Methoxy formation in the reaction of CH3O2 radicals with NO

Formation of methoxy (CH₃O) radicals in the reaction (1) CH₃O₂+NOCH₃O+NO₂ at 298 K has been observed directly using time resolved LIF. The branching ratio % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaeqOXdyMaae% 4qaiaabIeadaWgaaWcbaGaae4maaqabaGccaqGpbGaaeiiaiaabIca% ieqacaWF9aGaa8hiaiaa-nbicaWFGaGaeuiLdqKaai4waiaaboeaca% qGibWaaSbaaSqaaiaabodaaeqaaOGaae4taiaac2facaWFVaGaeuiL% dqKaai4waiaaboeacaqGibWaaSbaaSqaaiaabodaaeqaaOGaae4tam% aaBaaaleaacaqGYaaabeaakiaac2facaqGPaaaaa!4E31!\[\phi {\rm{CH}}_{\rm{3}} {\rm{O (}} = -- \Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}]/\Delta [{\rm{CH}}_{\rm{3}} {\rm{O}}_{\rm{2}} ]{\rm{)}}\] has been determined by quantitative cw-UV-laser absorption at 257 nm of CH₃O₂ and CH₃ONO, the product of the consecutive methoxy trapping reaction (2) % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaae4qaiaabI% eadaWgaaWcbaGaae4maaqabaGccaqGpbacbeGaa83kaiaa-bcaieaa% caGFobGaa43taiaa+bcacaGFOaGaa83kaiaa+1eacaGFPaGaa4hiai% abgkziUkaabccacaqGdbGaaeisamaaBaaaleaacaqGZaaabeaakiaa% b+eacaqGGaGaaeOtaiaab+eacaqGGaGaa4hkaiaa-TcacaGFnbGaa4% xkaiaa+5cacaGFGaGaa4hiaiabeA8aMnaaBaaajqwaacqaaiaaboea% caqGibWaaSbaaKazcaiabaGaae4maaqabaqcKfaGaiaab+eaaSqaba% aaaa!55AC!\[{\rm{CH}}_{\rm{3}} {\rm{O}} + NO ( + M) \to {\rm{ CH}}_{\rm{3}} {\rm{O NO }}( + M). \phi _{{\rm{CH}}_{\rm{3}} {\rm{O}}} \] is found to be (1.0±0.2). The rate constant k ₁ is (7±2) 10^-12 cm³/molecule · s in good agreement with previous results.     

Differences in Kilometre‐scale wind and humidity boundary‐layer structure at GATE

Abstract

During the GARP Atlantic Tropical Experiment (GA TE) in the summer of 1974, identical tethersonde packages were flown to heights of 1,000 m from two ships with a crosswind separation of approximately 4 km. The differences in the profiles and fixed level time series from the two packages are a measure of spatial variability in the tropical marine boundary layer.

Correlation analysis indicate a cellular pattern in the large‐scale wind field. Similar analyses of the temperature and humidity fields give quite different results.     

Cainozoic Stratigraphy of the lake Eyre basin and part of the arid region lying to the South

The Cainozoic history of the Lake Eyre region opened with a period of deep weathering during which many of the older rocks were extensively kaolinized. Following erosion and later deposition of a thin sheet of Tertiary fluviatile deposits, a period of weathering resulted in the widespread formation of silcrete. Another period of erosion and deposition was followed by soil formation and minor silici‐fication.

An important period of erosion followed during which some of the main elements of the present landscape were outlined. Warping during this interval gave rise to shallow basins in which lacustrine sediments accumulated. At about the same time, a system of mound springs developed near the western margin of the Great Artesian Basin. Another major period of erosion followed, by which time the main topographic features of the present landscape had evolved. This last event probably took place near the close of the Tertiary. Throughout the Tertiary, drainage was external and ancestral Lake Eyre remained fresh.

The Quaternary was characterized by four periods of aeolian and, to a lesser extent, water erosion and deposition alternating with periods of landscape stability, when weathering and soil formation took place.

Throughout the Cainozoic there was an alternation of relatively humid and dry periods, but true aridity and internal drainage did not appear until the Quaternary. Sand ridges were not formed until the late Quaternary. Intervals of gentle warping occurred from time to time during the Tertiary, but the Quaternary has for the most part been a period of stability. These events have given rise to a sequence of distinctive rock and soil‐stratigraphic units whose characteristics are considered in some detail.     

The Volch’etundrovsky Massif of the autonomous anorthosite complex of the Main Range, the Kola Peninsula: Geological, petrogeochemical, and isotope-geochronological studies

The Volch??etundrovsky Massif occupies the middle part of the autonomous anorthosite complex of the Main Range, has a sheet morphology and marks the tectonic suture between the Kola block and the Belomorian mobile belt. The massif is characterized by homogenous structure and consists of the volumetrically dominant Main Zone including leucogabbro, leucogabbronorites, and anorthosites, and Marginal Zone made up of leuconorites and gabbronorites with subordinate plagioclasites and orthopyroxenites. Chemically, the rocks of the Volch??etundrovsky Massif are ascribed to the normal (tholeiitic and calc-alkaline) petrochemical series with typomorphic high Al₂O₃ contents (11.71?C29.32 wt %). With Al₂O₃ increase in the leuconorite-anorthosite series, the SiO₂ and TiO₂ contents show weak variations, CaO and alkalis insignificantly increase, whereas the MgO and FeO contents sharply decrease. The rocks of the Volch??etundrovsky Massif reveal significant REE fractionation and increase in total REE content in the leuconorite-anorthosite series, most approximating the Paleoproterozoic (Sumian) anorthosites of the Kola region. The anorthosites and leucogabbro are characterized by flat HREE, while the leuconorites is strongly depleted in HREE due to garnet fractionation. All rocks of the massif have significant positive Eu anomalies caused by the plagioclase accumulation. Zircons are characterized by LREE depletion and enrichment in HREE. This defines the steep positive slope of the plots complicated by the negative Eu and positive Ce (in zircons from leucogabbro) anomalies, which is typical of the REE distribution patterns in the unaltered zircons from igneous rocks. In zircons from anorthosites, the Ce anomaly is weak to absent. The trace-element distribution in the rocks of the Volch??etundrovsky Massif show positive Ba, Ta, Pb, Sr, Sc, and V anomalies, being controlled by the mineral specifics of the massif and the presence of definite accessory minerals. New U-Pb zircon data on the rocks of the Volch??etundrovsky Massif indicate that the leuconorites from the Marginal Zone were formed 2473 ± 7 Ma and 2463 ± 2.4 Ma ago, and the leucogabbro from the Main Zone, 2467 ± 8 Ma. These rocks have negative ?_Nd(T) from -1.54 up to -3.10, which indicates their derivation from enriched mantle reservoir variably contaminated by crustal material. The anorthosites of the Main Zone define an U-Pb age of 2407 ± 3 Ma and ?_Nd(T) = ?3.78, which presumably reflect the timing of hydrothermal-metasomatic alterations in the upper part of the magmatic chamber accompanied by significant crustal contamination.     

Suspended sediment concentration in a buoyant plume: Fraser River,Canada

A study of suspended sediment concentration in the buoyant plume of the Fraser River, Canada, showed that unstratified flow conditions at the river mouth caused resuspension of sandy bed material and high concentrations of coarse sediment. When flow at the mouth was stratified, sediment was fine-grained and concentrations were low. Application of a multivariate model revealed that suspended sediment concentration along the plume axis was controlled primarily by distance seaward of the river mouth, secondly by tidal height, and least by sediment concentration in the river.     

LARGE-SCALE CIRCULATION CONDITIONS AFFECTING THE HURRICANE FORMATION OVER THE NORTH ATLANTIC OCEAN

A contrasting study of the large-scale circulation features responsible for months or seasons with many hurricanes and those with few hurricanes has revealed that the frequency of hurricane formation over the North Atlantic Ocean is enhanced by the following conditions:There exists a well-developed subtropical high-pressure belt displaced to the north; a deep Icelandic low; a stronger-than-normal polar vortex with a deep polar trough dipping far southward along the eastern part of the United States; a dominant high-pressure ridge over western Canada and the United States; and a jet stream displaced northward over these regions. At 200 hPa, an anomalous anticyclonic circulation prevails over the subtropical North Atlantic. A stronger-than-normal upper easterly flow prevails. Positive sea surface temperature anomalies prevailing on a seasonal or long-term basis tend to be favorable for the formation of hurricanes.     

Building capacity for integrated coastal management in developing countries

The need for building human and institutional capacity has been identified in Agenda 21 of the UNCED conference as well as by a number of international environmental institutions as essential for integrated coastal management (ICM) and sustainable development in developing coastal states. There is a growing need for coastal management practitioners and organizations with expertise in planning and implementation for ICM. The application of strategies for institutional development and building human capacity in coastal management and other fields shows that short-term intensive training efforts and long-term institutional strengthening programs are appropriate to address the issues and needs of ICM. An overview of the experience of the URI/USAID International Coastal Resources Management Program in Sri Lanka, Thailand and Ecuador presents lessons learned for strengthening ICM efforts in developing countries.     

Wave run-up and overtopping on smooth and rough slopes of coastal structures

A series of hydraulic model tests has been carried out in a glass wave flume to investigate the influences of wave height, wave period, wave steepness, surf similarity parameter, roughness, layer thickness and porosity on wave run-up and overtopping of 1:2 sloped impermeable and permeable breakwaters fronted by a 1:10 gentle, smooth beach slope. The analysis of results involves the correlation between the overtopping energy transfer with the relative wall height and the relationship between wave run-up and overtopping rate. Further, measured wave run-up and overtopping rates are compared with the results given in the Shore Protection Manual (1984), Automated Coastal Engineering System (1992)and results of other investigators.