Zwei Hornblenden aus Metabasiten der Hochalm-Ankogelgruppe

Ohne Zusammenfassung     

US institutional pathways to clean coal and shale gas: lessons for China

China's 12th Five-Year Plan (2011–2015) envisages that shale gas and coal will be central to its energy future. However, for China to meet the energy security and climate change objectives set out in its 12th Five-Year Plan it will be reliant on the widespread commercial deployment of two key technologies; hydraulic fracturing combined with horizontal drilling for shale gas, and carbon capture and storage (CCS) for coal. China is moving to acquire these technologies through technology transfer and diffusion from the US, but progress has been slow, and neither is currently available in China on a commercial scale. Drawing on interviews in the US and China, this article argues that China's expectation of technology from the US may well be disappointed because of factors unique to the US institutional environment that have made the development of fracking technology possible and hinder the development of CCS technology at a commercial scale.

Policy relevance

If China is to meet the energy security and climate change objectives set out in its 12th Five-Year Plan it will be reliant on the widespread commercial deployment of fracking and clean coal technologies. While China expects to acquire these technologies via technology transfer and diffusion from the US, progress has been slow. Because of factors unique to the US institutional environment the availability of both technologies on a commercial scale in China is unlikely in the coming years. As a result, Chinese policy makers would be well-advised not to count on these technologies to meet their energy and climate goals.     

Denitrification capacity in a subterranean estuary below a Rhode Island fringing salt marsh

Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary, the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary below a Rhode Island fringing salt marsh.¹⁵N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

3D inversion of gravity data by separation of sources and the method of local corrections: Kolarovo gravity high case study

We present a novel methodology for 3D gravity/magnetic data inversion. It combines two algorithms for preliminary separation of sources and an original approach to 3D inverse problem solution. The first algorithm is designed to separate sources in depth and to remove the shallow ones. It is based on subsequent upward and downward data continuation. For separation in the lateral sense, we approximate the given observed data by the field of several 3D line segments. For potential field data inversion we apply a new method of local corrections. The method is efficient and does not require trial-and-error forward modeling. It allows retrieving unknown 3D geometry of anomalous objects in terms of restricted bodies of arbitrary shape and contact surfaces. For restricted objects, we apply new integral equations of gravity and magnetic inverse problems. All steps of our methodology are demonstrated on the Kolarovo gravity anomaly in the Danube Basin of Slovakia.     

Magnetic cleansing of weathered/tarry oiled feathers--the role of pre-conditioners

Iron powder has previously been demonstrated to be effective in the removal, via magnetic harvesting, of a wide variety of oil contaminants from feathers and plumage. This study investigates the efficacy of magnetic cleansing for the removal from feathers of tarry contamination that has been allowed to weather. Clusters of feathers from Mallard duck (Anas platyrhnchos) and Little Penguin (Eudyptula minor) were completely immersed in a tarry contaminant and allowed to weather from one to fourteen days. The contaminant was removed using a magnetic cleansing protocol and the removal efficacy assessed gravimetrically. For one, seven and fourteen days of weathering, a final removal (after fourteen treatments) of more than 99% and 97% was achieved for duck feathers and penguin feathers, respectively. Repeating the experiments (for a seven-day weathering period) for both duck and penguin feathers, with the judicious application of a pre-conditioner (olive oil), further improved removal efficacy. A convenient method to screen for improved pre-conditioning agents is suggested.     

A mineral magnetic and scaled-chrysophyte paleolimnological study of two northeastern Pennsylvania lakes: records of fly ash deposition, land-use change, and paleorainfall variation

A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. ²¹⁰Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the ²¹⁰Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Variations in the geomagnetic dipole moment during the Holocene and the past 50 kyr

All absolute paleointensity data published in peer-reviewed journals were recently compiled in the GEOMAGIA50 database. Based on the information in GEOMAGIA50, we reconstruct variations in the geomagnetic dipole moment over the past 50  kyr, with a focus on the Holocene period. A running-window approach is used to determine the axial dipole moment that provides the optimal least-squares fit to the paleointensity data, whereas associated error estimates are constrained using a bootstrap procedure. We subsequently compare the reconstruction from this study with previous reconstructions of the geomagnetic dipole moment, including those based on cosmogenic radionuclides (¹⁰Be and ¹⁴C). This comparison generally lends support to the axial dipole moments obtained in this study. Our reconstruction shows that the evolution of the dipole moment was highly dynamic, and the recently observed rates of change (5% per century) do not appear unique. We observe no apparent link between the occurrence of archeomagnetic jerks and changes in the geomagnetic dipole moment, suggesting that archeomagnetic jerks most likely represent drastic changes in the orientation of the geomagnetic dipole axis or periods characterized by large secular variation of the non-dipole field. This study also shows that the Holocene geomagnetic dipole moment was high compared to that of the preceding  40  kyr, and that  4 · 10²²  Am² appears to represent a critical threshold below which geomagnetic excursions and reversals occur.