Quantitative models for reconstructing catchment ice-extent using physical-chemical characteristics of lake sediments

The physical characteristics of surface sediments from a suite of pristine lakes on Signy Island, maritime Antarctic, were used to develop a quantitative link between catchment ice-extent and lake-sediment response. Percentage dry weight, median particle size, percentage loss-on-ignition and wet density of the lakes' surface sediments were the most significant variables explaining contemporary catchment ice-extent. Two independent reconstruction models – Partial Least Squares (PLS) and a Modern Analog Technique (MAT) – were applied to dated sediment cores at two sites on Signy Island. The validity of the reconstructions was tested against historical information on catchment ice-extent. With sufficiently high sedimentation rates and sampling resolution, the models can predict sub-decadal changes in ice-extent. The model results are best regarded as indicators of erosion resulting from meltwater activity in the catchment. Comparison of results with Twentieth Century climate records affirms the hypothesis that climatic warming is the most likely cause for the ice retreat observed on Signy Island during the last 40 yrs. Similar reconstruction models using these simple sedimentary measures could be developed for analogous locations in the Antarctic and in Arctic and Alpine regions.     

SCAP meeting no.10

Mike Bode , Phil Charles and Carlos Frenk report the minutes of the tenth meeting of the Standing Conference of Astronomy Professors, held at the RAS, Burlington House on 30 January 2001.     

Salt-bearing fumarole deposits in the summit crater of Oldoinyo Lengai, Northern Tanzania: interactions between natrocarbonatite lava and meteoric water

Oldoinyo Lengai in the Northern Tanzania rift is the only active nephelinite–carbonatite stratovolcano. We report the discovery of thermonatrite, aphthitalite, halite and sylvite fumarole deposits on recent natrocarbonatite lava flows erupted in the summit crater during the wet season. These salt deposits occur as delicate, concave fringes or tubes that line the cooling cracks in the lava flows and consist of intergrowths of euhedral crystals. The presence of a dark altered zone, depleted in halides and alkalies, adjacent to cooling cracks and observations of steam fumaroles emanating from the fractures suggest that the salts are formed by sublimation from saturated vapours generated by the extrusion of lavas over meteoric water. The crystallisation sequence recorded in the salts suggests that mixing between meteoric steam and magmatic CO₂ and H₂S occurs at high temperatures resulting in the sublimation of carbonates and sulphates. At lower temperatures the vapours are dominated by meteoric steam and sublimate halides. The high solubility of the fumarole salts within meteoric water and their formation only during the wet season implies that these are ephemeral deposits that are unlikely to be preserved in the geological record.     

Teacher''s Aide: Modeling Hole-Effect Variograms of Lithology-Indicator Variables

Common variogram models, such as spherical or exponential functions, increase monotonically with increasing lag distance. On the other hand, a hole-effect variogram typically exhibits sinusoidal waves that form peaks and troughs, thereby conveying the cyclicity of the underlying phenomenon. In order to incorporate this cyclicity into a stochastic simulation, hole effects in the experimental variogram must be fitted appropriately. In this paper, we recommend use of several multiplicative-composite variogram models to fit hole-effect experimental variograms. These consist of a cosine function to provide wavelength and phase of cyclicity, multiplied by a monotonic model (e.g., spherical) to attenuate amplitudes of the cyclical peaks and troughs. These composite models can successfully fit experimental lithology-indicator variograms that contain a range of cyclicities, although experimental variograms with poor cyclicity require special considerations.     

Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.