Heavy metals in the hydrological cycle: Trends and explanation

This paper reviews the major sources and transport characteristics of heavy metals in the hydrological cycle. It is demonstrated that heavy metal releases to the environment have changed from 19th and early 20th century production-related activities to consumption-oriented factors in more recent times. The relative roles of particle size, sorption and desorption processes, partitioning and the chemical speciation of heavy metals on fine sediments are identified to understand the likely fate of heavy metals released into fluvial systems. It is argued that the spatial and temporal distribution of heavy metals in the river corridor depends not only on an understanding of metal solubility and speciation, but also on an understanding of sediment dynamics which control, for example, floodplain alluviation and the accumulation of metals in the bottom sediments of contaminated rivers, lakes and reservoirs. Existing long- and short-term records are examined to identify the current state of knowledge about the factors which affect heavy metal releases into aquatic environments. With limited exceptions, it is shown that few long-term studies of trends in heavy metal transport are available although, for some major rivers, limited data on trends in metal concentration exists. Palaeolimnological reconstruction techniques, based on an analysis of lake and reservoir sediments, are identified as a possible means of supplementing monitored records of heavy metal transport. Although numerous studies have suggested that trends in atmospheric contamination, mining and urbanization may be identified in the bottom sediment record, other research has shown that the radionuclide-based chronology and the heavy metal distribution within the sediment are more likely to be a function of post-depositional remobilization than the history of metal loading to the basin. Despite these limitations, it is shown that the incorporation of reservoir bottom sediment analysis into a heavy metal research programme, based in river corridors of Midland England, provides an opportunity to identify and quantify the relative contribution of point and non-point contributions to the heavy metal budget and to relate trends in metal contamination to specific periods of catchment disturbance.     

Can channel banks be the dominant source of fine sediment in a UK river?: an example using 137Cs to interpret sediment yield and sediment source

Cultivated fields have been shown to be the dominant sources of sediment in almost all investigated UK catchments, typically contributing 85 to 95% of sediment inputs. As a result, most catchment management strategies are directed towards mitigating these sediment inputs. However, in many regions of the UK such as the Nene basin there is a paucity of sediment provenance data. This study used the caesium‐137 (¹³⁷Cs) inventories of lake and floodplain cores as well as the ¹³⁷Cs activities of present day sediment to determine sediment provenance. Sediment yields were also reconstructed in a small lake catchment. Low ¹³⁷Cs inventories were present in the lake and floodplain cores in comparison to the reference inventory and inventories in cores from other UK catchments. Caesium‐137 activities in the present day sediments were low; falling close to those found in the channel bank catchment samples. It was estimated that 60 to 100% of the sediment in the Nene originated from channel banks. Pre‐1963 sediment yields were approximately 11.2 t km^?2 yr^?1 and post‐1963 was approximately 11.9 t km^?2 yr^?1. The lack of increased sediment yield post‐1963 and low sediment yield is unusual for a UK catchment (where a yield of 28 to 51 t km^?2 yr^?1 is typical for a lowland agricultural catchment), but is explained by the low predicted contribution of sediment from agricultural topsoils. The high channel bank contribution is likely caused by the river being starved of sediment from topsoils, increasing its capacity to entrain bank material. The good agreement between the results derived using cores and recently transported sediments, highlight the reliability of ¹³⁷Cs when tracing sediment sources. However, care should be taken to assess the potential impacts of sediment particle size, sediment focusing in lakes and the possible remobilization of ¹³⁷Cs from sedimentary deposits. Copyright © 2016 John Wiley & Sons, Ltd.     

Monitoring soil erosion on agricultural land: results and implications for the Rother valley,West Sussex,UK

Monitoring has played a key role in understanding the rates, extent and frequency of erosion on agricultural land and this includes projects in Switzerland, Germany and the UK. In this case we focus on highly erodible soils in the Rother valley, West Sussex, southern England on which grow a range of arable crops throughout the year. Erosion rates and extent are high, particularly in response to exceptionally wet periods in the early winter. In the monitored period, rates on summer crops were relatively low due to an absence of intense summer storms. In the years 2015–2020, erosion was localized to where limited areas of bare ground coincided with heavy winter rainfall. Issues of river pollution, associated with excessive sedimentation, off-site flooding and a high degree of connectivity between arable fields and the river, are of increasing concern. Mitigation measures need to be expanded to protect freshwater systems and properties. This study has implications for similar programmes in intensely farmed regions. © 2020 John Wiley & Sons, Ltd.     

Tropical shrimp trawl fisheries: Fishers’ knowledge of and attitudes about a doomed fishery

Tropical shrimp trawl fisheries are unsustainable, and similar sets of management measures are used globally to address the direct and indirect costs of their practices. Yet little is known about shrimp fishers’ perceptions, despite the clear importance of human behaviour in determining the success of fisheries management. This article presents the results of interviews with industrial shrimp trawl fishers from the southern Gulf of California, Mexico, and reveals fishers’ knowledge and attitudes that should be considered when developing management plans for industrial shrimp trawl fisheries. Fishers were asked to comment on problems facing the fishery, management options to address the issues, and the future of the fishery in general. The interviews also elicited new knowledge on effort and valuable components of bycatch, useful to the management process. Among the problems facing the Gulf of California fishery, fishers tended to identify those generated externally—fluctuations in shrimp populations, increases in fishing effort, decreases in shrimp prices and increasing overheads—and thus distance themselves from responsibility for management options. The successes of any mitigation measures for the fishery are likely to depend on proper enforcement and reliable governance, as our study indicates. Should strong enforcement be put in place, then trawl free areas seem to be the most pragmatic way to alleviate problems associated with the fishery; our effort data point to areas that might have greatest acceptance among fishers. A reduction in capacity would clearly complement marine zoning for trawl free areas. In the long run, however, it may be economic extinction of the fishery that reduces pressure on the marine ecosystem.     

Stochastic Radiative Transfer on Modeled Cloud Fields

Several efforts are currently underway to improve cloud-radiation parameterizations in Global Climate Models (GCMs) by incorporating statistical properties of the cloud field. Although some radiation parameterizations, which are already computationally costly, now incorporate subgrid scale variability in cloud properties, they are not yet capable of using this information in their calculations of the 3-D radiation fields. Before drastic changes are made to such algorithms to incorporate cloud-cloud radiation interactions, the impact of including realistic high-resolution cloud distributions on the shortwave fluxes should be assessed. This letter provides a framework for carrying out such assessments, including a new methodology that blends a stochastic radiative transfer model, high-resolution cloud fields from a mesoscale meteorological model, and a threshold and object identification technique applied to cloud water content fields. This process provides a link between the radiative fluxes calculated in GCMs, where clouds occur at a subgrid scale, and the highly resolved cloud fields in a regional climate model, which can provide cloud field statistics. Two case studies are described herein.     

Flush-Joint Threads Find a Home

With the rapid growth of PVC in the well casing and screen market, many different applications and methods of use have surfaced. One major method of fastening or joining thermoplastic well casing is the flush-joint thread. Widespread use of flush-joint threads on Schedule 40 and Schedule 80 pipe has caused concern about the physical strength and hydrostatic integrity of these threads. These concerns are magnified when one discovers the multitude of different manufacturers, each with his own thread design. There has, however, been a solution: Committee F17 of ASTM has passed a change in the Standard F480, which is now: ASTM F480–88A Standard Specification for Thermoplastic Well Casing and Couplings Made In Standard Dimension Ratios (SDR), Schedule 40 and Schedule 80. This change partially consists of incorporating specifications for flush-joint threads in Schedule 40 and Schedule 80 casing, in sizes ± inch to 16 inch in Schedule 80 and 2 inch to 16 inch in Schedule 40. This long overdue standard now ensures field thread compatibility with all pipe specified with this standard. It also requires manufacturers to cut a functional and reliable thread.
Extensive testing has been done to determine the physical properties of the specified thread. The three tests that help the purchaser determine the working parameters of this flush-joint thread include:
1. Tensile test of the threaded joint
2. Internal hydrostatic pressure test
3. External hydrostatic pressure test.
Using ASTM guidelines test methods were developed for testing this thread. Results show that the new thread specification in F480 is a valid and functional design.     

Forward modeling corona growth in a partially eclogitized leucogabbro, Bourbon Island, North-East Greenland

Coronitic textures are common in partially eclogitized igneous bodies, such as gabbros, leucogabbros, and anorthosites, east of the Germania Land Deformation Zone in North-East Greenland. Coronas formed by prograde metamorphic processes that transformed the gabbroic bodies to eclogite facies, and record frozen stages of the prograde metamorphic evolution of these rocks. A metaleucogabbro-norite body on Bourbon Island in Jøkelbugt is characterized by three concentric areas: a coronitic core, a mottled inner rim with areas of completely eclogitized material surrounded by a matrix of coronitic metaleucogabbro, and an outer rim of strongly foliated and completely retrogressed amphibolite. The Bourbon body preserves four stages of the prograde metamorphic history: Stage I, Stage II, Stage III, and Eclogite Stage. Stage I coronas are found only in the core of the body, which is the least reacted part of the leucogabbro-norite and the closest to the protolith, and is characterized by the corona sequence Pl_rim/Grt + Kfs + Amp/Grt + Amp/Cpx_rim. The typical corona sequence for Stage II is Pl_rim/Grt + Pl + Zo/Cpx_rim/Amp_rim. Stage III samples show a Pl_rim + Ky + Scp/Grt + Pl + Qtz/Qtz + Pl sequence, with the relict clinopyroxene being replaced in part by microcrystalline aggregates of Cpx + Amp + Pl. The Eclogite Stage shows relict Pl completely replaced by Grt, and the relict Cpx completely replaced by aggregates of Omp + Pl + Kfs + Amp. We tested open-system grain boundary diffusion (OSGBD) theories to model the prograde Stage I symplectitic coronas. The observed ratio of the thickness of the different layers is Pl_rim:Grt + Kfs + Amp:Grt + Amp:Cpx_rim equal to 3:1.3:0.95:0.5. These ratios are very close to the modeled ones of 2.7:1.1:1:0.5. Furthermore, subtle textural changes within the Grt + Kfs + Amp corona were also reproduced by the model. The model gave us insight into the conditions of the metamorphic system in which the coronas formed. The sequence Pl_rim/Grt + Kfs + Amp/Grt + Amp/Cpx_rim formed by diffusion driven reactions in an open system involving gain of Fe, K, and Na, and loss of Ca and Mg at the original clinopyroxene–plagioclase boundary. Relative mobilities of the different components within the corona layers were L_MgMg > L_AlAl > L_SiSi > L_CaCa > L_KK > L_FeFe > L_NaNa. Fluid circulation was active to some degree during the transformation to eclogite. The differences between core, inner rim, and the two domains within the inner rim of the metaleucogabbro-norite can be explained by different degrees of fluid circulation in different portions of the rock. The presence of phases containing Cl and P, such as scapolite, in completely eclogitized samples supports the presence of fluid circulation in the system. Another possible explanation for the mottled appearance of the inner rim is protolith heterogeneity.     

The use of multivariate statistics to elucidate patterns of floodplain sedimentation at different spatial scales

Floodplains are depositional features of riverine landscapes that display complex sedimentation patterns that are amenable to multi‐scale approaches. We examined sedimentation in the Lower Balonne floodplain, Queensland, Australia, at three different spatial scales: the channel (10³ km), floodplain process zone (10 km) and geomorphic unit (10² m) scales, and compared scale‐related patterns evident from stratigraphy with those evident from quantitative multivariate analysis. Three stratigraphic sequences were found in the Lower Balonne floodplain: generally fining upward, episodic fining upward, and mud‐dominated. Stratigraphical analysis revealed the detailed character of sedimentary sequences embedded within the scale patterns derived from multivariate analysis. Multivariate statistical analyses of a range of textural and geochemical data revealed different patterns of floodplain sedimentation at each scale. At the channel scale, sediment texture and geochemistry were more heterogeneous in the Culgoa River than in Briarie Creek. At the floodplain process zone scale clear patterns of sediment texture and geochemistry were observed along the upper, mid and lower floodplain process zones of Briarie Creek, but not along the Culgoa River. At the geomorphic unit scale, clear patterns of sediment texture and geochemistry were observed among the bank, buried channel and flat floodplain units of the Culgoa River, but were not as clear in Briarie Creek. Recognition of rivers as hierarchically organized systems is an emerging paradigm in river science. Our study supports this paradigm by demonstrating that different sedimentation patterns occur at different scales to reveal a hierarchically organized floodplain environment. Copyright © 2006 John Wiley & Sons, Ltd.     

SYNCONVERGENT, DUCTILE N-DIRECTED SHEARING ON THE WESTERN MARGIN OF THE NANGA PARBAT SYNTAXIS, N. PAKISTAN

SYNCONVERGENT, DUCTILE N-DIRECTED SHEARING ON THE WESTERN MARGIN OF THE NANGA PARBAT SYNTAXIS, N. PAKISTAN1　BurgJ P ,ChaudryMN ,GhazanfarM ,etal.StructuralevidenceforbackslidingoftheKohistanarcinthecollisionalsystemofnorthwestPakistan[J] .Geology 1996 ,2 4 ( 8) ,739～ 74 2 . 2　ChamberlainCP ,ZeitlerPK ,EricksonE .ConstraintsonthetectonicevolutionofthenorthwesternHimalayafromgeochronologicandpetrologicstudiesofBabusarPass,Pakistan[J] .Journa…     

A record of Holocene environmental and ecological changes from Wildwood Lake,Long Island,New York

Analyses of pollen, charcoal and organic content in a lake sediment core from Wildwood Lake, Long Island, New York, provide insights into the ecological and environmental history of this region. The early Holocene interval of the record (ca. 9800–8800 cal. a BP) indicates the presence of Pinus rigida–Quercus ilicifolia woodlands with high fire activity. A layer of sandy sediment dating to 9200 cal. a BP may reflect a brief period of reduced water depth, consistent with widespread evidence for cold, dry conditions at that time. Two other sandy layers, bracketed by ¹⁴C dates, represent a sedimentary hiatus from ca. 8800 to 4500 cal. a BP. This discontinuity may reflect the removal of some sediment during brief periods of reduced water depth at 5300 and 4600 cal. a BP. In the upper portion of the record (<4500 cal. a BP), subtle changes at ca. 3000 cal. a BP indicate declining prevalence of Quercus–Fagus–Carya forests and increasing abundance of Pinus rigida, perhaps due to reduced summer precipitation. Elevated percentages of herbaceous taxa in the uppermost sediments represent European agricultural activities. However, unlike charcoal records from southern New England, fire activity does not increase dramatically with European settlement. These findings indicate that present‐day Pinus rigida–Quercus ilicifolia woodlands on eastern Long Island are not a legacy of recent, anthropogenic disturbances. Copyright © 2010 John Wiley & Sons, Ltd.