Reconstruction of subglacial depositional conditions based on the anisotropy of magnetic susceptibility: an example from Dębe (central Poland)

The analysis of low-field anisotropy of magnetic susceptibility (AMS) was used to reconstruct the subglacial deposition conditions during the Main Stadial of the Odranian Glaciation (MIS 6) in till deposits from a site in Dębe (central Poland). Based on the AMS parameters, six till beds were identified (intervals 1–6). The declination of the maximum magnetic susceptibility axis (k₁) indicates that the ice sheet was moving in from the northwest. The obtained results confirm the thesis about the preferred direction of ice-sheet transgression during the Odranian Glaciation (MIS 6) in this part of Poland. This interpretation is also confirmed by data obtained from measurements of the long axis of clasts, which agree with the orientation of k₁. Based on the AMS results, a significant part of the profile was deformed through simple shear and direct interaction of the ice sheet with the underlying sediment (beds 2–5). The lowest part of the till (bed 6) may have been deposited on a southeast-trending slope or post-depositional deformed by uneven loading of the ice cover. The upper part of the profile (especially in interval 1) could be deposited with an impact of pore water.     

Fen ecosystem responses to water‐level fluctuations during the early and middle Holocene in central Europe: a case study from Wilczków,Poland

This paper presents a palaeoenvironmental reconstruction of the Wilczków fen (central Poland). The fen developed in an inactive valley at the onset of the Holocene (~11 ka BP) and peat accumulation lasted until 5.7 ka BP. Multi‐proxy reconstructions were made on the basis of palaeobotanical, cladoceran, chironomid, beetle and geochemical analyses. A Kohonen self‐organizing map (SOM, unsupervised artificial neural network) of the biotic sequence distinguished four stages of fen history. Stage X₁ (11.0–10.7 ka BP) was relatively wet and cool. Organic matter started to accumulate but the habitat conditions remained unstable. Moss, sedge and fern communities then developed. Sedimentary changes reveal an intensive groundwater supply at that time. Numerous and diverse chironomid and cladoceran subfossils indicate nearly permanent aquatic conditions. During stage Y₁ (10.6–9.2 ka BP) conditions were dry and the upper peat layer desiccated. Cladocera nearly disappeared whereas chironomids were represented by semi‐terrestrial and predatory (Tanypodinae) species. Conditions started to be more reducing. All the remaining samples belonged to the interweaving stages X₂ and Y₂. Stage Y₂ (mostly 9.1–7.3 and 6.0–5.7 ka BP) was also dry but humidity increased towards the top. Oxidizing conditions occurred and the pH became more alkaline, favouring Cladium mariscus. The basin received mostly allochthonous matter input at that time. Stage X₂ (mostly 6.8–6.1 ka BP) was humid and warm. The groundwater supply remained low but there was an increase in precipitation, changing local conditions to ombrotrophic. Species‐rich chironomid and cladoceran communities were associated with temporary pools. Finally, conditions returned to those characteristic of stage Y₂. The presented reconstruction documents long‐term abiotic and biotic changes determined by water supply, including groundwater outflow, which have rarely been detected at a multi‐proxy scale. We show that inactivated valley fens are sensitive to climate‐driven hydrological fluctuations. Kohonen neural networks appear to be a promising method for analysing variability in multi‐proxy data.     

The impact of pelagic (Daphnia longispina) and benthic (Dreissena polymorpha) filter feeders on chlorophyll and nutrient concentration

An outdoor experiment testing the effect of water flea (Daphnia longispina) and zebra mussels (Dreissena polymorpha) on physical and chemical water parameters and chlorophyll concentration changes was carried out in 12 containers filled with 150 l of unfiltered water from a lowland reservoir. During the 11 weeks of the experiment, the following physical, chemical and biological measurements were recorded: temperature (°C), oxygen concentration (mg dm⁻³), pH, conductivity (S cm⁻¹), concentration of phosphate phosphorus (PO₄-P) and ammonia nitrogen (NH₄-N) (g dm⁻³), total nitrogen (TN) and total phosphorus (TP) (g dm⁻³), phytoplankton community structure and chlorophyll a concentration (g dm⁻³). The amount of ammonia ions was the highest in the treatment with zooplankton, while phosphate ions reached the highest values in treatments with zebra mussels. The results confirmed the ability of Daphnia to increase the NH₄:PO₄ ratio, whereas excretion from zebra mussels resulted in a decrease in both the N:P ratio (ranging from 9 to 13) and the NH₄:PO₄ ratio in water. In both treatments containing zebra mussels, P-rich water enabled sudden growth of Chlorophyta, resulting in blooms of Hydrodictyon reticulatum after 3–4 weeks of the experiment. Such phenomena were not observed in the control and Daphnia treatments. Our results indicate that zebra mussels, in contrast to Daphnia, may increase the symptoms of water eutrophication and contribute to blooms of expansive phytoplankton species.     

Prediction of equilibrium Li isotope fractionation between minerals and aqueous solutions at high P and T: An efficient ab initio approach

The mass-dependent equilibrium stable isotope fractionation between different materials is an important geochemical process. Here we present an efficient method to compute the isotope fractionation between complex minerals and fluids at high pressure, P, and temperature, T, representative for the Earth’s crust and mantle. The method is tested by computation of the equilibrium fractionation of lithium isotopes between aqueous fluids and various Li bearing minerals such as staurolite, spodumene and mica. We are able to correctly predict the direction of the isotope fractionation as observed in the experiments. On the quantitative level the computed fractionation factors agree within 1.0‰ with the experimental values indicating predictive power of ab initio methods. We show that with ab initio methods we are able to investigate the underlying mechanisms driving the equilibrium isotope fractionation process, such as coordination of the fractionating elements, their bond strengths to the neighboring atoms, compression of fluids and thermal expansion of solids. This gives valuable insight into the processes governing the isotope fractionation mechanisms on the atomic scale. The method is applicable to any state and does not require different treatment of crystals and fluids.     

Erythemal UV observations at Belsk,Poland, in the period 1976–2008: Data homogenization,climatology, and trends

Measurements of erythemal irradiance have been carried out continuously at Belsk since May 1975. We present a homogenization procedure of the UV time series for the period of 1976–2008. Long-term oscillations discovered in the homogenized data set agree with those extracted from the reconstructed UV data for all-sky and clear-sky conditions. The UV climatology was established and the UV variability was determined. Positive UV trends were found for the period of 1976-2008 in the annual mean (5.6±0.9% per decade), in the seasonal mean for the warm subperiod of the year (April–October, 5.5±1.0% per decade), and in monthly means (∼2–9% per decade). A satisfactory agreement between the trend extracted from the homogenized ground-based data and that found in satellite UV data for Belsk (1979–2008) supports the reliability of satellite trend analyses over wider areas during snowless periods.     

Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Relationships between fluorescence and its components,absorption coefficients and organic carbon concentrations

In this study, the CDOM absorption coefficient at 350 nm [a_CDOM(350)] and CDOM excitation emission matrix (EEM) fluorescence were used to estimate annual fluxes of dissolved organic carbon (DOC) from the Cape Fear River to Long Bay in the South Atlantic Bight. Water samples were collected during a 3.5 year period, from October 2001 through March 2005, in the vicinity of the Cape Fear River (CFR) outlet and adjacent Onslow Bay (OB). Parallel factor analysis (PARAFAC) of CDOM EEM spectra identified six components: three terrestrial humic-like, one marine humic-like and two protein-like. Empirical relationships were derived from the PARAFAC model between DOC concentration and a_CDOM(350), total fluorescence intensity and the intensities of respective EEM components. DOC concentration and CDOM optical parameters were very well correlated and R² values ranged from 0.77 to 0.90. Regression analyses revealed that the non-absorbing DOC fraction, in DOC concentration estimated from CDOM optical parameters, varied with the qualitative composition of the CDOM. DOC concentration and intensity of the humic-like CDOM components characterized by excitation maxima at longer wavelengths have significantly higher estimated non-absorbing DOC compared to the analogous relationships between DOC and intensity of the humic-like CDOM components characterized by excitation maxima at shorter wavelengths. The relationships between DOC concentration and intensity of one of the protein-like components resulted in significantly reduced non-absorbing DOC fraction in DOC concentration estimation. Results of regression analyses between fluorescence intensities of specific EEM components and CDOM-specific absorption coefficients suggest that the relative proportion of humic-like CDOM components (characterized by excitation maximum at longer wavelengths) and the main protein-like component have the most impact on the values of a?_CDOM(350). Based on the relationships between a_CDOM(350), Cape Fear River flow, and DOC concentrations, DOC fluxes were estimated for 2002, 2003 and 2004. DOC fluxes varied from 1.5 to 6.2 × 10¹⁰ g C yr^? 1, depending on river flow.     

Harmonizing the RR Lyrae and clump distance scales – stretching the short distance scale to intermediate ranges?

I explore the consequences of making the RR Lyrae and clump giant distance scales consistent in the solar neighbourhood, Galactic bulge and Large Magellanic Cloud (LMC). I employ two major assumptions: (i) that the absolute magnitude–metallicity, M _V (RR)–[Fe/H], relation for RR Lyrae stars is universal, and (ii) that absolute I magnitudes of clump giants, M _I (RC), in Baade's Window are known (e.g. can be inferred from the local Hipparcos -based calibration or theoretical modelling). A comparison between the solar neighbourhood and Baade's Window sets M _V (RR) at [Fe/H]=−1.6 in the range (0.59±0.05, 0.70±0.05), somewhat brighter than the statistical parallax solution. More luminous RR Lyrae stars imply younger globular clusters, which would be in better agreement with the conclusions from the currently favoured stellar evolution and cosmological models. A comparison between Baade's Window and the LMC sets M ^LMC(RC) _I in the range (−0.33±0.09,−0.53±0.09). The distance modulus to the LMC is μ ^LMC∈(18.24±0.08,18.44±0.07). Unlike M ^LMC(RC) _I , this range in μ ^LMC does not depend on the adopted value of the dereddened LMC clump magnitude, I ^LMC(RC)₀. I argue that the currently available information is insufficient to select the correct distance scale with high confidence.