Diisopropanolamine Biodegradation Potential at Sour Gas Plants

The potential for aerobic and anaerobic biodegradation of a sour gas treatment chemical, diisopropanolamine (DIPA), was studied using contaminated aquifer materials from three sour gas treatment sites in western Canada. DIPA was found to be readily consumed under aerobic conditions at 8°C and 28°C in shake flask cultures incubated with aquifer material from each of the sites, and this removal was characterized by first-order kinetics. In addition, DIPA biodegradation was found to occur under nitrate-, Min(IV)., and Fe(III)-reducing conditions at 28°C, and in some cases at 8°C, in laboratory microcosms, DIPA loss corresponded to consumption of nitrate, and production of Mn(II) and Fe(II) in viable microcosms compared to corresponding sterile controls. A threshold DIPA concentration near 40 mg/L was observed in the anaerobic microcosms. This report provides the first evidence that DIPA is biodegraded under anaerobic conditions, and our data suggest that biodegradation may contribute to DIPA attenuation under aerobic and anaerobic conditions in aquifers contaminated with this sour gas treatment chemical.     

The Δθ–zs relation for gravitational lenses as a cosmological test

Recently, Park &38; Gott claimed that there is a statistically significant, strong, negative correlation between the image separation Δθ and source redshift z _s for gravitational lenses. This is somewhat puzzling if one believes in a flat ( k  = 0) universe, since in this case the typical image separation is expected to be independent of the source redshift, while one expects a negative correlation in a k  = −1 universe and a positive one in a k  = +1 universe. Park &38; Gott explored several effects that could cause the observed correlation, but no combination of these can explain the observations with a realistic scenario. Here, I explore this test further in three ways. First, I show that in an inhomogeneous universe a negative correlation is expected regardless of the value of k . Secondly, I test whether the Δθ– z _s relation can be used as a test to determine λ₀ and Ω₀, rather than just the sign of k . Thirdly, I compare the results of the test from the Park &38; Gott sample with those using other samples of gravitational lenses, which can illuminate (unknown) selection effects and probe the usefulness of the Δθ– z _s relation as a cosmological test.     

Rapid underway profiling of water quality in Queensland estuaries

We present an overview of a portable underway water quality monitoring system (RUM-Rapid Underway Monitoring), developed by integrating several off-the-shelf water quality instruments to provide rapid, comprehensive, and spatially referenced 'snapshots' of water quality conditions. We demonstrate the utility of the system from studies in the Northern Great Barrier Reef (Daintree River) and the Moreton Bay region. The Brisbane dataset highlights RUM's utility in characterising plumes as well as its ability to identify the smaller scale structure of large areas. RUM is shown to be particularly useful when measuring indicators with large small-scale variability such as turbidity and chlorophyll-a. Additionally, the Daintree dataset shows the ability to integrate other technologies, resulting in a more comprehensive analysis, whilst sampling offshore highlights some of the analytical issues required for sampling low concentration data. RUM is a low cost, highly flexible solution that can be modified for use in any water type, on most vessels and is only limited by the available monitoring technologies.     

Recent estuarine sedimentation rates from shallow inter-tidal environments in western Scotland: implications for future sea-level trends and coastal wetland development

During the mid-late Holocene large sections of the Scottish coastline have been characterized by falling relative sea-levels resulting from differential glacio-isostatic uplift of this region of northern Britain. The complex interplay between crustal and sea-level movements continues to influence the morphological development of the Scottish coast. A number of geophysical models predict ongoing uplift of the Scottish landmass. However, a number of recent studies based upon the analysis of satellite altimetry data indicate a late 20th Century acceleration in the rate of eustatic sea-level rise.Detailed geochemistry, radiometric dating, and diatom analysis on selected sediment cores from four mature coastal marsh environments in Argyll, western Scotland, provides an opportunity to investigate the linkages between Twentieth century crustal movements, eustatic sea-level rise and recent rates of sedimentation recorded within marsh sediments across the proposed Scottish glacio-isostatic uplift dome.Solid-phase major and trace element geochemistry has been used to examine the extent to which post-depositional physical disturbance and/or chemical reactions may have influenced the reliability of the radiometric dating methods. Geochemical data indicate that the evolution of these marsh environments has not been significantly influenced by physical disturbance and overall the supply of minerogenic material to the marshes has been quite uniform.Vertical distributions of ²¹⁰Pb_excess and ¹³⁷Cs activity have been measured and used to develop models of recent marsh vertical accretion. Dating of the cores reveals subtle variations in the rates of sediment accumulation over the last c. 70 years between sites. For much of the last hundred years or so, sedimentation rates have been in good overall agreement with various estimations for sea-level rise, although at the more easterly sites these estimates are generally exceeded. However, quasi-equilibrium between marsh sedimentation and sea-level rise for much of the Twentieth Century is indicated from the Diatom analysis.Over the most recent period of marsh development (<10 years), a significant increase in the rate of surface sedimentation is recorded at all sites across the study area. Diatom analysis of these surface layers reveals an increase in the relative abundance of marine (polyhalobous) taxa in the near-surface sediments. This signifies a very recent increase in the rate of regional relative sea-level rise indicating that a regional threshold in coastal forcing has now been exceeded.These findings provide clear evidence that recent relative sea-level rise is now outpacing estimated rates of glacio-isostatic adjustment (GIA) across the proposed Scottish uplift dome.     

Late Quaternary landscape reconstruction and geochronology in the northern Pampas of Buenos Aires province,Argentina

This paper reports the main sedimentary characteristics, soil micromorphology and optically-stimulated luminescence (OSL) ages, and details the pedosedimentary reconstruction, of the Hudson site situated in the northern Pampas of Buenos Aires province. It also provides the OSL chronology and a reinterpretation of previously reported micromorphological features for the nearby site of Gorina. Finally, the stratigraphic records of both sites are compared and the main environmental events discussed in a regional context.At Hudson, situated at a low altitude environment close to the coastal plain, the basal fine-grained paludal deposits were unconformably covered by coastal marine sediments with an OSL age of ca. 128 ka supporting its correlation with the high stand of sea level of marine isotope stage 5e. A paleosol developed on the marine deposits and the underlying paludal sediments. OSL ages suggest that soil development and its subsequent erosion occurred over some period between ca. 128 and 54 ka. Fine sediment accumulation in a paludal environment continued until prior to ca. 23 ka when the accumulation of the uppermost loess mantle started. It continued until the early Holocene when present soil development began. At Gorina, OSL ages suggest that the upper part of the pedocomplex formed at some stage between ca. 194 and 56 ka. Loess then accumulated followed by an erosional phase; loess deposition restarted by ca. 29 ka and continued until the beginning of the Holocene (ca. 9 ka) when the present land surface was established.The stratigraphic and paleoenvironmental differences exhibited by the Hudson and Gorina records result from their contrasting geomorphological settings. The OSL geochronology suggests that the last interglacial (MIS 5) at Hudson is marked by the accumulation of marine deposits (MIS 5e) and the subsequent development of a paleosol. The equivalent soil-forming interval at Gorina is represented by the upper part of the buried pedocomplex. Both at Gorina and Hudson, loess accumulation was dominant especially during MIS 2. Loess accumulation continued during MIS 1 until the early Holocene with apparently somewhat higher sedimentation rates in Hudson. Pedogenesis has been predominant during the rest of the Holocene, resulting in the formation of the surface soil profiles.     

Modeling IR spectral energy distributions: a?pilot study of?starburst parameters and silicate absorption curves for some GOALS galaxies

This paper describes a pilot study into the spectral energy distribution (SED) fitting and the derivation of physical parameters for 19 galaxies observed as part of the Great Observatories All-sky LIRG Survey (GOALS) survey as observed with the Spitzer Space Telescope. For this we have used the pan-spectral fitting tools developed in a series of papers by Dopita and his co-workers. We show that the standard Lee and Draine ??astronomical silicate?? model cannot provide a good fit to the silicate absorption features as observed in the heavily dust-extinguished (A _V??50 mag.) starbursts. We have derived an empirical fit to the ??starburst silicate?? absorption in these objects. This absorption curve is consistent with the silicate grains being systematically larger in starburst environments than in the local Galactic interstellar medium. We demonstrate the sensitivity of the SED fitting to each of the fitted parameters, and derive these parameters for those galaxies which do not have an embedded AGN. This technique is simple and provides reasonably robust and uniform parameters for the starburst, especially as far as the star formation rate, population of old stars, compactness of the starburst region and total foreground extinction are concerned. However, the chemical abundances and the optical extinction cannot be reliably determined by this analysis, and optical SEDs will also be required to provide a complete characterization of the starburst region and of the surrounding galaxy.     

The geologist down your street: three famous geologists from a small town in Lancashire,England

The town of Colne in Pennine east Lancashire, northern England—once a centre of the textiles trade—is now best known locally as the home of Boundary Mill ‘shopping experience’. But there is more to the town than meets the eye, including three significant geologists.