Sorption and anaerobic biodegradation of soluble aromatic compounds during groundwater transport. 2. Computer modeling

. The natural attenuation of a binary mixture of toluene and 1,2,4-trimethylbenzene, which was previously experimentally demonstrated in anaerobic column experiments, was simulated with the newly-developed PHREEQC model to reveal the biogeochemical processes involved. The processes considered in this model include advection, diffusion, sorption, redox reactions (e.g., oxidation of toluene and 1,2,4-trimethylbenzene coupled to the reduction of microbial ferric iron), precipitation of secondary minerals such as siderite and magnetite, and dissolution of hydrous ferric oxides, as well as other thermodynamic equilibrium reactions. The functions of advection and diffusion built into the PHREEQC were conventionally simulated. The sorption was kinetically simulated based on a bicontinuum model, whereas biodegradation was described using a multiple-term Monod model. The processes mentioned above were coupled with a geochemical equilibrium model. The consistency between the experimental and modeling results indicates that the processes defined and the controlling parameters chosen could describe the coupled interactions between transport and biogeochemical reactions for the studied system. The discrepancy between modeling and experimental observations, however, also revealed the limitation of the modeling approach. In general, the model approach, which incorporates simplified mathematical representations of the true physico-chemical dynamics of the sorption and biodegradation processes of toluene and 1,2,4-trimethylbenzene under anaerobic conditions is a very efficient and good predictive tool in management and remediation of contaminant groundwater aquifers.     

Holocene glacial history and sea-level changes on James Ross Island,Antarctic Peninsula

A reconstruction of deglaciation and associated sea-level changes on northern James Ross Island, Antarctic Peninsula, based on lithostratigraphical and geomorphological studies, shows that the initial deglaciation of presently ice-free areas occurred slightly before 7400 ¹⁴C yr BP. Sea-level in connection with the deglaciation was around 30 m a.s.l. A glacier readvance in Brandy Bay, of at least 7 km, with the initial 3 km over land, reached a position off the present coast at ca. 4600 yr BP. The culmination of the advance was of short duration, and by 4300 yr BP the coastal lowlands again were ice-free. A distinct marine level at 16–18 m a.s.l. was contemporaneous with or slightly post-dates the Brandy Bay advance, thus indicating the relative sea-level around 4600–4500 yr BP. Our results from James Ross Island confirm that over large areas in this part of Antarctica the last deglaciation occurred late. © 1997 John Wiley & Sons, Ltd.     

Run-up of tsunamis and long waves in terms of surf-similarity

In this paper we review and re-examine the classical analytical solutions for run-up of periodic long waves on an infinitely long slope as well as on a finite slope attached to a flat bottom. Both cases provide simple expressions for the maximum run-up and the associated flow velocity in terms of the surf-similarity parameter and the amplitude to depth ratio determined at some offshore location. We use the analytical expressions to analyze the impact of tsunamis on beaches and relate the discussion to the recent Indian Ocean tsunami from December 26, 2004. An important conclusion is that extreme run-up combined with extreme flow velocities occurs for surf-similarity parameters of the order 3–6, and for typical tsunami wave periods this requires relatively mild beach slopes. Next, we compare the theoretical solutions to measured run-up of breaking and non-breaking irregular waves on steep impermeable slopes. For the non-breaking waves, the theoretical curves turn out to be superior to state-of-the-art empirical estimates. Finally, we compare the theoretical solutions with numerical results obtained with a high-order Boussinesq-type method, and generally obtain an excellent agreement.     

Rating curve uncertainty and change detection in discharge time series: case study with 44‐year historic data from the Nyangores River,Kenya

The intersection of the developing topic of rating curve and discharge series uncertainty with the topic of hydrological change detection (e.g., in response to land cover or climatic change) has not yet been well studied. The work herein explores this intersection, with consideration of a long‐term discharge response (1964–2007) for a ~650‐km² headwater basin of the Mara River in west Kenya, starting with stream rating and daily gauge height data. A rating model was calibrated using Bayesian methods to quantify uncertainty intervals in model parameters and predictions. There was an unknown balance of random and systemic error in rating data scatter (a scenario not likely unique to this basin), which led to an unknown balance of noise and information in the calibrated statistical error model. This had implications on testing for hydrological change. Overall, indications were that shifts in basin's discharge response were rather subtle over the 44‐year period. A null hypothesis for change using flow duration curves (FDCs) from four different 8‐year data intervals could be either accepted or rejected over much of the net flow domain depending on different applications of the statistical error model (each with precedence in the literature). The only unambiguous indication of change in FDC comparisons appeared to be a reduction in lowest baseflow in recent years (flows with >98% exceedance probability). We defined a subjective uncertainty interval based on an intermediate balance of random and systematic error in the rating model that suggested a possibility of more prevalent impacts. These results have relevance to management in the Mara basin and to future studies that might establish linkages to historic land use and climatic factors. The concern about uncertain uncertainty intervals (uncertainty²) extends beyond the Mara and is relevant to testing change where non‐random rating errors may be important and subtle responses are investigated. Copyright © 2013 John Wiley & Sons, Ltd.     

Reindeer management during the colonization of Sami lands: A long-term perspective of vulnerability and adaptation strategies

Reindeer husbandry's strong connection to the land, together with the ongoing climate-change debate, has generated growing interest in its socio-ecological resilience and vulnerability. The ability of indigenous societies and their activities to respond to change is widely recognized to be dependent on several factors, such as socioeconomic forces and aspects of governance, all of which have long historical backgrounds. However, although historians constantly address questions about human societies, there have been very few historical studies on their resilience, vulnerability and adaptation strategies. Here, using historical sources, we analyze the vulnerability of reindeer husbandry (and the Sami societies that depended on it) in Sweden during the 19th century. We demonstrate that although reindeer management was a much more diverse enterprise at that time than it is now, the major adaptation strategy and constraining forces were similar to those of today. The foremost adaptation strategy was, and still is, the flexible use of pasture area, and the clearest constraints during the 19th century were the loss of authority over the land and the imposed regulation of reindeer management-both of which were strongly connected to the process of colonization.

Terminology

Throughout this paper we use the terms reindeer management and reindeer pastoralism interchangeably. Sami reindeer pastoralism has been described as a complex system with two different aspects of management: herding and husbandry. Husbandry has been defined as the accumulations of profit whereas herding has been defined as the control of the animals in the terrain (Paine, 1970, p. 53). In a Swedish context husbandry questions concerning slaughter and castration of reindeer were discussed within the household and herding matters were resolved jointly within the traditional working community Siida. The Siida consisted of households working together on traditional pasturelands and these constellations were grouped together into administrative reindeer pasture districts (Sami villages) ( [Ingold, 1978], [Fellman, 1910] and [Beach, 1981]).     

Large-scale oil-in-ice experiment in the Barents Sea: monitoring of oil in water and MetOcean interactions

A large-scale field experiment took place in the marginal ice zone in the Barents Sea in May 2009. Fresh oil (7000 L) was released uncontained between the ice floes to study oil weathering and spreading in ice and surface water. A detailed monitoring of oil-in-water and ice interactions was performed throughout the six-day experiment. In addition, meteorological and oceanographic data were recorded for monitoring of the wind speed and direction, air temperature, currents and ice floe movements. The monitoring showed low concentrations of dissolved hydrocarbons and the predicted acute toxicity indicated that the acute toxicity was low. The ice field drifted nearly 80 km during the experimental period, and although the oil drifted with the ice, it remained contained between the ice floes.     

Societal need for improved understanding of climate change, anthropogenic impacts, and geo-hazard warning drive development of ocean observatories in European Seas

Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate.Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related?The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.