Supergene geochemistry and crystal morphology of gold in a semiarid weathering environment: application to gold exploration

Oxidation of sulfide- and carbonate-rich vein gold deposits under semiarid conditions can be represented as a three-stage process, each creating supergene environments conducive to dissolution and reprecipitation of gold-silver alloys. The three-stage weathering process of sulfide-carbonate gold veins is depth-dependent, and develops from the relatively young, lowermost weathering horizon just below the water table, through an intermediate weathering horizon in the oxidation zone above the water table, and culminating in the oxide-rich upper saprolite and oxisol.Neoformed gold crystals in the weathering profile have distinct composition and morphologic characteristics from the hypogene gold crystals associated with the sulfide- and carbonate-rich ores. Two distinct types of secondary gold are present in the weathering profile: (1) gold crystals associated with sulfates and arsenates; and (2) gold crystals associated with iron and aluminum oxides/hydroxides, or with kaolinite. The distinct crystal morphologies and mineralogical associations of primary and secondary gold are useful in prospecting for gold deposits in weathered terrains.     

Tunneling of seismic body waves through thin high-velocity layers in complex structures

Summary The hybrid ray-reflectivity method is applied to the problem of the transmission of the reflected wave field through a thin high-velocity layer (or through a thin stack of high velocity layers), situated in the overburden of the reflector. In the hybrid ray-reflectivity method, the standard ray method is applied in the smooth parts of the model, and the reflectivity method is used locally at the thin high-velocity layer. With the exception of small epicentral distances, the standard ray method itself fails in such computations. The reason is that a considerable part of the energy for overcritical angles of incidence may be tunneled through the thin high-velocity layer along complex ray-paths, corresponding to inhomogeneous waves. The reflectivity method, applied locally at the thin high-velocity layer, automatically includes all inhomogeneous wave contributions. Thus, the hybrid ray-reflectivity method removes fully the limitations of the standard ray method, but still retains its main advantages, such as its applicability to 2-D and 3-D complex layered structures, flexibility, and low-cost computations. In the numerical examples, the hybrid ray-reflectivity synthetic seismograms are compared with standard ray synthetic seismograms and with full reflectivity computations. The numerical examples show that the hybrid ray-reflectivity method describes the tunneling of seismic energy through a thin high-velocity layer with sufficient accuracy.     

UV observations of the symbiotic star EG And

EG And is a S-type symbiotic star. Presented are UV observations made by IUE from 1978 to 1991. From these observations the electron density and the electron temperature were obtained. The size of the Heii emitting region was estimated as 7.3R. Line and continuum variations confirm the binary nature of EG And.     

Ionospheric tomography using GNSS: multiplicative algebraic reconstruction technique applied to the area of Brazil

Experimental analysis was performed using multiplicative algebraic reconstruction technique (MART) to map the ionosphere over Brazil. Code and phase observations from the global navigation satellite system (GNSS) together with the international reference ionosphere (IRI) enabled the estimation of ionospheric profiles and total electron content (TEC) over the entire region. Twenty-four days of data collected from existing ground-based GNSS receivers during the recent solar maximum period were used to analyze the performance of the MART algorithm. The results were compared with four ionosondes. It was demonstrated that MART estimated the electron density peak with the same degree of accuracy as the IRI model in regions with appropriate geometrical coverage by GNSS receivers for tomographic reconstruction. In addition, the slant TEC, as estimated with MART, presented lower root-mean-square error than the TEC calculated by ionospheric maps available from the International GNSS Service (IGS). Furthermore, the daily variations of the ionosphere were better represented with the algebraic techniques, compared to the IRI model and IGS maps, enabling a correlation of the elevation of the ionosphere at higher altitudes with the equatorial ionization anomaly intensification. The tomographic representations also enabled the detection of high vertical gradients at the same instants in which ionospheric irregularities were evident.     

Bioaccumulation and depuration of Zn and Cd in mangrove oysters (Crassostrea rhizophorae, Guilding, 1828) transplanted to and from a contaminated tropical coastal lagoon

In order to study Zn and Cd accumulation and depuration, a set of oysters, Crassostrea rhizophorae, were transplanted to a metal contaminated coastal lagoon and another one was harvested there and transplanted to a non-polluted site. C. rhizophorae oysters and Perna perna mussels native from both sites were collected in order to monitor variability of metal concentration in resident populations. After three months exposure, oysters transplanted to the polluted site accumulated fourfold Zn (307-1319 microgg(-1)) without reaching the concentration level of resident oysters (9770 microgg(-1)). Cadmium concentrations had a slight but significant decrease during the same period (1.25-0.54 microgg(-1)). Oysters transplanted to the non-polluted site, showed threefold Zn depuration (6727-2404 microgg(-1)), while Cd had no significant variation (0.90-1.45 microgg(-1)). Results showed that transplanted oysters do not reach heavy metal concentrations in indigenous populations suggesting transplanted organisms would be better used to evaluate bioavailability instead of environmental concentrations.     

Conceptual fuzzy neural network model for water quality simulation

Artificial neural networks (ANNs) have been applied successfully in various fields. However, ANN models depend on large sets of historical data, and are of limited use when only vague and uncertain information is available, which leads to difficulties in defining the model architecture and a low reliability of results. A conceptual fuzzy neural network (CFNN) is proposed and applied in a water quality model to simulate the Barra Bonita reservoir system, located in the southeast region of Brazil. The CFNN model consists of a rationally‐defined architecture based on accumulated expert knowledge about variables and processes included in the model. A genetic algorithm is used as the training method for finding the parameters of fuzzy inference and the connection weights. The proposed model may handle the uncertainties related to the system itself, model parameterization, complexity of concepts involved and scarcity and inaccuracy of data. The CFNN showed greater robustness and reliability when dealing with systems for which data are considered to be vague, uncertain or incomplete. The CFNN model structure is easier to understand and to define than other ANN‐based models. Moreover, it can help to understand the basic behaviour of the system as a whole, being a successful example of cooperation between human and machine. Copyright © 2006 John Wiley & Sons, Ltd.     

Science-based and stakeholder-driven marine protected area network planning: A successful case study from north central California

The planning process for California's Marine Life Protection Act in north central California represents a case study in the design of a regional component of a statewide network of marine protected areas (MPAs) for improved ecosystem protection. We describe enabling factors, such as a legislative mandate, political will, and adequate capacity and funding that fostered a successful planning process. We identify strategic principles that guided the design of a transparent public planning process that delivered regional MPA network proposals, which both met science guidelines and achieved a high level of support among stakeholders. We also describe key decision support elements (spatial data, planning tools, and scientific evaluation) that were essential for designing, evaluating, and refining alternative MPA network proposals and for informing decision-makers.     

Influence of aquifer properties and the spatial and temporal distribution of recharge and abstraction on sustainable yields in semi‐arid regions

This paper aims to contribute to understanding the importance of four factors on the determination of sustainable yields: (i) aquifer properties; (ii) temporal distribution of recharge; (iii) temporal distribution of groundwater pumping; and (iv) spatial distribution of pumping wells. It is important to comprehend how the present‐day and future vulnerability of groundwater systems to pumping activities depend on these critical factors and what the risks are of considering sustainable yield as a fixed percentage of mean annual recharge (MAR). A numerical model of the Querença–Silves aquifer in Portugal is used to develop hypothetical scenarios with which these factors are studied. Results demonstrate the aquifer properties, particularly the storage coefficient, have an important role in determining the resilience of an aquifer and therefore to which degree it is dependent on the spatial and temporal distribution of abstraction and recharge, as well as the occurrence of extreme events. Sustainable yields are determined for the developed scenarios based on specific criteria rather than a fraction of MAR. Under simplified current recharge and abstraction conditions, the sustainable yield was determined at approximately 73% of MAR or 76 million m³. When considering a concentration of rainfall in time, as predicted by climate scenarios for the region, sustainable yield could drop to ca 70% of MAR. However, a more even distribution of pumping volumes throughout the year could increase this value. The location of the pumping wells is seen to affect the distribution of hydraulic heads in the aquifer, albeit without significant changes in sustainable yield. Copyright © 2011 John Wiley & Sons, Ltd.