Arsenic species in weathering mine tailings and biogenic solids at the Lava Cap Mine Superfund Site,Nevada City,CA

Background  

A realistic estimation of the health risk of human exposure to solid-phase arsenic (As) derived from historic mining operations is a major challenge to redevelopment of California's famed "Mother Lode" region. Arsenic, a known carcinogen, occurs in multiple solid forms that vary in bioaccessibility. X-ray absorption fine-structure spectroscopy (XAFS) was used to identify and quantify the forms of As in mine wastes and biogenic solids at the Lava Cap Mine Superfund (LCMS) site, a historic "Mother Lode" gold mine. Principal component analysis (PCA) was used to assess variance within water chemistry, solids chemistry, and XAFS spectral datasets. Linear combination, least-squares fits constrained in part by PCA results were then used to quantify arsenic speciation in XAFS spectra of tailings and biogenic solids.     

Sediment targets for informing river catchment management: international experience and prospects

Sediment plays a pivotal role in determining the physical, chemical and biological integrity of aquatic ecosystems. A range of factors influences the impacts of sediment pressures on aquatic biota, including concentration, duration of exposure, composition and particle size. In recognition of the need to assess environmental status for sediment and mitigate excessive sediment pressures on aquatic habitats, both water column and river substrate metrics have been proposed as river sediment targets. Water column metrics include light penetration, turbidity, sediment concentration summary statistics and sediment regimes. Substrate metrics include embeddedness, the fredle index and riffle stability. Identification of meaningful numeric targets along these lines has, however, been undermined by various issues including the uncertainty associated with toxicological dose‐response profiles and the impracticalities of deploying statistically robust sampling strategies capable of supporting catchment‐scale targets. Many of the thresholds reported are based on correlative relationships that fail to capture the specific mechanisms controlling sediment impacts on aquatic habitats and are stationary in nature. Temporal windows represented by the key life stages of specific species must be given greater emphasis. Given such issues and the need to support the revision of sediment targets for river catchment management, it is proposed that greater emphasis should be placed on developing generic modelling toolkits with the functionality for coupling current or future projected sediment regimes with biological response for a range of biota. Such tools should permit the identification of river catchment‐specific targets within a national context, based on biological effect and incorporate sufficient flexibility for utilizing updated physical, chemical, biological and catchment attribute data. Confidence will continue to be required in compliance screening to ensure cost‐effective management programmes for avoiding disproportionate investment in impacted river catchments. Copyright © 2011 John Wiley & Sons, Ltd.     

A record of late-Holocene environmental change from southern New England, USA

Analyses of a sediment core from Little Pond, located in the town of Bolton, Massachusetts, provide new insights into the history of environmental and ecological changes in southern New England during the late Holocene. Declines in organic content and peaks in the abundance of Isoetes spores indicate reduced water depth at 2900–2600, 2200–1800, and 1200–800 calibrated years before present (cal yr BP), generally consistent with the timing of dry conditions in records from elsewhere in the northeastern United States. The Little Pond pollen record features little change over the last 3000 yr, indicating that the surrounding vegetation was relatively insensitive to these periods of drought. The 1200–800 cal yr BP dry interval, however, coincides with increased abundance of Castanea pollen, suggesting that the expansion of Castanea in southern New England may have been influenced by late-Holocene climatic variability.     

Fe XXI emission line ratios as electron temperature diagnostics for the coronae of cool stars

A method for the reconstruction of the linear force-free magnetic field in a bounded domain (as a rectangular box, ) is presented here. The Dirichlet boundary-value problem for the Helmholtz equation is solved for the B _z component specified at the boundary. Chebyshev's iteration method with the optimal rearrangement of the iteration parameters sequence was used. The solution is obtained as for the positive-definite, and for the non-sign-definite difference analogue of the differential operator ² u + ² u. Specifying two scalar functions, B _x and B _y on the intersection of the lateral part of the boundary with one selected plane z = constant, and using B _z inside the , we have found B _x and B _y throughout .The algorithm was tested with the numerical procedure which gives the analytic solution B of the linear force-free field (LFFF) equations for the dipole in a half-space. The root-mean-square deviation of the analytic solution B from the calculated B does not exceed 1.0%. Boundary conditions for the B calculation were taken as given by the analytic LFFF solution B. Comparison of B with B, which was calculated by the potential non-photospheric boundary conditions, show that they differ significantly. Thus, the specification of boundary conditions at non-photospheric boundaries of the volume under consideration is of particular importance when modeling the LFFF in a bounded volume.The algorithm proposed here allows one to use the information about magnetic fields in the corona for the modeling of LFFF in a limited domain above an active region on the Sun.     

Book Reviews

Books reviewed:

Pyne, Stephen J., How The Canyon Became Grand: A Short History

Gibson, Clark C., Politicians and Poachers: The Political Economy of Wildlife Policy in Africa

Voeks, Robert A., Sacred Leaves of Candomblé: African Magic, Medicine, and Religion in Brazil

Grossman, Lawrence S., The Political Ecology of Bananas: Contract Farming, Peasants and Agrarian Change in the Eastern Caribbean

Fennell, David A., Ecotourism: An Introduction

Soffer, Arnon, Rivers of Fire: The Conflict Over Water in the Middle East

Light, Andrew and Smith, Jonathan M., Philosophy and Geography II: The Production of Public Space

Davies, Richard O., Main Street Blues: The Decline of Small-Town America

Driver, Felix and Gilbert, David, Imperial Cities: Landscape, Display and Identity

Baldassare, Mark, California in the New Millennium: The Changing Social and Political Landscape

Herzog, Lawrence A., From Aztec to High Tech: Architecture and Landscape Across the Mexico-United States Border

Cowie, Jefferson, Capital Moves: RCA’s Seventy-Year Quest for Cheap Labor

Aiken, Charles, The Cotton Plantation South Since the Civil War

Smith, Steven D., Crass, David, and Zierden, Martha A., The Southern Colonial Backcountry: Interdisciplinary Perspectives on Frontier Communities

Hoelscher, Steven D., Heritage of Stage: The Invention of Ethnic Place in America’s Little Switzerland

Bradley, Betsy Hunter, The Works: The Industrial Architecture of the United States     

Partial melting due to breakdown of an epidote‐group mineral during exhumation of ultrahigh‐pressure eclogite: An example from the North‐East Greenland Caledonides

In the North‐East Greenland Caledonides, P–T conditions and textures are consistent with partial melting of ultrahigh‐pressure (UHP) eclogite during exhumation. The eclogite contains a peak assemblage of garnet, omphacite, kyanite, coesite, rutile, and clinozoisite; in addition, phengite is inferred to have been present at peak conditions. An isochemical phase equilibrium diagram, along with garnet isopleths, constrains peak P–T conditions to be subsolidus at 3.4 GPa and 940°C. Zr‐in‐rutile thermometry on inclusions in garnet yields values of ~820°C at 3.4 GPa. In the eclogite, plagioclase may exhibit cuspate textures against surrounding omphacite and has low dihedral angles in plagioclase–clinopyroxene–garnet aggregates, features that are consistent with former melt–solid–solid boundaries and crystallized melt pockets. Graphic intergrowths of plagioclase and amphibole are present in the matrix. Small euhedral neoblasts of garnet against plagioclase are interpreted as formed from a peritectic reaction during partial melting. Polymineralic inclusions of albite+K‐feldspar and clinopyroxene+quartz±kyanite±plagioclase in large anhedral garnet display plagioclase cusps pointing into the host, which are interpreted as crystallized melt pockets. These textures, along with the mineral composition, suggest partial melting of the eclogite by reactions involving phengite and, to a large extent, an epidote‐group mineral. Calculated and experimentally determined phase relations from the literature reveal that partial melting occurred on the exhumation path, at pressures below the coesite to quartz transition. A calculated P–T phase diagram for a former melt‐bearing domain shows that the formation of the peritectic garnet rim occurred at 1.4 GPa and 900°C, with an assemblage of clinopyroxene, amphibole, and plagioclase equilibrated at 1.3 GPa and 720°C. Isochemical phase equilibrium modelling of a symplectite of clinopyroxene, plagioclase, and amphibole after omphacite, combined with the mineral composition, yields a P–T range at 1.0–1. 6 GPa, 680–1,000°C. The assemblage of amphibole and plagioclase is estimated to reach equilibrium at 717–732°C, calculated by amphibole–plagioclase thermometry for the former melt‐bearing domain and symplectite respectively. The results of this study demonstrate that partial melt formed in the UHP eclogite through breakdown of an epidote‐group mineral with minor involvement of phengite during exhumation from peak pressure; melt was subsequently crystallized on the cooling path.     

Testing benthic foraminiferal distributions as a contemporary quantitative approach to biomonitoring estuarine heavy metal pollution

Biomonitoring of estuarine pollution is the subject of active research, and benthic foraminifera are an attractive group to use for these purposes due to their ubiquitous presence in saline water and wide diversity. Here, we describe a case study of biomonitoring using benthic foraminifera in the French Mediterranean lagoon, Bages-Sigean lagoon. In this case, the major pollutants of interest are heavy metals in the sediment, particularly contaminated by Cu and Cd derived from industrial and agricultural sources. The foraminiferal assemblages of the Bages-Sigean lagoon are typical of normal paralic environments, but unusually almost completely lack agglutinated forms. The density of benthic foraminifera was shown to be more influenced by the sediment characteristics rather than heavy metal pollution. However, the relative abundance of Quinqueloculina bicostata was shown to increase in the most polluted areas and we propose that this taxon may be used as an indicator of heavy metal pollution.     

Enhanced alignment of plate ice crystals in a non-uniform electric field

An atmospheric electric field exerts a torque on both column and plate ice crystals. Columns tend to align along the direction of the field. One diameter of plate crystals also aligns parallel to a field, while a non-uniform diverging field leads to further orientation and proscribes a secondary orientation along the direction of least divergence. A laboratory investigation treats the electrical orientation of thin plate ice crystals in a non-uniform field as a two-step process. In the model, the average field provides the primary torque and aligns one diameter of the plate crystal while simultaneously a spatially varying component of the field aligns the perpendicular diameter. The first element of the process, the primary torque, has been investigated previously. The complete reorientation, caused by a secondary torque, is investigated herein. Experimentally a stronger field with sufficient non-uniformity is required to demonstrate the secondary torque. The realignment caused by this torque depends also on the strength of the aerodynamic torques on the falling ice crystals. Experiments in a laboratory cold chamber with small thin plate crystals in an electric field provided by a charged rod demonstrate crystal reorientation by changing the reflections of a beam of white light. A model incorporating electrical torques is applied to the laboratory observation and used to investigate the possibility of the effects occurring in the atmosphere. Fields near lightning strokes, which are strong but of short duration, may reorient small crystals. Larger crystal aggregates like planar snowflakes are governed by the same electrical torques. It is suggested that the secondary torque realignment might be observable for aggregates large enough to be detected by radar in cases pertaining to weaker but longer duration fields associated with cloud electrification. A simplification of the model is used to investigate electrically caused crystal motion and linear aggregation, with applications to the atmosphere and to lightning initiation.     

Stratigraphy, biostratigraphy and C-isotopes of the Permian–Triassic non-marine sequence at Dalongkou and Lucaogou, Xinjiang Province, China

Measured lithostratigraphic sections of the classic Permian–Triassic non-marine transitional sequences covering the upper Quanzijie, Wutonggou, Guodikeng and lower Jiucaiyuan Formations at Dalongkou and Lucaogou, Xinjiang Province, China are presented. These measured sections form the framework and reference sections for a range of multi-disciplinary studies of the P–T transition in this large ancient lake basin, including palynostratigraphy, vertebrate biostratigraphy, chemostratigraphy and magnetostratigraphy. The 121 m thick Wutonggou Formation at Dalongkou includes 12 sandstone units ranging in thickness from 0.5 to 10.5 m that represent cyclical coarse terrigenous input to the lake basin during the Late Permian. The rhythmically-bedded, mudstone-dominated Guodikeng Formation is 197 m and 209 m thick on the north and south limbs of the Dalongkou anticline, respectively, and 129 m thick at Lucaogou. Based on limited palynological data, the Permian–Triassic boundary was previously placed approximately 50 m below the top of this formation at Dalongkou. This boundary does not coincide with any mappable lithologic unit, such as the basal sandstones of the overlying Jiucaiyuan Formation, assigned to the Early Triassic. The presence of multiple organic δ¹³C-isotope excursions, mutant pollen, and multiple algal and conchostracan blooms in this formation, together with Late Permian palynomorphs, suggests that the Guodikeng Formation records multiple climatic perturbation signals representing environmental stress during the late Permian mass extinction interval. The overlap between the vertebrates Dicynodon and Lystrosaurus in the upper part of this formation, and the occurrence of late Permian spores and the latest Permian to earliest Triassic megaspore Otynisporites eotriassicus is consistent with a latest Permian age for at least part of the Guodikeng Formation. Palynostratigrahic placement of the Permian–Triassic boundary in the Junggar Basin remains problematic because key miospore taxa, such as Aratrisporites spp. are not present. Palynomorphs from the Guodikeng are assigned to two assemblages; the youngest, from the upper 100 m of the formation (and the overlying Jiucaiyuan Formation), contains both typical Permian elements and distinctive taxa that elsewhere are known from the Early Triassic of Canada, Greenland, Norway, and Russia. The latter include spores assigned to Pechorosporites disertus, Lundbladispora foveota, Naumovaspora striata, Decussatisporites mulstrigatus and Leptolepidites jonkerii. While the presence of Devonian and Carboniferous spores and Early Permian pollen demonstrate reworking is occurring in the Guodikeng assemblages, the sometimes common occurrence of Scutasporites sp. cf. Scutasporites unicus, and other pollen, suggests that the Late Permian elements are in place, and that the upper assemblage derives from a genuine transitional flora of Early Triassic aspect. In the Junggar Basin, biostratigraphic data and magnetostratigraphic data indicate that the Permian–Triassic boundary (GSSP Level) is in the middle to upper Guodikeng Formation and perhaps as high as the formational contact with the overlying Jiucaiyuan Formation.