Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

Berriasian (Lower Cretaceous) brachiopods from the Crimea

Four successive assemblages of Berriasian brachiopods distinguished for the first time in the Crimea are correlated with concurrent subdivisions of the ammonoid scale. Berriasian brachiopods are represented by 44 species of 27 genera and 14 families, which are most complete in terms of taxonomic composition as compared to other concurrent brachiopod faunas known elsewhere. The assemblages are dominated by local species. As is proved, the Berriasian brachiopods studied are appropriate for age determination, subdivision and correlation of their host deposits. Their geographic distribution that has been analyzed elucidates connections of the Berriasian sea basins within the Mediterranean paleozoogeographic region.     

New data on Upper Kimmeridgian-Tithonian biostratigraphy and ammonites of the eastern Crimea

Based on ammonites, Upper Kimmeridgian sediments are first established in the Crimean Mountains. The Kimmeridgian-Tithonian boundary recognizable in a continuous section is placed inside the Dvuyakomaya Formation of uniform largely clayey sediments. Assemblages of Kimmeridgian ammonites Lingulaticeras cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Oloriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian forms (?Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel) are described. A new biostratigraphic scheme proposed for the upper Tithonian-Berriasian of the Crimean Mountains includes the following new biostratigraphic units: the Euvirgalithacoceras cf. tantalus Beds of the upper Kimmeridgian, ?Lingulaticeras efimovi Beds of the lower Tithonian, and Oloriziceras cf. schneidi and Paraulacosphinctes cf. transitorius beds of the upper Tithonian. The middle Tithonian is proposed to consist of the fallauxi and semiforme (presumably) zones. The ammonities found determine the early Kimmeridgian-Berriasian age of the Dvuyakornaya Formation that is most likely in tectonic contact with the underlying Khutoran Formation.     

The Kyrgyz-Ata Synform in the South Tien Shan: Structural and kinematic aspects of its evolution

The complexes of metamorphic rocks that take part in the tectonic structure of the South Tien Shan are mostly confined to the cores of large synforms and occupy high structural position therein. Problems of their age, origin, metamorphic conditions, and relationships with the adjacent unmetamorphosed Paleozoic sequences have remained debatable throughout the history of geological investigations. The results of detailed studies of the Kyrgyz-Ata Synform, a typical structure of the Turkestan-Alay Zone in the South Tien Shan, are reported in this paper. The metamorphic rocks of the Kan Group participate in the structure of this synform. On the basis of the study of structural assemblages and the kinematic analysis, it is concluded that the multistage evolution of this tectonic unit proceeded under transpressive conditions of volcanic trough “crushing.” The detailed study of rock alteration in the contact zone between the Kan Group and the Middle Devonian basic volcanic rocks allowed us to suggest that the metamorphic Kan Group is not a self-dependent stratigraphic unit but represents an infrastructure (a metamorphosed analogue of the volcanic sequence and underlying rocks) displaced tectonically over its own suprastructure.     

Managanese and iron in the White Sea: Sedimentation and diagenesis

Iron and manganese in bottom sediments studied along the sublatitudinal transect from Kandalaksha to Arkhangelsk are characterized by various contents and forms depending on sedimentation environments, grain size of sediments, and diagenetic processes. The latter include redistribution of reactive forms leading to enrichment in Fe and Mn of the surface sediments, formation of films, incrustations, and ferromanganese nodules. Variations in the total Fe content (2–8%) are accompanied by changes in the concentration of its reactive forms (acid extraction) and the concentration of dissolved Fe in the interstitial water (1–14 μM). Variations in the Mn content in sediments (0.03–3.7%) and the interstitial water (up to 500 μM) correspond to a high diagenetic mobility of this element. Changes in the valence of chemical elements results in the redox stratification of sediment strata with maximum concentrations of Fe, Mn, and sulfides. Organic matter of sediments with a considerable terrestrial constituent is oxidized by bottom water oxygen mainly at the sediment surface or in anaerobic conditions within the sediment strata. The role of inorganic components in organic matter oxidation changes from surface sediments, where manganese oxyhydroxide dominates among oxidants, to deeper layers, where sulfate of interstitial water serves as the main oxidant. Differences in river runoff and hydrodynamics are responsible for geochemical asymmetry of the transect. The deep Kandalaksha Bay serves as a sediment trap for manganese (Mn content in sediments varies within 0.5–0.7%), whereas the sedimentary environment in the Dvina Bay promotes its removal from sediments (Mn 0.05%).