Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

Glauconites from the Late Palaeocene — Early Eocene Naredi Formation,western Kutch and their genetic implications

Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin. In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western Kutch.     

西昆仑落石沟一带铅锌矿成矿规律与找矿前景

西昆仑落石沟矿带是新疆西南部重要的成矿区带,落石沟矿带已发现铁、铜、铅锌矿(床)点13处,成矿潜力巨大。文章在综合前人工作成果的基础上,就区域内铅锌矿的分布规律、成矿地质背景、矿床地质特征、区域物化探异常特征、成矿模式、控矿因素等方面进行了介绍,重点以宝塔山、多宝山铅锌矿作为典型矿床对其成矿特征进行了分析和对比,指出西昆仑落石沟一带为寻找MVT型(碳酸盐岩容矿型)铅锌矿的有利地区,初步总结了该成矿带铅锌矿的控矿规律,确定了区域预测要素,提出了找矿有利地区。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

去除EOS/MODIS 1B数据中"弯弓"效应的方法

分析了中分辨率成像光谱仪EOS／MODIS的扫描方式,在此基础上研究了EOS／MODIS1B数据集“弯弓”效应的成因。对EOS／MODIS1B数据02级产品HDF文件的格式进行了探讨,并以250m分辨率资料为例,在2002年7月13日10时的MODIS资料中选取鄱阳湖以北部分地区,读取其数据进行插值、Lambert投影、重采样等处理,从而消除了影响资料使用的“弯弓”效应,同时也完成了对EOS／MODIS数据的几何校正,取得了一定的效果,为EOS／MODIS遥感资料在今后得以广泛应用作了有益的尝试。     

华北及其邻区块体转动模式和动力来源

块体的转动是地壳中重要的构造运动形式。根据地质、地球物理和地震活动性等资料，可将华北及其邻区划分为３个亚板块，华北亚板块可进一步细分为多个级块体，这些不同级别的块体或多或少都显示出一定的刚体特性。根据地质构造、地震和古地磁测量等资料，详细地论细地论述了不同级块体的转动问题，即华北及其邻区的黑龙江、华北和华南等３个近东西向亚板块自老第三纪以来相对于新疆地区顺时针转动了１．６°～３．５°；华北亚板块内     

武汉市宝通寺地铁站基坑工程监测与分析

介绍了武汉市轨道交通二号线一期工程第20标段宝通寺地铁车站基坑工程的支护设计和监测方案,并对监测结果中基坑周围岩土体侧向水平位移和内支撑轴力进行了初步分析。监测结果表明：土层和岩层在基坑开挖过程中的侧向水平变形程度相差较大,且不同状态的土层侧向水平变形程度亦不相同;由于土层相对于岩层侧向变形较大,其支护时所表现出来的内支撑轴力亦比较大。因此,对于不同地层,进行基坑支护方案选择时应根据其不同变形性质进行合理的优化设计,对土层和岩层可采取不同的支护形式,以到达既安全又经济的目的。     

北祁连加里东造山带从挤压到伸展造山机制的转换

早古生代早期，北祁连造山带发生强烈的挤压变形作用，形成加里东期的俯冲－增生杂岩、高压变质岩，并使造山带岩石圈地壳加厚缩短。志留纪末期，加厚的造山带岩石圈由于垮塌作用及根部的拆沉作用，使造山带从挤压造山机制转换为伸展造山机制，并进入后造山伸展作用阶段，增厚的岩石圈开始减薄，发生不同层次的伸展作用，同时伴随花岗岩及Ａｎ∈变质岩的穹隆以及泥盆纪磨拉石盆地上叠盆地（Ｃ－Ｔ）的形成。石炭纪末，北祁连造山带岩石圈地壳已基本减薄到正常厚度。而现今的北祁连造山带的缩短和抬升则为喜马拉雅期再造山作用的产物     

冬春季切变类冰雹发生条件的对比分析

本文以 1996年 12月 31日和 1981年 5月 1日为例 ,对冬、春季节发生在江苏的较大范围的切变类冰雹天气过程作了对比分析。结果指出 ,无论冬季或春季当高原东部有深槽东移 ,冷暖空气在江淮地区交汇 ,地面抬升系统为暖切 ,并有大气层结不稳定 (Δθse( 50 0 - 850 ) <0℃ =中心和较强的风向和风速垂直切变、85 0hPa西南急流轴、85 0hPa最大水汽通量轴线、5 0 0和 85 0hPa正涡度中心等相配置时 ,就可能导致江苏地区较大范围强对流天气的发生。