mineralization in the East Tianshan, the Poyi and Poshi ultramafic bodies were formed from more primitive magmas, and this helps to explain why the sulfide mineralization has high Ni tenor.     

Analysis of the microclimate and CO2 flux characteristics in arid desert wetland ecosystem in summer: A case study in Xihu desert wetland,Dunhuang, China

Xihu desert wetland is an important and unusual environment in China or even in the world. However, until now, little research has been focused on the microclimate and CO₂ flux characteristics in this area. This paper reports the characteristics of daily variations of microclimate and CO₂ flux in the Dunhuang Xihu desert wetland, based on data observed in the desert wetland during a period of continuous fine weather in summer 2012. Results indicate that the characteristics of the micrometeorology were significantly affected by the land–lake breeze during the study period, and updrafts were prevalent in this region. The friction wind speed and the vertical velocity were much greater than those in the Maqu grasslands. The energy budget was strongly imbalanced: the latent heat flux was significantly higher than the sensible flux. The daily mean values of total solar radiation and net radiation were larger than those in Maqu grasslands and Jinta oasis. There was a temperature inversion and inverse humidity gradient in the atmospheric surface layer at night. The desert wetland ecosystem was a carbon sink during the whole of the observation period, and the maximum rate of carbon absorption usually occurred at about 11:00 hr each day in this region.