Eliminierung und Rückgewinnung von Metallionen aus Abwässern — eine Übersicht

The present state and the trends of the recovery of heavy metals from wastewaters are presented. The classical precipitation techniques are insatisfactory due to increases of solubility in the presence of impurity ions and/or complexing agents. At present, ion-exchange processes constitute the most frequently used method of metal recycling with an effective enrichment of metal ions. For the effective separation of metals from solutions of a low concentration the electrolytic reduction demands large electrode surface areas. In cells with fixed-bed or fluidized cathodes one can obtain specific electrode surface areas of some 10³ m²/m^m3. For the future, processes of extraction and especially membrane separation will gain in importance. In the past few years, a large number of highly selective metal extracting agents as well as the liquid membrane permeation with suitable carriers were developed. Combinations of membrane separation processes with chemical reactions may attain the same importance, as e.g. ultrafiltration in connection with the fixation of metal ions to watersoluble polymers. In the long run, especially techniques will prevail which will not only result in metal enrichment but also in the recovery of the raw material water.     

Effects of deforestation and afforestation on climate

Forests cover 29% of the continents. Their importance for mankind is not only due to wood production but also by their manyfold influences on the biosphere. The properties of forest stands influence climate, water balance, air constituents and the dynamic of atmosphere. The welfare functions of forests can be observed in the global as well as in the local or microscale. Anthropogenic measures, as deforestation and air pollution, endanger the forests and by that one of the main pillars of nature on earth.     

Results from the MERKUR experiment: Mass budget and vertical motions in a large valley during mountain and valley wind

Summary Based on measurements made in March 1982 in the Inn valley during the MERKUR experiment, an attempt was made to compute the mass budget of a large alpine valley during periods of mountain and valley wind.The computations come from measurements of the alongvalley mass flux and assumptions on the fluxes in the slope layer and tributaries.Vertical motions in the valley's atmosphere have been evaluated from the mass budget computations. These motions, including the subsidence which compensates for daytime upslope winds and the subsidence which compensates for the valley wind flowing into tributaries during the day, are of great importance for the understanding of the thermal circulation.The results allow better estimation of vertical advection, which contributes to the budgets of momentum and energy.With 8 Figures