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61.
Emmanuelle Montarges-Pelletier Laurent Jeanneau Pierre Faure Isabelle Bihannic Odile Barres Bruno S. Lartiges 《Environmental Geology》2007,53(1):85-102
The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany.
One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting
and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier
Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose,
water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four
main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step,
mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate
matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions
(0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another,
seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite)
were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very
fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter
content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential
sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations,
confirming the origin of polluted material. 相似文献
62.
Particularly well exposed structures in folded and cleaved sedimentary cover immediately overlying a crystalline basement have been studied. Chemical analysis (X.R.F. and microprobe) reveal pressure solution process and give the possibilities of measurement of mass transfer. Study of fluid inclusion veins has determined the temperature pressure conditions: thermal effect of the basement and decrease of temperature and pressure with the age of various synkinematic veins.Characteristic examples of the behaviour of a heterogeneous material during coaxial and non-coaxial deformation are shown:
- 1. (1) Successive different asymmetrical folds, various cleavages and fractures appear in a shear zone parallel to the main fabric with variations of thickness and rock behaviour.
- 2. (2) Evolution of cleavage in such a shear zone (with or without slipping) is linked to the relations between the rotation of contraction direction and the rate of the cleavage process.
- 3. (3) Fold axes changed from the horizontal y direction to the vertical (or E—W transversal to the crystalline massif) X direction, with increase of the (X/Z) and (X/Y) ratios (obtained by fossils and reconstructed fold shape). This strain is always heterogeneous and the most deformed zone frequently evolves to discontinuities with slip.
- 4. (4) Indentation exists on all scale: from hard object (100 μ, with parenthesis form of pressure solution cleavage apparent on map distribution of various element) to basement block (with variation of strain value in the indented cover).
63.
64.
Pierre Adam Philippe Schaeffer Sylvestre Gug Estelle Motsch Pierre Albrecht 《Organic Geochemistry》2009,40(8):885-894
A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches. 相似文献
65.
Using an Atmospheric Global Circulation Model, we assess the relevance of selected atmospheric mechanisms for climate evolution of Saharan and sub-Saharan regions since the Miocene. First, we test the influence of the East-African Rift System uplift on atmospheric dynamics. Although the uplift played an important role in triggering East-African rainfall, no significant impact over central and western Africa has been detected. We also analyse the feedbacks of a giant lake on the climate of Chad basin. First results infer a negative feedback of the giant lake on the water balance, as convection is weakened by the cold water surface and as water evaporated from the lake does not feed the basin hydrological cycle. Lastly, we suggest that colder than present sea surface temperatures over the Gulf of Guinea reinforce the West-African monsoon, by enhancing the moisture advection engine via stronger thermal contrast between the ocean and the continent. 相似文献
66.
67.
Review: Microbial biocenoses in pristine aquifers and an assessment of investigative methods 总被引:2,自引:6,他引:2
The current knowledge of microbial biocenoses (communities) in pristine aquifers is presented in a review, which also discusses their relevance for questions of groundwater protection. Aquifers are heterogeneous on all scales and structured in a variety of habitats. The void spaces in many aquifers are small. The biocenoses are thus predominantly composed of microorganisms and, often, microinvertebrates. Larger voids and macroorganisms occur in karst cavities. Due to the absence of light, the biocenoses depend on chemical energy resources, which are, however, scarce in non-contaminated groundwater. The microorganisms thus show small cell sizes, low population densities and reduced activity; they developed specific strategies to survive oligotrophic conditions. The review also discusses the impact of contamination on the biocenoses, and the potential use of the biocenoses or specific organisms as indicators for groundwater quality, and the limits of this approach. Bacteria are either planktonic or attached to aquifer material, which requires both fluid and solid phase sampling. Most groundwater bacteria are viable but non-culturable. Consequently, cultivation techniques give an incomplete picture of the biocenoses, while methods from molecular microbiology provide genetic fingerprints of the entire community. Different analytical methods are available to count microorganisms, identify species, characterise microbial diversity, and measure activity. 相似文献
68.
Pierre Lanari Yann Rolland Stéphane Schwartz Olivier Vidal Stéphane Guillot Pierre Tricart Thierry Dumont 《地学学报》2014,26(2):130-138
Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and 40Ar/39Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision. 相似文献
69.
Studies in the past have tried to reproduce the mechanical behaviour of granular materials by proposing constitutive relations based on a common assumption that model parameters and parameters describing the properties, including gradation of individual grains are inevitably linked. However successful these models have proved to be, they cannot account for the changes in granular assembly behaviour if the grains start to break during mechanical loading. This paper proposes to analyse the relation between grading change and the mechanical behaviour of granular assembly. A way to model the influence of grain breakage is to use a critical state‐based model. The influence of the amount of grain breakage during loading, depending on the individual grain strength and size distribution, can be introduced into constitutive relations by means of a new parameter that controls the evolution of critical state with changes in grain size distribution. Experimental data from a calcareous sand, a quartz sand, and a rockfill material were compared with numerical results and good‐quality simulations were obtained. The main consequences of grain breakage are increased compressibility and a gradual dilatancy disappearance in the granular material. The critical state concept is also enriched by considering its overall relation to the evolution of the granular material. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献