底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。     

黑河下游河岸林植物水分来源初步研究

通过分析黑河下游极端干旱区荒漠河岸林植物木质部水及其不同潜在水源稳定氧同位素组成(δ18O),应用"同位素质量守恒多元"分析方法初步研究了不同潜在水源对河岸林植物的贡献.结果表明:在黑河下游荒漠河岸林生态系统,在河水转化为地下水和土壤水及水分在土壤剖面再分配的过程中均存在强烈的同位素分馏.对植物水δ18O而言,胡杨、柽柳和苦豆子的δ18O分别为-6.43‰、-6.28‰～和-6.61‰,较苦苣菜(-5.14‰)和蒲公英(-5·52‰)明显偏负.柱状频率图显示胡杨最多能利用93%的地下水,柽柳最多利用90%的地下水.而苦豆子97%水分来源于80 cm土层范围内的土壤水.除0～20 cm土层内的土壤水外,苦苣菜和蒲公英可能还有其他潜在水源.即在黑河下游天然河岸林乔木和灌木较多地利用地下水,而草本植物仍然以地表水为主.     

Difference-frequency ultrasound generation from microbubbles under dual-frequency excitation

The difference-frequency (DF) ultrasound generated by using parametric effect promises to improve detection depth owing to its low attenuation, which is beneficial for deep tissue imaging. With ultrasound contrast agents infusion, the harmonic components scattered from the microbubbles, including DF, can be generated due to the nonlinear vibration. A theoretical study on the DF generation from microbubbles under the dual-frequency excitation is proposed in formula based on the solution of the RPNNP equation. The optimisation of the DF generation is discussed associated with the applied acoustic pressure, frequency, and the microbubble size. Experiments are performed to validate the theoretical predictions by using a dual-frequency signal to excite microbubbles. Both the numerical and experimental results demonstrate that the optimised DF ultrasound can be achieved as the difference frequency is close to the resonance frequency of the microbubble and improve the contrast-to-tissue ratio in imaging.     

1997—2017年塔克拉玛干沙漠腹地降水特征

利用塔克拉玛干沙漠腹地塔中气象站1997—2017年逐日和逐时降水资料,分析塔克拉玛干沙漠腹地降水日变化特征、极端强降水特征及其天气背景。结果表明：1997—2017年研究区降水量呈增加趋势、降水日数呈减少趋势,大雨雨量和雨日明显增加,降水呈增强演变。降水多见于6月,最大雨强为8.4 mm·h^-1。降水量日变化呈多峰特征,降水量最大值出现在23：00,06：00是降水频次最多时刻。降水强度和降水频次对降水量作用不同,午后至前半夜强度大,频次少;而后半夜至清晨频次多,强度小。降水以短历时降水为主,其中1～3 h的短历时降水对总降水量贡献率高达61.76%。日降水和小时降水的99百分位强度阈值分别为15.3 mm·d^-1和6.0 mm·h^-1,大于90百分位极端降水量占总降水量贡献率近半。极端强降水天气发生在南疆盆地受北纬40°以南低槽、切变槽或弱的气旋式风场控制地区,南疆盆地提前增湿,民丰850 hPa比湿接近或超过10 g·kg^-1的背景下,降水连续性较差,多中小尺度引发局地短时降水。     

徐闻南山镇红树林沉积物及红树植物中重金属的累积特征与迁移规律

为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律,选取了徐闻南山镇红树林为研究对象,通过测定红树林沉积物及红树植物不同部位（根、茎、叶）的重金属质量分数,运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明：1）红树林沉积物重金属质量分数表现为铬（Cr）＞锌（Zn）＞镍（Ni）＞铜（Cu）＞铅（Pb）＞砷（As）＞汞（Hg）＞镉（Cd）,为中等变异程度;除了镍（Ni）元素外,其余7种重金属未超过国家一级标准,除了铅（Pb）元素外,其余7种重金属均超过广东省土壤环境背景值,说明研究区沉积物中重金属具有一定的积累效应。2）沉积物中砷（As）、铜（Cu）、锌（Zn）、汞（Hg）、镍（Ni）、铬（Cr）富集因子值均＞1.5,说明受到轻微人为活动影响;各站位镍（Ni）富集因子值均＞5,结合研究区背景,反映了镍（Ni）受到自然和人为输入的共同影响。3）白骨壤体内重金属主要集中在根部,而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄,说明白骨壤对重金属的吸附能力比红海榄强。汞（Hg）集中分布在植物的叶片部位,且与其他重金属之间相关性不明显;推测汞（Hg）主要通过叶片吸收进入植物体内,与交通运输污染有关。4）不同红树植物对不同重金属富集能力各异,白骨壤对重金属的富集能力表现为：镉（Cd）＞砷（As）＞铜（Cu）＞锌（Zn）＞汞（Hg）＞铅（Pb）＞镍（Ni）＞铬（Cr）,红海榄表现为：镉（Cd）＞铜（Cu）＞汞（Hg）＞锌（Zn）＞铅（Pb）＞砷（As）＞镍（Ni）＞铬（Cr）。白骨壤和红海榄对汞（Hg）的运移能力都较强;红海榄对镉（Cd）的富集能力和转运能力都较强,而白骨壤对镉（Cd）富集能力较强,转运能力却较弱,这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。     

福建省复杂地形下旬平均气温分布式模拟

为建立高时空分辨率的福建省复杂地形下气温栅格数据集,利用福建省及其周边33个常规气象站观测资料,基于数字高程模型（DEM）数据,综合考虑海拔、太阳总辐射、地表长波有效辐射对旬平均气温的影响,模拟了福建省复杂地形下旬均温的空间分布。结果表明：1）常规站验证结果显示：各旬气温绝对误差平均值（MAE）最小为0.46℃,最大为2.3℃,全年平均为0.87℃;加密站验证结果显示,MAE最大为2.3℃,最小0.5℃,全年平均为0.96℃。2）模拟结果能反映旬均温的宏观分布规律与局地细节特征。宏观范围内,旬均温受纬度影响较大,由北至南气温逐渐升高,沿海地区旬均温整体高于内陆,山区旬均温明显较低;局地范围内,各坡向上气温差异显著,海拔越高、坡度越大,差异越明显;地形因子对旬平均温的影响具有季节差异,具体表现为冬季时地形因子对旬均温的影响最大,秋季次之,春夏季节中地形因子对旬均温的影响最弱。     

山东乳山英格庄金矿床地质特征及成因浅析

英格庄金矿为胶东牟平-乳山成矿带上的一个中型金矿床。该矿床矿体严格受金牛山断裂带控制,呈脉状、透镜状和囊状平行斜列式产出;矿体平均厚1．58～1．98m,平均品位3．96×10^-6～4．77×10^-6。矿石类型主要为黄铁矿石英脉型;矿石中金属矿物主要为银金矿、自然金、黄铁矿等。围岩蚀变包括绢云母化、硅化、绿泥石化、黄铁矿化等。研究表明,英格庄金矿床为一中低温热液脉型金矿,属Groves等提出的造山型金矿范畴。     

Challenges in developing China's marine protected area system

Since the 1980s, there have been continuous increases in the coverage of marine protected areas (MPAs) in China, and a total of 158 MPAs have been declared. The MPA system in China is characterized by (1) decentralised designation and management with reduced control from the central government; (2) a dominance of de jure fully protected MPAs that are often implemented as de facto multiple-use areas; and (3) a lack of objective evaluation processes. To improve China's MPA system requires an appropriate integration of fully protected and multiple-use MPAs, and an approach that balances the advantages of top-down and bottom-up approaches.     

Decomposition analysis on direct material input and dematerialization of mining cities in Northeast China

Material dematerialization is a basic approach to reduce the pressure on the resources and environment and to realize the sustainable development. The material flow analysis and decomposition method are used to calculate the direct material input (DMI) of 14 typical mining cities in Northeast China in 1995-2004 and to analyze the demateri-alization and its driving factors in the different types of mining cities oriented by coal, petroleum, metallurgy and multi-resources. The results are as follows: 1) from 1995 to 2006, the increase rates of the DMI and the material input intensity of mining cities declined following the order of multi-resources, metallurgy, coal, and petroleum cities, and the material utilizing efficiency did following the order of petroleum, coal, metallurgy, and multi-resources cities; 2) during the research period, all the kinds of mining cities were in the situation of weak sustainable development in most years; 3) the pressure on resources and environment in the multi-resources cities was the most serious; 4) the petro-leum cities showed the strong trend of sustainable development; and 5) in recent years, the driving function of eco-nomic development for material consuming has continuously strengthened and the controlling function of material utilizing efficiency for it has weakened. The key approaches to promote the development of circular economy of min-ing cities in Northeast China are put forward in the following aspects: 1) to strengthen the research and development of the technique of resources' cycling utilization, 2) to improve the utilizing efficiency of resources, and 3) to carry out the auditing system of resources utilization.     

长营岭—龙门冲原生晕异常及找矿预测

通过对珊瑚矿田长营岭－龙门冲地区岩石地球化学测量,圈定了该区Ｗ、Ｓｎ、Ｃｕ、Ｚｎ、Ａｓ、Ｂ、Ｆ等元素异常,原生晕严格受ＮＥ和ＮＷ两组断裂控制。综合评价认为处于长营岭钨锡矿带南延带的南风井多元素组合异常是矿异常,该异常明显地受ＮＥ（Ｆ９）断裂和ＮＷ（Ｆ１０）断裂控制,浓集中心位于Ｆ９断裂下盘,与长营岭矿区矿体在ＮＷ断裂下盘富集的规律相同。测区内,异常形态与北区具连续性,异常强度弱于北区,组分分带显示以隐伏花岗岩为成矿中心,但沿矿带由ＮＥ到ＳＷ并无明显的组分分带和元素组合变化,矿田内不仅矿带南延并向ＳＷ方向倾伏,而且很有可能深部隐伏花岗岩体亦分枝向南延伸。