Chromite in the Paricutin lava flows (1943–1952)

Small euhedral chromite crystals are found in olivine macrophenocrysts (Fo_80–84) from the basaltic andesites (150 ppm Cr) erupted in 1943–1947, and in orthopyroxene macrophenocrysts of the andesites (75 ppm Cr) erupted in 1947–1952. The majority of the chromite octahedra are 5–20 μm in diameter, and some are found in clusters and linear chains of three or more oriented chromite crystals. The composition of the majority of the chromite grains within olivine and orthopyroxene macrophenocrysts is Fe²⁺/(Fe²⁺+Mg)=0.5–0.6, Cr/(Cr+Al)=0.5–0.6 and Fe³⁺/(Fe³⁺+Al+Cr)=0.2–0.3. The chromite crystals in contact with the groundmass are larger, subhedral, and grade in composition from chromite cores to magnetite rims. Comparison of the composition of chromite with those of other volcanic rocks shows that the most primitive Paricutin chromite is richer in total iron and higher in Fe³⁺/(Fe³⁺+Al+Cr) than primary chromite in most lavas. The linear chains of oriented chromite octahedra are found in olivine and orthopyroxene macrophenocrysts, and in the groundmass. These chromite chains are thought to result from diffusion-controlled crystallization because of the very high partition coefficient (1000) of Cr between chromite and melt. We conclude that chromite was a primary phase in the lavas at the time of extrusion and that magnetite only crystallized after extrusion during cooling of the lava flows. The presence of chromite microphenocrysts in andesitic lavas containing as little as 70 ppm Cr can be explained by dissolved H₂O in the melt depressing the liquidus temperature for orthopyroxene such that chromite becomes a liquidus phase. The influence of dissolved H₂O can also explain the lack of plagioclase macrophenocrysts in most of the lavas and the relatively high partition coefficient (20) of Ni between olivine and melt and the high partition coefficient (40) of Cr between orthopyroxene and melt. The liquidus temperature of the basaltic andesite is estimated to have been less than 1140°C, assuming H₂O>1 wt.%, and the log f_O2 to have been above that of the QFM buffer. The chromite and orthopyroxene liquidus temperature of the andesites, assuming H₂O>1 wt.%, is estimated to have been 1100°C or less. The derivation of the later andesites from the earlier basaltic andesites has been explained by a combination of fractional crystallization of olivine, orthopyroxene and plagioclase, and assimilation of xenoliths. The significantly lower Cr, Ni and Mg of the andesites may have been in part due to the separation of olivine macrophenocrysts plus enclosed chromite crystals from the earlier basaltic andesites.     

Seasonal uranium distributions in the coastal waters off the Amazon and Mississippi Rivers

The chemical reactivity of uranium was investigated across estuarine gradients from two of the world’s largest river systems: the Amazon and Mississippi. Concentrations of dissolved (<0.45 μm) uranium (U) were measured in surface waters of the Amazon shelf during rising (March 1990), flood (June 1990) and low (November 1991) discharge regimes. The dissolved U content was also examined in surface waters collected across estuarine gradients of the Mississippi outflow region during April 1992, August 1993, and November (1993). All water samples were analyzed for U by isotope dilution inductively coupled plasma mass spectrometry (ICP-MS). In Amazon shelf surface waters uranium increased nonconservatively from about 0.01 μg I^?1 at the river’s mouth to over 3 μg I^?1 at the distal site, irrespective of river discharge stage. Observed large-scale U removal at salinities generally less than 15 implies a) that riverine dissolved U was extensively adsorbed by freshly-precipitated hydrous metal oxides (e.g., FeOOH, MnO₂) as a result of flocculation and aggregation, and b) that energetic resuspension and reworking of shelf sediments and fluid muds on the Amazon shelf released a chemically reactive particle/colloid to the water column which can further scavenge dissolved U across much of the estuarine gradient. In contrast, the estuarine chemistry of U is inconclusive within surface waters of the Mississippi shelf-break region. U behavior is most likely controlled less by traditional sorption and/or desorption reactions involving metal oxides or colloids than by the river’s variable discharge regime (e.g., water parcel residence time during estuarine mixing, nature of particulates, sediment storage and resuspension in, the confined lower river), and plume dispersal. Mixing of the thin freshwater lens into ambient seawater is largely defined by wind-driven rather than physical processes. As a consequence, in the Mississippi outflow region uranium predominantly displays conservative behavior; removal is evident only during anomalous river discharge regimes. ‘Products-approach’ mixing experiments conducted during the Flood of 1993 suggest the importance of small particles and/or colloids in defining a depleted U versus salinity distribution.     

Relative importance of grazing and nutrient controls of macroalgal biomass in three temperate shallow estuaries

Macroalgal biomass and competitive interactions among primary producers in coastal ecosystems may be controlled by bottom-up processes such as nutrient supply and top-down processes such as grazing, as well as other environmental factors. To determine the relative importance of bottom-up and top-down processes under different nutrient loading conditions, we estimated potential amphipod and isopod grazer impact on a dominant macroalgal species in three estuaries in Waquoit Bay, Cape Cod, Massachusetts, that are subject to different nitrogen loading rates. We calculated growth increases and grazing losses in each estuary based on monthly benthic survey data of macrophyte biomass and herbivore abundance, field grazing rates of amphipods (Microdeutopus gryllotalpa andCymadusa compta) and an isopod (Idotea baltica) on the preferred and most abundant macroalga (Cladophora vagabunda) and laboratory grazing rates for the remaining species, and in situ macroalgal growth rates. As nitrogen loading rates increased, macroalgal biomass increased (3×), eelgrass (Zostera marina) was lost, and herbivore abundance decreased (1/4×). Grazing rates increased with relative size of grazer (I. baltica > C. compta > M. gryllotalpa) and, for two of the three species investigated, were faster on algae from the high-nitrogen estuary in comparison to the low-nitrogen estuary, paralleting the increased macroalgal tissue percent nitrogen with nitrogen load. Macroalgal growth rates increased (2×) with increasing nitrogen loading rate. The comparison between estimated growth increases versus losses ofC. vagabunda biomass to grazing suggested first, that grazers could lower macroalgal biomass in midsummer, but only in estuaries subject to lower nitrogen loads. Second, the impact of grazing decreased as nitrogen loading rate increased as a result of the increased macroalgal growth rates and biomass, plus the diminished abundance of grazers. This study suggests the relative impact of top-down and bottom-up controls on primary producers varies depending on rate of nitrogen loading, and specifically, that the impact of herbivory on macroalgal biomass decreases with increasing nitrogen load to estuaries.     

Use of annular flumes to determine the influence of current velocity and bivalves on material flux at the sediment-water interface

A benthic annular flume for both laboratory and in situ deployment on intertidal mudflats is described. The flume provides a means of quantifying material flux (i.e., biodeposition of suspended particulates, sediment resuspension, nutrients, oxygen, and contaminants) across the sediment-water interface in relation to changes in current velocity and benthic community structure and/or population density of key macrofauna species. Flume experiments have investigated the impact of the infaunal bivalveMacoma balthica and the epifaunal bivalveMytilus edulis on seston and sediment flux at the sediment-water interface. The bioturbatorMacoma was found to increase the sediment resuspension and/or erodability by 4-fold, at densities similar to those recorded at the Skeffling mudflat (Humber estuary) (i.e., >1000 individuals m^?2). There was a significant correlation between sediment resuspension andMacoma density (r=0.99; p<0.001), which supported previous in situ field observations indicating bioturbation byMacoma enhanced sediment erodability. Biodeposition rates (g m^?2 h¹) ofMytilus edulis andCerastoderma edule were quantified and related to changes in population density in a mussel bed (Cleethorpes, Humber estuary). Biodeposition rates were up to 40-times the natural sedimentation rates. At the highest mussel bed densities (i.e., 50–100% cover or >1400 mussels m^?2) the physical presence of this epifaunal bivalve on the sediment surface reduced erosion by 10-fold. The shift from net biodeposition to net erosion occurred at current velocities of 20–25 cm s^?1. These results demonstrate that infaunal and epifaunal bivalves can have a significant impact on seston flux or sediment deposition and on sediment resuspension or erodability in estuaries where there are extensive mudflats.     

Seasonal dynamics of aggregates and their typical biocoenosis in the Elbe Estuary

In 1995, an extensive investigation was carried out in the Elbe Estuary in Germany. Special attention was paid to organisms, including bacteria, amoebae, ciliates, flagellates, rotifers, larvae ofDreissena polymorpha, and nematodes, dispersed in the water column and associated firmly or loosely with different types of aggregates. The abundance, size, and colonization by microorganisms of the aggregates varied during the seasons. The largest aggregates were found during spring and summer, when diatoms, rotifers, and crustaceans were present. The most aggregates were encountered in spring and from summer to autumn. Most of the species observed during the study were more common in pelagic habitats than in benthic ones. However, the presence of ciliates in the groups Hypotrichida and Sessilida as well as as flagellates in the groups Biosoecida, Cercomonadida, Choanoflagellida, Chrysomonadida, Kinetoplastida, and amoebae and some nematodes in the open water depends, upon the availability of surfaces, because they are sessile or poor swimnters, and some flagellates and amoebae need to attach themselves to an object to feed. Most organisms were much more abundant in or on aggregates than in the surrounding water during spring and summer, which indicates that aggregates enhance the habitat and promote the development of the organisms. From spring through autumn, the structure of the community associated with the aggregates is influenced by the pelagic environment. The presence of the species in the benthic community was detected only during summer.     

The Population of KPC-Scale Flat-Spectrum Radio Sources

In this paper we present a subsample of 55 flat-spectrum radio sources dominated by (∼ 100 mas) kpc-scale structure, selected from a parent sample of 1665 VLA sources. Most are core-jets and 23 are CSO/MSO candidates. Properties of the subsample are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Observations of Electromagnetically Coupled Dust in the Jovian Magnetosphere

We report on dust measurements obtained during the seventh orbit of the Galileo spacecraft about Jupiter. The most prominent features observed are highly time variable dust streams recorded throughout the Jovian system. The impact rate varied by more than an order of magnitude with a 5 and 10 hour periodicity, which shows a correlation with Galileo's position relative to the Jovian magnetic field. This behavior can be qualitatively explained by strong coupling of nanometer-sized dust to the Jovian magnetic field. In addition to the 5 and 10 h periodicities, a longer period which is compatible with Io's orbital period is evident in the dust impact rate. This feature indicates that Io most likely is the source of the dust streams. During a close (3,095 km altitude) flyby at Ganymede on 5 April 1997 an enhanced rate of dust impacts has been observed, which suggests that Ganymede is a source of ejecta particles. Within a distance of about 25 R_J(Jupiter radius, R_J= 71,492 km) from Jupiter impacts of micrometer-sized particles have been recorded which could be particles on bound orbits about Jupiter. This revised version was published online in July 2006 with corrections to the Cover Date.     

The ortho- to para- ratio of H2 in the starburst of NGC 253

We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H₂ lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H₂ to be ∼2. This indicates that the bulk of the H₂ emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H₂ emission arises from PDRs, it is likely that the ratio of H₂ to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.     

Alkaline ultramafic lamprophyres and associated carbonatite dykes from the Kalix area,northern Sweden

Alkahne ultramafic lamprophyres and associated carbonatite dykes form north-south trending dyke swarms. The lamprophyres are sub-divided into micaceous, picritic and breccia varieties. Carbonatites sensu stricto (beforsites) occur very subordinate.The dykes of the Kalix area show great similarities to petrographically related rocks from other Scandinavian occurrences (Sokli, Alnö and Fen). Major differences are found in their tectonic setting (regularly striking dyke swarms) and the REE-pattern (distinctly negative cerium anomalies).The following petrogenetic model is advanced for the Kalix dykes: (1) partial melting of upper mantle material, (2) Intrusion into a crustal magma chamber, fractional crystallization, (3) Interactions between crystallized material and the volatile phase (light REE depletion, oxidation of cerium), (4) Intrusion in fracture zones under horizontal tension.

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Zusammenfassung Alkalin-ultrabasiscbe Lamprophyre und begleitende KarbonatitgÄnge bilden nordsüdlidi streichende GangschwÄrme. Die Lamprophyre zeigen gewisse Ähnlichkeiten zu alnöitischen und kimberlitischen Gesteinen; sie wurden unterteilt in glimmerreiche und pikritische Lamprophyre sowie Brekzien. Karbonatite im engeren Sinn treten nur sehr untergeordnet auf; sie sind als Beforsite charakterisiert.Die Ganggesteine des Kalix-Gebiets weisen gro\e Ähnlichkeiten mit petrographiscb verwandten Gesteinen von anderen skandinavischen Vorkommen (Sokli, Alnö und Fen) auf. GrundsÄtzliche Unterschiede finden sich vor allem im tektonischen Auftreten (ziemlich konstant streichende GangschwÄrme) und im Verteilungsmuster der seltenen Erden (deutlich negative Cer-Anomalien).Die Bildung der Kalix-GÄnge wird folgenderweise erklÄrt: (1) Partielle Aufschmelzung des oberen Mantels, (2) Intrusion der Schmelze in eine krustale Magmakammer, gefolgt von fraktionierter Kristallisation, (3) Reaktion zwischen vorzugsweise kristallisiertem Material und der volatilen Phase (Entarmung an leichten seltenen Erden, Oxidation des Cers), (4) Intrusion in Bruchzonen, die horizonteller Dehnung ausgesetzt sind.

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Résumé Des lamprophyres alcalins ultrabasiques accompagnés de carbonatites forment des essaims de dykes de direction nord-sud. Les lamprophyres se subdivisent en variétés micacée, picritique ainsi que brÊchique. Les carbonatites sensu stricto sont rares et sont plutÔ des beforsites.Les dykes de la région de Kalix présentent de grandes similitudes avec des roches pétrographiquement apparentées d'autres localités Scandinaves (Sokli, Alnö et Fen). Les différences essentielles sont dues à leur situation tectonique (essaims de dykes de direction régulière) ainsi qu'à la distribution des Terres Rares (anomalie négative distincte de cérium).Le modèle pétrogénétique suivant est proposé pour les dykes de Kalix: (1) fusion partielle de matériau du manteau supérieur, (2) intrusion dans une chambre magmatique de l'écorce et cristallisation fractionnée, (3) interaction entre le material déjà cristallisé et la phase volatile (appauvrissement des éléments légers des Terres Rares, oxydation du cérium), (4) intrusion le long de zones de fracture dans des conditions d'extension horizontale.

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