Ecological indices tracking distinct impacts along disturbance-recovery gradients in a temperate NE Atlantic Estuary – Guidance on reference values

Results gathered from a monitoring programme on the Mondego Estuary (Western Coast of Portugal) were compliant with findings drawn from other studies, which pointed out that unstable environments, namely estuarine systems, constitute a great challenge for the use of environmental tools such as ecological indices. The Margalef Index, the Shannon–Wiener Index and AMBI were proposed to evaluate the ecological status of benthic communities in the scope of the European Water Framework Directive (WFD) in Portugal and other European member states. In this system these indices were not equally effective in tracking changes in benthic communities that expressed obvious responses to anthropogenic disturbances (eutrophic situations and severe physical disturbance) and to subsequent impacts' cessation. Natural variability played an important role on the indices' response, with estuarine gradient and habitat heterogeneity affecting the ranges of values obtained, and with extreme climate events slowing down the ongoing recovery process. Nonetheless, both natural and anthropogenic variability during the study period could be satisfactorily detected if we accounted for the information provided by all three indices. Based on the whole range of variation observed (a) as a response to different kinds of impacts, and (b) along recovery gradients, as well as accounting for the natural driving forces acting upon estuarine benthic invertebrate communities, we propose a set of reference values for these three indices. This proposal aims at contributing to the implementation of classification tools within the scope of the European WFD.     

Fluorescence as a Tool for Tracing the Organic Contamination from Pulp Mill Effluents in Surface Waters

Three‐dimensional fluorescence spectra of water samples from an eucalyptus bleached kraft pulp mill and from a river, upstream and downstream of the discharge of the effluent, revealed the existence of a peak at δ_exc = 280 nm and δ_em = 340 nm Δδ = 60 nm), characteristic of effluentπs organic matter. Humic substances were isolated from the effluent by sequential adsorption onto resins XAD‐8 and XAD‐4 in series. Their synchronous fluorescence spectra with Δδ = 60 nm do also exhibit an intense signal at δ_exc = 280 nm (≈ 300 nm in the humic acid fraction). The peak is absent in the spectra of humic substances isolated from a non‐polluted site of the river, but it is clearly seen in the spectra of the humic substances from a site downstream of the discharge of the effluent. Synchronous fluorescence spectra (Δδ = 60 nm) of water samples from the river and its lagoon were recorded and revealed to be an easy and fast way of tracing the organic contamination from the effluent.     

Vertical oscillations due to axial-bending coupling during seismic response of RC bridge piers

The paper presents a numerical investigation on the behaviour of reinforced concrete bridge piers subjected to horizontal seismic input. The scope of the investigation is to quantify the phenomenon of bending-induced axial vibrations. The results of a set of analyses conducted on single-column bent systems indicate that flexural cracking produces, in fact, significant axial vibrations. This effect is particularly relevant in squat elements with low axial force where the sway of the cross-sectional neutral axis under alternate bending causes strong hammering impulses at crack closure. Quantification of the effects related to this phenomenon can be determinant for the seismic assessment of existing bridges as well as for the design of new bridges. Likewise, performance and design forces of bearings and other anti-seismic devices can be estimated with more accuracy, based on the expected level of combined vertical and horizontal acceleration response on decks. The pier overall flexural response is not significantly altered by the fluctuation in axial force associated to these impulses, although local moment–curvature behaviour is, due to axial–bending interaction. Shear resisting mechanisms should be more sensitive to these vibrations and shear failure anticipated when a reduction in the axial contribution to the section shear capacity occurs. A tentative equation for the prediction of this flexural-induced vertical acceleration component is proposed based on simplified section kinematics and elastic impact analysis. Copyright © 1999 John Wiley & Sons, Ltd.     

Chemical defenses against generalist fish predators and fouling organisms in two invasive ahermatypic corals in the genus Tubastraea

The introduction of exotic marine species has caused considerable economic and ecological damage around the world. Some of these species possess adaptations such as secondary metabolites which facilitate their successful invasion into new areas. In this study we tested two hypotheses: (i) crude extracts produced by two invasive hard corals Tubastraea coccinea and Tubastraea tagusensis, introduced to the southwest Atlantic, inhibit predation by generalist fish; (ii) substances found in the crude extracts of both species reduce or enhance the settlement of other organisms. In an in situ palatability bioassay the extract of T. tagusensis reduced predation by generalist fish. The extracts of both species of coral showed species‐specific effects on fouling organisms in in situ gel plate bioassays. Control and extract plates had similar total cover, although plates with extracts had significantly fewer Cladophora sp., and Lithophyllum sp. was only detected on control gels. In contrast, a hydrozoan was only found on plates with extracts and overall community ordination demonstrated clear differences in the fouling communities between treatments. These results demonstrate that both coral species have chemical substances which can bring about a negative interaction with potential fish predators and competitors such as algal and invertebrate foulers and the advantage gained could explain their success in invading new regions to the detriment of local fauna and flora.     

Predicting significant wave height with artificial neural networks in the South Atlantic Ocean: a hybrid approach

Ocean Dynamics - Accurate simulations of significant wave height (Hs) are extremely important for the safety of navigation, port operations, and oil and gas exploration. Thus, accurate forecasts of...     

Preliminary Investigation of the Molise (Italy) Earthquakes of 31 October and 1 November 2002

On 31 October and 1 November 2002, two earthquakes took place in the Italian region of Molise. 29 deaths were reported, while many buildings collapsed or suffered major damage. The tectonics of the earthquakes and historic seismicity of the area are briefly described. The distribution of damage and macroseismic intensity are confronted with the current seismic zonation of the region. In particular, the paper deals with the damage suffered by different types of structures, namely masonry and RC buildings and historical churches. The observed damage is mainly attributed to the poor quality of the materials and execution of construction, lack of maintenance and protective devices (e.g., steel ties), as well as to structural interventions. Reference is made to the management of the post-earthquake emergency. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fog measurements at the site “Falda Verde” north of Chañaral compared with other fog stations of Chile

Fog collection data registered through a Standard Fog Collector (SFC) installed by a local fishermen's association at a height of 600 m at the “Falda Verde” site, north of the Chilean harbor Chañaral (26°17′S/70°36′W), from November 1998 to November 2000, are analyzed. Trying to give new lights on the dynamics of fog along the Chilean northern coast, this article compares, for the first time, the data obtained at Falda Verde with those obtained at five other Chilean fog stations. The total time period runs from 1987 to 2001. A mean of 1.46 l/m²/day was registered at the Falda Verde site after 2 years of measurements, one of the lowest yields along the north Chilean coast. After a brief historical recapitulation of fog researches in the study area, geographical explanations of the water yields obtained in different sites are discussed. The annual mean collection from Cerro Moreno and Paposo shows a clearly different behavior from all other sites, showing a greater stability throughout the year. Other stations have a marked difference between extreme seasons. Alto Patache yields, if not the best in Chile, are very high and offer unexpected possibilities for future applications in the coast. Stations located away from the seashore (Cerro Guatalaya) are clearly less productive. Ocean proximity, altitude, south and southwest orientations of the coastal ranges and local relief explain some of the differences noted.     

Assessing aquifer vulnerability to pollutants by electrical resistivity tomography (ERT) at a nitrate vulnerable zone in NE Spain

There is an increasing demand for groundwater vulnerability maps which illustrate the exposure of aquifers against pollution. These maps show areas of greatest potential for groundwater contamination on the basis of local subsurface conditions. Parameters affecting vulnerability are mainly permeability and thickness of each protective layer. For unconsolidated sediments, the permeability is strongly related to the clay content, which can be deduced from indirect resistivity methods, like electrical-imaging. Such geophysical methods can be of great help in groundwater vulnerability studies because they disturb neither the structure nor the dynamics of the soil. Sensibility analysis was performed of the electrical resistivity tomography method for accurately mapping soil media. Managers and public administrators may effectively use this method for assessing the potential risk of groundwater contamination. In the studied zone, electrical resistivity exhibits a wide range of variability that can be easily correlated to soil parameters, such as clay content and hydraulic conductivity. A numerical index of protection has been assessed from the geophysical information derived from 2D electrical resistivity tomography. This work represents a preliminary approach on the natural vulnerability evaluation of shallow aquifers at the Empordà basin (NE Spain) that is highly affected by diffuse pollution by nitrates.     

Multidimensional scaling visualization of earthquake phenomena

Earthquakes are associated with negative events, such as large number of casualties, destruction of buildings and infrastructures, or emergence of tsunamis. In this paper, we apply the Multidimensional Scaling (MDS) analysis to earthquake data. MDS is a set of techniques that produce spatial or geometric representations of complex objects, such that, objects perceived to be similar/distinct in some sense are placed nearby/distant on the MDS maps. The interpretation of the charts is based on the resulting clusters since MDS produces a different locus for each similarity measure. In this study, over three million seismic occurrences, covering the period from January 1, 1904 up to March 14, 2012 are analyzed. The events, characterized by their magnitude and spatiotemporal distributions, are divided into groups, either according to the Flinn–Engdahl seismic regions of Earth or using a rectangular grid based in latitude and longitude coordinates. Space-time and Space-frequency correlation indices are proposed to quantify the similarities among events. MDS has the advantage of avoiding sensitivity to the non-uniform spatial distribution of seismic data, resulting from poorly instrumented areas, and is well suited for accessing dynamics of complex systems. MDS maps are proven as an intuitive and useful visual representation of the complex relationships that are present among seismic events, which may not be perceived on traditional geographic maps. Therefore, MDS constitutes a valid alternative to classic visualization tools, for understanding the global behavior of earthquakes.     

Water column characterisation on the Azores platform and at the sea mounts south of the archipelago

This study provides data concerning the hydrography and water chemistry of the Atlantic region between 29-38° N and 27-31° W, and establishes background values for dissolved Cu, Cd, Pb and As. Three water masses were identified: the Eastern North Atlantic Central Water (ENACW), the Mediterranean Water (MW) and the North Atlantic Deep Water (NADW). The ENACW exhibits a clear meridional gradient of temperature and salinity, with comparatively high values at the southern sites and lower values on the Azores platform. The ENACW, which includes the euphotic zone, also had comparatively high concentrations of oxygen and lower concentrations of nutrients and metals. The Cu, Cd and Pb results suggest that new background concentrations for OSPAR Region V (the Wider Atlantic) should be established as follows: 0.15-13nM for Cu, 0.05-1.4nM for Cd and 0.03-5nM for Pb. The background concentrations of As for OSPAR Region V should be 7-28nM.