利用接收函数方法研究青藏高原东南部地壳结构

青藏高原东南部作为板块碰撞的前缘地带一直是地球科学研究的热点,为了揭示碰撞前缘地带地壳结构特征,作者 利用布设在中国青藏高原东南部的38个宽频带流动台站记录的2487条远震P波接收函数,采用接收函数CCP叠加（共转换点 叠加）和H-κ叠加两种方法获得了研究区域详细的地壳厚度图像和泊松比值。研究结果显示：两种方法获得的地壳厚度特征 具有较好的一致性;青藏高原东南部地壳厚度存在明显的东西差异和南北差异;喜马拉雅构造区内莫霍面深度变化较大, 介于65~80 km之间;拉萨地体内莫霍面深度介于72~80 km之间;雅鲁藏布缝合带两侧地壳厚度突变,缝合带北侧和南侧地 壳厚度相差约8 km。研究区域平均泊松比值较小,为0.24,和大多数造山带泊松比偏低的特征类似。研究区域中下地壳广 泛存在强转换界面,该界面可能对应中下地壳高速层的上界面,埋深40~70 km,表明壳内发生深熔或部分熔融作用,导致 壳内发生重力分异,在中下地壳形成了高速薄层。     

利用P波S波相结合的逆时偏移方法监测微地震群

微地震定位是油气资源开采中评估水力压裂质量和评估矿山地震和水库地震安全的重要手段。但是,采用地震震相 到时定位的方法很难对具有相近到时的微地震事件群精确定位地震。本文尝试用P波和S波结合的逆时偏移方法对具有相 近到时的微地震定位。先用绝对振幅记录做逆时偏移,获得P波和S波以及P波与S波结合的综合波场,再采用波前在震源 位置成像前后的汇聚到散射的转换过程作为成像条件,提取震源位置和发震时刻。用数值模拟生成具有相近到时的微地震 群,然后用该方法定位微地震。结果表明该方法可以有效提取各个震源位置和发震时刻。     

南海北部表层颗粒有机碳的季节和年际变化遥感分析

海洋颗粒有机碳（POC）是海洋固碳的一个关键参数。为了研究南海北部陆架及海盆表层POC浓度的时空分布特征以及变化趋势,本文利用2009-2011年4个季节的实测数据,对NASA发布的MODIS/AQUA卫星月平均POC遥感产品,进行了验证和校正;并利用校正后的遥感数据分析了2003-2014年POC的时空分布特征和变化趋势。发现POC遥感产品与南海北部实测数据具有较好的线性关系（R2=0.72）,但存在系统性偏高,需利用实测数据对遥感数据进行区域性校正。分析校正后的遥感数据发现,南海北部陆架POC浓度较高,平均为（33.34±8.02）mg/m3;吕宋海峡西南海域浓度较低,平均为（29.25±6.20）mg/m3;中央海盆区浓度最低,平均为（27.02±4.84）mg/m3。春夏季POC浓度较低,最低值一般出现在5月,冬季（12月至翌年1月）POC浓度达到最高。利用2003-2014年的长时间序列遥感叶绿素（Chl a）和海表温度（SST）、混合层深度（MLD）模式数据,以及实测数据对南海北部POC浓度的影响机制进行了分析。发现POC与Chl a在秋冬呈现较好的相关关系（R2=0.51）,但在春夏季较离散,表明秋冬季生物作用对POC影响较大。2003-2014年期间,POC与Chl a、MLD及SST存在明显的年际变化,但并没有显著的上升或下降趋势。     

Succession and seasonal variation in epilithic biofilms on artificial reefs in culture waters of the sea cucumber <Emphasis Type="Italic">Apostichopus japonicus</Emphasis>

Periphytic biofilms in aquaculture waters are thought to improve water quality, provide an additional food source, and improve the survival and growth of some reared animals. In the Asia- Pacific region, particularly in China, artificial reefs are commonly used in the commercial farming of sea cucumbers. However, few studies have examined the epilithic biofilms on the artificial reefs. To gain a better understanding of the succession of epilithic biofilms and their ecological processes in sea cucumber culture waters, two experiments were conducted in culture waters of the sea cucumber Apostichopus japonicus in Rongcheng, China, using artificial test panels. On the test panels of succession experiment, more than 67 species were identified in the biofilms. On the test panels of seasonal variation experiment, more than 46 species were recorded in the biofilms. In both experiments, communities of epilithic biofilms were dominated by diatoms, green algae and the annelid Spirorbis sp. In the initial colonization, the dominant diatoms were Cocconeis sp., Amphora spp. and Nitzschia closterium in June, which were succeeded by species of Navicula, Cocconeis and Nitzschia (July to September), and then by Licmophora abbreviata, Nitzschia closterium and Synedra spp. in the following months. A diatom bloom in the autumn and filamentous green algae burst in the summer were also observed. Ecological indices well annotated the succession and seasonal changes in epilithic communities. Multidimensional scaling (MDS) analysis found significant differences in diatom community composition among months and seasons. Fast growth of biofilms was observed in the summer and autumn, whereas the biomass of summer biofilms was largely made up of filamentous green algae. Present results show that the components of epilithic biofilms are mostly optimal foods of A. japonicus, suggesting that biofilms on artificial reefs may contribute important nutritional sources for sea cucumbers during their growth seasons. Future works should include quantitative determination of the contribution of epilithic biofilms to the diet of A. japonicus, potential roles of epilithic biofilms in regulating the water quality of sea cucumber ponds, and the regulation of epilithic biofilms in sea cucumber culture ponds.     

Distributed estimation and analysis of precipitation recharge coefficient in strongly-exploited Beijing plain area,China

The precipitation recharge coefficient(PRC), representing the amount of groundwater recharge from precipitation, is an important parameter for groundwater resources evaluation and numerical simulation. It was usually obtained from empirical knowledge and site experiments in the 1980 s. However, the environmental settings have been greatly modified from that time due to land use change and groundwater over-pumping, especially in the Beijing plain area(BPA). This paper aims to estimate and analyze PRC of BPA with the distributed hydrological model and GIS for the year 2011 with similar annual precipitation as long-term mean. It is found that the recharge from vertical(precipitation + irrigation) and precipitation is 291.0 mm/yr and 233.7 mm/yr, respectively, which accounts for 38.6% and 36.6% of corresponding input water. The regional mean PRC is 0.366, which is a little different from the traditional map. However, it has a spatial variation ranging from –7.0% to 17.5% for various sub-regions. Since the vadose zone is now much thicker than the evaporation extinction depth, the land cover is regarded as the major dynamic factor that causes the variation of PRC in this area due to the difference of evapotranspiration rates. It is suggested that the negative impact of reforestation on groundwater quantity within BPA should be well investigated, because the PRC beneath forestland is the smallest among all land cover types.     

A low-dimensional subsurface model for saturated and unsaturated flow processes: ability to address heterogeneity

A low-dimensional model that describes both saturated and unsaturated flow processes in a single equation is presented. Subsurface flow processes in the groundwater, the vadose zone, and the capillary fringe are accounted for through the computation of aggregated hydrodynamic parameters that result from the integration of the governing flow equations from the bedrock to the land surface. The three-dimensional subsurface flow dynamics are thus described by a two-dimensional equation, allowing for a drastic reduction of model unknowns and simplification of the model parameterizations. This approach is compared with a full resolution of the Richards equation in different synthetic test cases. Because the model reduction stems from the vertical integration of the flow equations, the test cases all use different configurations of heterogeneity for vertical cross-sections of a soil-aquifer system. The low-dimensional flow model shows strong consistency with results from a complete resolution of the Richards equation for both the water table and fluxes. The proposed approach is therefore well suited to the accurate reproduction of complex subsurface flow processes.     

Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry

The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al₂O₃ content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g^?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g^?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g^?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g^?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.     

Dye adsorption on electrochemical exfoliated graphene oxide nanosheets: pH influence,kinetics and equilibrium in aqueous solution

Graphene oxide nanosheets were synthesized by electrochemical exfoliation. X-ray diffraction, scanning electron microscopy, atomic force microscopy, Raman spectrometry and Fourier transform infrared spectrometry were used to characterize crystal structure, particle size, thickness and function groups of the nanosheets. The nanosheets were examined for adsorption of methyl orange, an anionic dye, in aqueous solution at different pHs and temperatures. The maximum adsorption capacity of methyl orange on graphene oxide nanosheets obtained from the Langmuir isotherm was 138.69 mg/g at pH 2.0, which is larger than that of other carbonaceous adsorbents. The large adsorption affinity of graphene oxide nanosheets to methyl orange might be due to the presence of hydrogen bonding and π–π interaction between methyl orange and graphene oxide nanosheets. Adsorption kinetics followed a pseudo-second-order kinetic model, and the isotherm adsorption results were fitted with Langmuir isotherm model in a monolayer adsorption manner. The thermodynamic studies indicated that the adsorption reaction was a spontaneous physisorption process.     

Probabilistic evaluation of tunnel face stability in spatially random soils using sparse polynomial chaos expansion with global sensitivity analysis

The sparse polynomial chaos expansion is employed to perform a probabilistic analysis of the tunnel face stability in the spatially random soils. A shield tunnel under compressed air is considered which implies that the applied pressure is uniformly distributed on the tunnel face. Two sets of failure mechanisms in the context of the limit analysis theory with respect to the frictional and the purely cohesive soils are used to calculate the required face pressure. In the case of the frictional soils, the cohesion and the friction angle are modeled as two anisotropic cross-correlated lognormal random fields; for the purely cohesive soils, the cohesion and the unit weight are modeled as two anisotropic independent lognormal random fields. The influences of the spatial variability and of the cross-correlation between the cohesion and the friction angle on the probability density function of the required face pressure, on the sensitivity index and on the failure probability are discussed. The obtained results show that the spatial variability has an important influence on the probability density function as well as the failure probability, but it has a negligible impact on the Sobol’s index.     

2℃温升目标下中国排放配额分析

本文以国际社会当前所有主要分配方案为基础,研究了2℃温升目标下中国2011-2050年间排放配额,通过控制变量进一步分析了配额分配对于主要参数设置的敏感性。研究结果表明,在与2℃目标相兼容的RCP2.6路径下,到2050年中国CO₂累计排放配额范围为150～440 Gt CO₂,基于等人均排放的分配方式已经变得最不利于中国。为维护合理的排放权益,在气候谈判中中国必须坚持对历史排放的完整追溯。全球排放路径的设定对中国配额也有着非常显著的影响,当2050年全球配额比2010年排放减少40%～50%时,中国在2℃目标下CO₂累计配额范围为151～474 Gt CO₂,当减少50%～60%时为138～478 Gt CO₂,构成中国配额公平范围下限的方案受排放路径的影响更大。