黄铁矿表面及其与Au（HS）2^—溶液作用的STM研究

本文用ＳＴＭ研究了黄铁矿和方铅矿表面的原子结构、纳米级微形貌、电子态分布及其吸附态的特点。ＳＴＭ电流图象揭示了表面缺陷与表面电子态之间的对应关系，硫化和的表面的化学反应活性可能是表现缺陷引起的局域导电性增强有关。ＳＴＭ观察进一步表明黄铁矿和方铅矿对金的硫氢配合物的吸附作用优先发生于扭折位和台阶边缘等高能部位，反映出吸附态的分布也是与表面电子态分布相对应的。这样就从微观领域考证了硫化物表面对化学活性     

High Pressure-Differential Thermal Analysis and Ultrasonic Wave Amplitude Analysis of Ice-Water Equilibrium at 1.5-5.0GPa

Water is the most active component in all geological systems.It has an important effect on the physical properties of minerals and melts.It also plays a key role in the evolution of the Earth.Accurate thermodynamics data on water are currently confined to pressures below 1.0GPa and temperatures below 900℃.Presented in this paper are new data available on the P-T properties of water at pressures up to 5.0GPa,develoged from differential thermal analysis and ultrasonic wave amplitude analysis.It has been found that there may exist another ternary point at 3.0GPa and that ultrasonic wave amplitude change of ice-water transition shows two inflection points above 2.0GPa, consistent with the two peaks of differential thermal curves above 2.0GPa .It may be a new phenomenon which needs further study.     

0.25—3.75GPa和20—370℃条件下0.025molNaCl溶液电导率研究

在０．２５－３．７５ＧＰａ和２０－３７０℃条件下测量了ＮａＣｌ溶液的电导率。结果表明（１）电导率随温度增高而增大，且电导率的对数与温度的倒数为线性关系，但不同压力不其斜率不同。（２）电导率与压力的 关系较为复杂，存在着不连续性。即在２．２５－３．３７ＧＰａ压力范围，电导率随压力增大而增大；在１．２５－２．００ＧＰａ压力范围，电导率与压力几乎无关；０．７５ＧＰａ压力的电导率高于相邻力的电导率。上述。     

瑶沟等地区勘查金矿的放射性和非放射性气体地球化学方法的研究

本文介绍了瑶沟等地区勘查金矿的放射性和非放射性气体地球化学方法的研究成果：基本查明了应用本方法勘查金矿的主要条件是金矿中伴生有足够的Ｕ，Ｈｇ和碳酸盐矿物；研制成了壤中气（Ｒｎ－ＣＯ２）联测技术，提高了测量质量和探测深部矿体的能力；利用壤中气（Ｒｎ－ＣＯ２）异常进行了成矿预测，并已获得成功。     

Conductivity of NaCl solution at 0.4–5.0 GPa and 25–500 °C

NaCI-H₂O is the most fundamental ternary system in geology. Until now, the measurements of electrical conductivity of NaCl solutions are still little at high pressures (> O.5 GPa) We measured the conductivity of 0.01 m NaCl solution at 0.4–5.0 GPa and 25-500°C. The results are consistent with that of Quist and Marshall (1968) at 0.4 GPa. The conductivity of NaCl solution increases with increasing temperature. The results also show that the conductivity of NaCl solution changes little with increasing pressure below 1.5 GPa and changes rapidly with increasing pressure above 1.5 GPa. The rapid increase of the conductivity of NaCl solution may play an important role in many geological processes (such as the genesis of ore deposits under hydrothermal condition) and other fields. Project supported by the National Natural Science Foundation of China.     

Properties of wave velocity for two types of granitoids at high pressure and temperature and their geological meaning

The wave velocity for two types of granitoids was measured using the analytic method of full-wave vibration at high pressure and high temperature. The laws of velocity changes for them differ with the pressure boost and temperature rise, and the velocity change of S-type is more violent than that of I-type. The “softening point” of compressional wave velocity (V μ) is also revealed during the measurement for two types of granitoids imitating the pressure and temperature at a certain depth. But the depth of “softening”, V_p after “softening” and the percentage of V_p’s drop around the “sofrening point” for two types of granitoids are obviously different. The depth of “softening” is 15 km approximately and V_p after “softening” is 5.62 km/s for S-type granitoid. But for I-type granitoid the depth of “softening” is 26 km approximately and V_p after “softening” is 6. 08 km/s. Through careful analysis of rock slices after the experiment, it was found that the “softening” of elastic-wave velocity is caused by the partial melting of granite. Combined with the results of geophysical prospecting, these results suggest that the low-velocity layers developing in the interior of Earth crust are related to thc partial melting of different types of granitoids. The formation of the low-velocity layer in the upper-middle Earth crust is closely related to the development of S-type granitoid, but that in the lower Earth crust is closely related to the development of I-type granitoid.     

东风山前寒武纪含铁建造金矿床中的稀土元素

东风山含铁建造金矿床中稀土元素含量普遍较低。东风山群是含矿层,其不同层位岩石和矿物的稀土含量有所差别。大理岩和含铁层中铁闪石的稀土含量最低,甚至低于稀土地壳丰度;上部角岩、下部角岩和石榴子石中稀土含量近似其他壳丰度;而板岩和花岗岩中稀土含量远高于其他壳丰度。稀土元素分布的特点反映了东风山金矿床形成于一个半封闭和较还原的海盆地,金矿化是在弱碱性条件下产生。黄铁矿中出现独居石类矿物,这可能与陆壳重熔改造形成花岗岩时产生的局部富轻稀土热液沿黄铁矿裂隙渗入有关。     

蚀变岩中物质迁移的定量计算：以锡矿山锑矿床为例

本文提出了确定沉积岩蚀变作用过程中的不活动组分的方法，并以锡矿山锑矿床为例，定量计算了蚀变岩中各组分的带入带出量，研究表明：锡矿山锑矿硅化过程中ＴｉＯ２和Ａｌ２Ｏ３为不活动组；ＳｉＯ２，Ｋ２Ｏ，Ｎａ２Ｏ及锑，硫，坤，汞，铅和钡为带入组分；而ＣａＯ，ＭｇＯ，Ｆｅ２Ｏ３，ＭｎＯ及铜，锌为带出组分，锑，钡，硫，ＳｉＯ２和ＣａＯ有较大的带进或带出量，锡矿山锑矿床矿石矿物为单一辉锑矿可能是由于矿液中缺少其它     

从层序地层学研究试论华北地区寒武系与奥陶系分界

华北地区寒武系－奥陶系过渡沉积可划分为三个层序：凤山层序、两河口－红花园层序和大湾层序，凤山层序与两河口－红花园层序之间的界面为Ⅱ型层序界面（ＳＢ２），而两河口－红花园层序与大湾层序之间的界面为Ｉ型层序界面（ＳＢ１）。华北地区寒武系－奥陶系界线应置于两河口－红花园层序的海侵体系域的下界面，在徐州地区为三山子组（狭义）与韩家组之间，在北京西山为韭园组微晶丘与冶里组之间。     

面向未来的海面变化研究

长期以来以地质时期海面变化过程等理论性研究为主要方向的海面变化研究经过７０年代在观念、方法和资料积累方面的突破，自８０年代初期以来进入了以“面向未来”为基调的成熟发展的新阶段，出现了一大批关于未来海面变化幅度及其影响和对策的研究成果，形成了较为完整的研究体系。９０年代初以来的几年间，世界海面研究的活跃领域是地质历史时期（例如ＬＧＭ，５ｅ等阶段）的海面实况、极地冰原对气候变化的反应、海面控制原理、海面模型以及绝对海面的航天测量技术与应用等方面。这一情况在一定程度上体现了“预测热”之后的“冷思考”。中国海面变化研究近年来取得了令世人瞩目的迅速发展，今后应注意引进先进技术方法，加强学科间的交叉合作，发掘自身的优势，向纵深发展