多层天然气藏叠加的地表化探异常特征及实例

通过大量实践,总结了单层气气藏、含双层气气藏和含多层气气藏在理想条件下的异常形态特征,实例为解释油气化探异常提供了一定的地球化学依据。     

铁硫化物球粒

铁硫化物的合成,通常是通过固－气反应来实现,本文利用电弧放电的方法,使黄铁矿（ＦｅＳ２）还原成磁黄铁矿（Ｆｅ１－ｘＳ）、陨硫铁（ＦｅＳ）和金属铁（Ｆｅ）,利用反光显微镜（ＲＬＭ）,Ｘ射线衍射（ＸＲＤ）,扫描电镜（ＳＥＭ）,透射电镜（ＴＥＭ）和能谱（ＥＤＳ）综合研究合成物的特征及各物相的相互关系。初步研究了合成物的电学和磁学性能。讨论在电弧作用的还原环境里,ＦｅＳ２向ＦｅＳ、Ｆｅ１－ｘ和Ｆｅ转变的特     

Characteristics and uranium mineralization of ore-bearing rock series in Qianjiadian sandstone-type uranium deposits,Songliao Basin

The Qianjiadian sandstone-type uranium deposit in Songliao Basin has become an ultra-large uranium deposit since its exploration and continuous development. The geological and metallogenic characteristics of this area have been studied widely since its discovery,but the detailed petrological features of its ore-bearing construction and favorable metallogenic conditions still require much detailed research. The mineralization of urnium deposit includes various geological processes resulting in the accumulation of uranium element. The source rock with high uranium concentration and much easier for the leaching of uranium is the basis of uranium mineralization. The later oxidation-reduction,mineral alteration are the key for the uranium deposits. In this paper,the petrological characteristic of lithology sandstone-type uranium deposit is studied by using the micro experimental analysis. It is found that the host rocks are primarily composed of medium-fine grained feldspar lithic sandstone,fine grained feldspar lithic sandstone,boulder-clay-bearing sandstone and glutenin. The amount of quartz and feldspar are close to the rock debris. The debris are mainly composed of rhyolite,rhyolitic tuff,and some trochyte,ayenite-aplite,granite,granite porphyry,andesite,silicalite and mudstone etc. the epigenetic alteration includes the carbonatization and kaolinization is general and intense at the local region,followed by the secondary epigenetic alteration includes pyritization,ferrugination and little baratization. Deep oil and gas infiltrate into the oil-bearing strata causing the oil stains,spots and spillage. The symbiosis of pyrite berry globule and micritic pyrite are common. The uranium element exists in the uranium-bearing minerals(e.g.,asphalt and coffinite)as well as the adsorbed state. The multi-genesis and multi-stages of the metallogenic model is established,i.e.,sedimentary preconcentration stage-interlayer infiltration stage-the oil and gas transformation stage-the oil and gas reduction stage.     

兰州第四纪黄土/古土壤序列物源演变: 来自于碳酸盐矿物的证据*

黄土/古土壤的物源研究对于揭示第四纪气候变化和青藏高原隆升历史具有重要意义。本研究以位于黄土高原西部1.4 Ma以来的兰州黄土/古土壤沉积序列为研究对象,基于X射线衍射技术分析了黄土/古土壤中的主要矿物组成,侧重于碳酸盐矿物含量,追溯了兰州黄土/古土壤的直接物源。结果显示: (1)1.4 Ma以来兰州地区黄土/古土壤沉积物的主要直接源区为柴达木盆地沙漠区和阿拉善干旱区。(2)基于二元混合模型计算的潜在原始源区对兰州黄土白云石和总碳酸盐矿物的相对贡献率以及长石与石英比值结果一致支持1.4 Ma以来兰州黄土原始物源发生了多次变化。1.4~1.1 Ma和0.9~0.3 Ma青藏高原东北缘造山带(昆仑山、祁连山)和中亚造山带对兰州黄土的贡献相当,而1.1~0.9 Ma和0.3 Ma以来,中亚造山带对兰州黄土的物源贡献增加,这可能分别是对中更新世气候转型和0.3 Ma以来青藏高原及邻近地区干冷气候增强的响应。1.15 Ma和0.8 Ma兰州黄土/古土壤中高的白云石含量、碳酸盐矿物总含量以及0.8 Ma长石与石英比值的快速升高可能是对“昆黄运动”的响应,进而造成了昆仑山、祁连山对黄土高原物源贡献的增加。     

北极涛动对青藏高原冬季变暖的影响

基于青藏高原地区1960-2010年高分辨率(0.5°×0.5°)的逐日地面气温格点资料以及 1960-2010年NCEP/NCAR全球月平均海平面气压场、高度场、风场的再分析格点资料(2.5°×2.5°), 通过计算青藏高原(74.75°~104.25° E, 26.75°~40.25° N)冬季地面温度平均值经标准化处理后得到的区域冬季气温强度指数, 分析了冬季北极涛动(AO)、西伯利亚高压与同期青藏高原地面气温的特征和关系. 结果表明: AO为负(正)相位时, 中高纬西风气流偏弱(强), 有(不)利于极地冷空气向南输送, 西伯利亚地区源地冬季风偏强(弱), 青藏高原冬季气温指数减小(增大), 地面气温偏低(高). 对AO作M-K突变分析, 发现其突变年份为1975年, 通过对突变年份前后高度场和风场作差值场分析, 结果显示: 冬季AO处于高指数时期, 500 hPa上, 欧洲东部槽变浅, 青藏高原北部的高压脊减弱, 环流呈纬向发展, 青藏高原上盛行偏南风, 气温偏高, 青藏高原地区为暖冬期; 200 hPa 上, 青藏高原东部的槽明显加深, 使得青藏高原地区对流层顶至平流层底的环流趋势以经向发展为主, 该区域主要受到偏北的急流控制, 易导致降温.     

Screening of extraction methods for Cd and As bioavailability prediction in rhizospheric soil using multivariate analyses

Heavy metals in tailings and mining wastes from abandoned mines can be released into adjacent agricultural field and bioaccumulated in crops or vegetables. Therefore, prediction of metal bioavailability has become an important issue to prevent adverse effect of bioaccumulated metals on human health. In this study, single and sequential extraction methods were compared using multivariate analysis to predict the bioavailability of Cd and As in contaminated rhizosphere soils. Single extraction using 0.1 M HCl for Cd and 1.0 M HCl for As had an extraction efficiency of 8–12% for soil Cd and 14–17% for soil As compared to total concentration extracted with aqua regia. Using sequential extraction, Fe–Mn-bound Cd (FR3) and residual Cd (FR5) were the dominant fractions representing 43 and 41% of total Cd concentration. For As, the strongly absorbed form (FR2) was the most abundant chemical fraction showing 45–54% of the total As concentration in soil. Multivariate analyses showed that single extraction with HCl and total concentration of Cd and As in soil were significantly correlated to potato and green onion plant tissue metal concentration. Although little information was obtained with multiple regression analysis because of multicollinearity of variables, the result of principle component analysis (PCA) revealed that the highest positive loading was obtained using total concentration of Cd and As in soil in the first principle component (PC1). In addition, total concentration of Cd and As in soil was independently grouped with other chemical fractions by cluster analysis. Therefore, the overall result of this research indicated that total concentrations of Cd and As in rhizosphere soils were the best predictors of bioavailability of heavy metals in these contaminated soils.     

A simulation experimental study on oxidative kinetics of sphalerite under hypergene condition

The sphalerite oxidative kinetics under hypergene condition was simulated and studied by means of a mixed flow reactor over a pH range of 1.0 7.8,and at dissolution temperatures from 20 to 55℃,ferric ion concentrations from 1.0×10-5 to 1.0×10-2 mol/L,O 2 flux of 0.5 L/min,and oxidants of ferric ion and O 2.It is indicated that with ferric ion as oxidant,the oxidation rate of sphalerite increases with increasing ferric ion concentration,temperature and decreasing pH value,and under the studied conditions,the dissolution rates of Zn and Cd are approximately identical,with the values of activation energy being 41.75 and 42.51 kJ·mol-1,respectively,suggesting that the oxidation rate of sphalerite is controlled by chemical reactions on mineral surface.However,with O 2 as oxidant,the oxidation mechanism of sphalerite varies with pH value.Oxidation rate decreases with increasing pH value when pH is lower than 5.95,whereas the increase of pH value results in an increase in oxidation rate when pH value is higher than 7.The oxidation rate of sphalerite can be expressed as:R Zn =10 1.1663 [Fe3+] 0 0.154 ·[H+] 0.2659 ·e-41.75/RT or R Cd =10 1.7292 [Fe3+] 0 0.170 ·[H+] 0.2637 ·e-42.51/RT     

微/纳结构的弗雷德盐对铜的絮凝-吸附研究

以含钙聚合铝(PACCa)作为导向剂与铝源,在常温常压下合成了微/纳结构(微米/纳米尺度)的弗雷德盐。当水溶液中的ρ(Cu2+)为4.406 mg/L时,每升含铜溶液投入0.45 g弗雷德盐对Cu2+的去除率为99.02%。背散射(BEI)与二次电子(SEI)的SEM研究表明:微/纳结构的弗雷德盐在水处理中经历了溶解-结晶过程,XRD鉴定证实弗雷德盐分解后形成方解石晶体与无定形氧化铝。微/纳结构的弗雷德盐去除Cu2+的絮凝沉淀机理与吸附反应模式有所不同,弗雷德盐在絮凝过程中与水中CO2作用转变成方解石与无定形氧化铝,同时Cu2+在碱性环境下生成氢氧化物,新生成的无定型氢氧化铝迅速吸附铜的氢氧化物并裹挟方解石沉淀。     

EASY%R_o法在地温梯度恢复中的局限性——以海拉尔盆地乌尔逊凹陷为例

EASY%Ro法是一种寻找能与现今Ro垂向分布达到最佳匹配的古地温梯度的反演热史分析法,涉及到的一个重要环节是有约束条件的最优化计算。基于4种地温梯度约束方式(逐步升高、逐步降低、先降后升、先升后降)的计算发现,EASY%Ro可以得到有差异的地温梯度史结果,又能达到现今相同的Ro分布,即EASY%Ro得到的地温梯度史有一定的不确定性;这种不确定性发生在反演地质时间段的早期。对乌尔逊凹陷4口井4种约束条件得到的地温梯度史结果分析说明,乌尔逊凹陷在大磨拐河组沉积时期的地温梯度值最高,伊敏组至今处于下降过程,大磨拐河组之前的地温梯度无法确定,但不高于大磨拐河组时期。     

巴姆地震变形场和应力场：Ⅱ．用FEPG有限元方法求解

本文利用FEPG有限元程序对2003年12月的巴姆地震变形场和应力场进行了模拟计算.2003年12月26日,巴姆地区发生6.6级地震.Nakamura、Suzuki等人利用余震资料和地震破坏程度的分布图分析了余震震中的统计分布形式,得到了此次地震的发震断层是巴姆断层以西大约5km的Arg-e-Bam隐伏断层的结论.凌勇等人从差分干涉雷达(D-InSAR)出发,得到了此次地震的同震干涉条纹和雷达视线方向的位移场,并从雷达干涉的相干图上确定了发震断层的痕迹.他们还利用Okada程序模拟计算了此次地震的位移场,模拟计算的结果与D-InSAR测量的位移场比较符合.Okada程序从断层的位错为出发点进行计算,从运动学角度对此次地震变形场和应力场进行研究;本文从动力学的角度出发,研究远场区域边界的应力状态以及断层的物性参数的变化对巴姆地震形变场的影响,将各种计算结果进行对比的同时也和前人的结果相比较.本文计算中采用了凌勇等人的断层参数,即Arg-e-Bam隐伏断层为近南北走向,向东倾斜,近直立的倾角,右旋走滑,其(Strike,dip,slip)为(175°,80°,173°).断层未延伸到地表,自地面以下1km处往下延伸16km的宽度,断层长度为20km.对断层的杨氏模量、泊松比、断层附近区域的边界受力大小、两个主应力的比例以及主应力的方向的改变对计算结果的影响做了讨论.最后通过上述几组计算结果建立了一个与前人结果较为符合的巴姆地震参数模型.通过计算,一方面揭示了应力状态和物性参数的影响,另一方面也说明Arg-e-Bam隐伏断层是此次地震的发震断层这一结论是可信的.