Changes of oceanographic characteristics and the state of pollution in the Izmit bay following the earthquake of 1999

The Izmit Bay is an elongated semi-enclosed bay in the Marmara Sea. It is being increasingly polluted by both domestic and industrial waste discharge since 1970’s. A monitoring program was conducted between 1999-2000 to document the state of pollution in the bay. This includes the effect of Marmara (Izmit) earthquake (magnitude 7.4) that occurred in August 1999. A stable two-layer ecosystem exists in the bay throughout the year due to continuous inflows of the saltier Mediterranean and brackish Black Sea waters to the Marmara basin. Therefore, the principal biochemical characteristics of the bay are governed by the two-layer flow system over the basin. Dissolved oxygen (DO) is generally at a saturated levels in the surface layer which is 10 to 15 m thick, but it is depleted to 60–70 μM in the lower layer, exhibiting a steep gradient in the sharp halocline. When the earthquake occurred, great loads of industrial wastes were released into the bay surface waters, which enhanced primary production in the upper layer and thus large export of particulate organic matter to lower layer and eventually to the bottom. Accordingly, DO was consumed and anoxic condition was established even in the upper layer/halocline interface, the halocline and bottom waters of the eastern and central bay. In this period, concurrent increases were observed in phosphate and ammonia contents at the halocline and in deep waters whilst the nitrate was almost consumed via denitrification processes in the anoxic water. Recently, the industrial C, N and P loads increased by as much as 8 fold within five years (1995–2000) whilst domestic inputs increased by 50%. Total organic matter discharged to the bay increased more than double within the last 15 years. Besides, most factories in the region release toxic wastes into the bay after only partial treatment.     

Reliability analysis of drilled shaft behavior using finite difference method and <Emphasis Type="Italic">Monte Carlo</Emphasis> simulation

Load displacement analysis of drilled shafts can be accomplished by utilizing the “t-z” method, which models soil resistance along the length and tip of the drilled shaft as a series of springs. For non-linear soil springs, the governing differential equation that describes the soil-structure interaction may be discretized into a set of algebraic equations based upon finite difference methods. This system of algebraic equations may be solved to determine the load–displacement behavior of the drilled shaft when subjected to compression or pullout. By combining the finite difference method with Monte Carlo simulation techniques, a probabilistic load–displacement analysis can be conducted. The probabilistic analysis is advantageous compared to standard factor of safety design because uncertainties with the shaft–soil interface and tip properties can be independently quantified. This paper presents a reliability analysis of drilled shaft behavior by combining the finite difference technique for analyzing non-linear load–displacement behavior with Monte Carlo simulation method. As a result we develop probabilistic relationships for drilled shaft design for both total stress (undrained) and effective stress (drained) parameters. The results are presented in the form of factor of safety or resistance factors suitable for serviceability design of drilled shafts.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

A method for generating uniform size-segregated pyrite particle fractions

Background  

Standardized sample preparation techniques allow comparison of pyrite dissolution experiments under diverse conditions. Our objective was to assess dry and wet sieving preparation methodologies, and to develop a reproducible technique that yields uniformly size-distributed material within a limited size range of interest.     

Composition of Kerogen in Kupferschiefer from Southwest Poland

Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR).     

<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.     

Field investigation of deformation characteristics and stress mobilisation of a soil slope

Stress mobilisation and deformation of a slope are important for engineers to carry out reliable design of retaining systems. However, most case histories reported mainly on the response of pore water pressure (PWP), whereas knowledge about the stress deformation characteristics of slope is limited. In this study, a saprolitic soil slope was instrumented to monitor not only the responses of PWP but also horizontal stress and horizontal displacement. To assist in the interpretation of field data, a series of laboratory tests was conducted to characterise volume change behaviour of the soil taken from the site, under the effects of both net stress and suction. During a rainstorm event when positive PWP built up, a remarkably large displacement of 20 mm was recorded between 5.5- and 6-m depths, and the top 5 m of the slope exhibited translational downslope movement. This caused an increase in Bishop’s effective horizontal stress by 350 %, which reached a peak value close to 40 % of a Bishop’s effective passive stress. During the subsequent dry season when suction was recovered, an upslope rebound of 10 mm was recorded. Comparison of field and laboratory data reveals that the rebound was attributed to suction-induced soil shrinkage. This rebound led to a decrease in the Bishop’s effective horizontal stress previously built up during the storm event.     

Behavior of Shallow Strip Footing on Twin Voids

This paper numerically examines the bearing capacity and failure mechanism of a shallow strip foundation constructed above twin voids. The voids may refer to caves, caverns, underground aqueduct or tunnels due to water seepage, chemical reaction or deliberately excavated in soil deposit. The ability of numerical model to accurately predict the system behavior is evaluated by performing verification analyses on existing researches. Subsequently, a parametric study carried out to reveal the influence of size of footing/voids and their location (i.e. depth, spacing, eccentricity) on the bearing capacity of footing. To clarify the failure mechanism, the distribution of shear strain in the soil for different scenarios is assessed. The parametric study provided a new framework to determine the bearing capacity and the mode of failure for footings on voids. Based on the results, a criterion can be issued to avoid collapse of footing/voids regarding the shape, location and size of voids. The results can also be used to design construction of a footing on existing voids while the acquired failure mechanisms can be appointed to develop analytical solutions for this problem. Results demonstrated that a critical depth for voids and a critical distance between them exist where the influence on the ultimate bearing capacity of footing disappears.     

Seasonal Fisheries Changes in Low-Rainfall Mangrove Ecosystems of Iran

To determine the role of mangroves for fisheries in the arid region of the Persian Gulf, we investigated fish community structure and trophic diversity in intertidal creeks with and without mangroves. Fish community abundances and biomass were compared across habitats and seasons. To identify variations in overall community trophic niches among habitats and seasons, we measured niches with size-corrected standard ellipse areas (SEA_c) calculated from C and N stable isotope values. Although there was a slightly greater species richness occurred in mangrove creeks, we found a general similarity in the diversity patterns in creeks with and without mangroves. Also, there were no consistent differences in fish abundance or biomass for mangrove vs. non-mangrove fish collections. Community trophic diversity measured as SEA_c also showed no significant difference between mangrove and non-mangrove sites. Instead, strong seasonal patterns were observed in the fish assemblages. Winter samples had consistently higher fish abundance and biomass than summer samples. Winter SEA_c values were significantly higher, indicating that the fish community had a larger isotopic niche in winter than summer. Overall, we found that seasonality was much stronger than habitat in determining fish community structure and trophic diversity in the mangrove and non-mangrove ecosystems of Qeshm Island, Iran.