Influence of sedimentary environments on mechanical properties of clastic rocks

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.     

某些磷灰石矿物的红外吸收光谱

本文讨论了各种磷灰石矿物的光谱特征,氟磷灰石和羟磷灰石的光谱-结构关系及磷灰石中CO_3~(2-)和OH~(-1)离子的存在形式。在结构资料基础上,对氟磷灰石和羟磷灰石中的PO_4~(3-)离子进行了相关分析,给出了内模式的分配数目。碳氟磷灰石中的CO_3~(2-)离子的光谱与简单无水碳酸盐和氟磷灰石混合物光谱之间的差异表明,C0_3~(2-)离子以类质同象形式进入磷灰石结构中。磷灰石中的P_2O_5含量随CO_2含量的增加而降低,PO_4~(3-)离子的v_4带随CO_2的增加或减少而变化,这表明PO_4~(3-)与CO_3~(2-)离子之间存在密切的相关关系,CO_3~(2-)-PO_4~(3-)取代是类质同象置换的一种形式。羟磷灰石OH-OPO_3中的O-O距离和它的高温光谱证明,OH~(-1)离子以氢键形式存在。     

瞬变电磁法在煤矿水害防治中的应用

煤层附近的富水区(带)严重威胁着煤矿的生产安全，探明地下煤层附近富水区的赋存和断层、裂隙的发育情况，可以有效地指导煤矿水害的防治工作。对于含水地层及富水区，瞬变电磁法在多测道剖面上具有典型响应特征，据此可以查明地下水分布情况。在山东某煤田和河南某矿，应用瞬变电磁勘探，准确地查明了煤层顶底板富水区。．     

南秦岭西乡群锆石SHRIMP U—Pb年龄及其构造地质意义

2009年陕西省地质志修编项目组,重点对出露于西乡县城东孙家河附近,南秦岭西乡群孙家河组英安质火山熔岩进行了锆石SHRIMP U-Pb同位素年代学和岩石化学、稀土元素、微量元素等方面的研究,获得了新的同位素年龄为814.8±5.2 Ma。认为该岛弧火山系的形成时代为青白口纪晚期,属晋宁期古扬子板块西缘与青康滇古板块汇聚的产物,为研究南秦岭扬子陆块过渡基底的形成时代,提供了有力的佐证。对进一步详细研究扬子陆块Rodinia超大陆汇聚时限及秦岭造山带的构造演化提供了新的时代证据,具有重要的地质构造意义。     

甘肃北山红柳园地区泥盆系三个井组和墩墩山群LA-ICP-MS锆石U-Pb测年及其意义

对甘肃北山红柳园地区三个井组下部玄武岩和墩墩山群安山质火山岩进行了LA-ICP-MS锆石U-Pb年龄测定,三个井组火山岩形成于420Ma±15Ma,相当于晚志留世;墩墩山群火山岩形成于367Ma±10Ma,相当于晚泥盆世。测年结果表明,晚志留世北山古生代洋盆已经俯冲消亡,并开始碰撞造山,而晚泥盆世墩墩山群火山岩则是北山早古生代洋盆碰撞造山后裂谷拉伸作用的产物,标志北山及相邻地区晚泥盆世进入到新的构造演化阶段——晚古生代板内伸展阶段。     

Lead isotope geochemical characteristics of Pb-Zn-Cu deposits on the southwestern margin of Tarim, and their significance

The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt.     

成矿带1∶20万水系沉积物地球化学分区的方法及地质意义:以西藏冈底斯铜多金属成矿带为例

以冈底斯铜多金属成矿带为例,阐述了利用1∶20万和1∶50万水系沉积物地球化学测量开展成矿区带地球化学分区的方法和思路,进一步对其地质意义进行了探讨。结果表明:小比例尺的水系沉积物地球化学数据具有地球化学分区示踪意义。总结出一套操作性强的地球化学分区方法,其方法具有指示找矿方向的实际意义,对区域构造单元划分具参考价值。地球化学分区为该区的找矿方向、成矿远景评价及基础地质调查奠定了基础。     

石灰岩含水介质中苯系物（BTEX） 生物可降解性判识

    岩溶含水系统遭受石油烃污染的环境问题十分普遍。相对于多孔含水介质,石油烃BTEX在石灰岩含水介质中的生 物可降解性还不确定。为此,本研究开展了BTEX在石灰石和岩溶地下水介质中的静态微元体实验。经过77天的实验检测 分析,结果表明：（1） BTEX化合物在可利用电子受体溶解氧或硝酸盐存在条件下具有生物可降解性;（2） 向系统中补充 电子受体硝酸盐,具有促进生物降解的作用,其对BTEX的去除率可高达94%;（3） 未发现补充硫酸盐能够促进BTEX生物 可降解性;（4） 甲苯和二甲苯容易被生物降解,但苯的去除具有一定的难度。     

湘黔地区震旦纪菌藻硅质岩特征及形成机理探讨

湘黔地区震旦纪菌藻硅质岩化学成分纯净,硅质矿物含量95%以上,几乎都为泥晶—微晶石英,石英结晶度平均为6.35。岩石具菌藻生物结构,以纹层状构造为主。其中丰富的菌藻生物化石,按形态可划分为三种类型。岩石属原生沉积成因,二氧化硅的聚沉一方面通过菌藻有机体的硅化作用,另一方面是菌藻生物化学作用引起微环境变化而导致二氧化硅的聚沉。     

西南山区某铁路隧道口高位落石三维运动特征分析

西南山区某铁路隧道口上部广泛分布着高位危岩体,对下部隧道建(构)造物具有严重的威胁.采用Rockfall Analyst软件对该隧道上部五类不同尺寸的高位危岩体进行三维运动轨迹数值模拟,研究表明:研究区的高位危岩落石具有弹跳高度大、速度快、冲击能量高的特点;弹跳高度、运动速度与危岩落石的质量无关,冲击能量大小与落石质量...