Supergene geochemistry and crystal morphology of gold in a semiarid weathering environment: application to gold exploration

Oxidation of sulfide- and carbonate-rich vein gold deposits under semiarid conditions can be represented as a three-stage process, each creating supergene environments conducive to dissolution and reprecipitation of gold-silver alloys. The three-stage weathering process of sulfide-carbonate gold veins is depth-dependent, and develops from the relatively young, lowermost weathering horizon just below the water table, through an intermediate weathering horizon in the oxidation zone above the water table, and culminating in the oxide-rich upper saprolite and oxisol.Neoformed gold crystals in the weathering profile have distinct composition and morphologic characteristics from the hypogene gold crystals associated with the sulfide- and carbonate-rich ores. Two distinct types of secondary gold are present in the weathering profile: (1) gold crystals associated with sulfates and arsenates; and (2) gold crystals associated with iron and aluminum oxides/hydroxides, or with kaolinite. The distinct crystal morphologies and mineralogical associations of primary and secondary gold are useful in prospecting for gold deposits in weathered terrains.     

Implications of uncertain future fossil energy resources on bioenergy use and terrestrial carbon emissions

The magnitude and character of the global resource base of fossil fuels is a key determinant of the evolution of the future global energy system and corresponding fossil fuel carbon emissions. What is less well understood is the potential magnitude of impact of the availability of fossil fuels, due to the interaction with biomass energy, on agriculture, land use, ecosystems and therefore carbon emissions from land-use change. This paper explores these links and implications. We show that if oil resources are limited, then the consequently higher price for liquids induces both the use of coal-to-liquids technology deployment, but also enhanced production of bioenergy crops particularly in a business-as-usual scenario. This in turn implies greater pressure to convert unmanaged ecosystems to produce bioenergy, and higher rates of terrestrial carbon emissions from land use.     

Legacies of a Contested Campus: Urban Renewal,Community Resistance,and the Origins of Gentrification in Denver

The postwar urban renewal experience varied among US cities according to the result of local social contests pitting those imposing their power to transform urban space against those resisting it. In this paper, we examine the role of one such contest in shaping urban renewal outcomes in Denver, using the case of the late 1960s Auraria project. The project sought to remove a poor, Hispanic neighborhood in order to build a new downtown college campus, generating community opposition from the inner city neighborhood residents, leaders of the city’s Chicano Movement, and historic preservation activists. We demonstrate how resistance actively shaped the ultimate form and character of the project, and how the legacies of this urban renewal contest extended—in unforeseen ways—beyond the immediate struggles of the time. We argue that these legacies provide the essential context for understanding planning practice, redevelopment strategies, and gentrification dynamics in the city today.     

Seasonal and Interannual Variability in the Distribution of Surface Nutrients and Dissolved Inorganic Carbon in the Northern North Pacific: Influence of El Niño

The seasonal and interannual changes in surface nutrients, dissolved inorganic carbon (DIC) and total alkalinity (TA) were recorded in the North Pacific (30–54°N) from 1995 to 2001. This study focuses on the region north of the subarctic boundary (∼40°N) where there was extensive monthly coverage of surface properties. The nutrient cycles showed large interannual variations in the eastern and western subarctic gyres. In the Alaska Gyre the seasonal depletion of nitrate (ΔNO₃) increased from 8–14 μmol kg⁻¹ in 1995–1999 to 21.5 μmol kg⁻¹ in 2000. In the western subarctic the shifts were similar in amplitude but more frequent. The large ΔNO₃ levels were associated with high silicate depletions, indicating enhanced diatom production. The seasonal DIC:NO₃ drawdown ratios were elevated in the eastern and central subarctic due to calcification. In the western subarctic and the central Bering Sea calcification was significant only during 1997 and/or 1998, two El Ni?o years. Regional C/N stoichiometric molar ratios of 5.7 to 7.0 (>40°N) were determined based on the years with negligible or no calcification. The annual new production (NP_a) based on ΔNO₃ and these C/N ratios showed large interannual variations. NP_a was usually higher in the western than in the eastern subarctic. However, values of 84 gC m⁻²yr⁻¹ were found in the Alaska Gyre in 2000 which is similar to that in the most productive provinces of the northern North Pacific. There were also large increases in NP_a around the Alaska Peninsula in 1997 and 1998. Finally, the net removal of carbon by the biological pump was estimated as 0.72 Gt C yr⁻¹ in the North Pacific (>30°N). This revised version was published online in August 2006 with corrections to the Cover Date.     

An early warning system for wave-driven coastal flooding at Imperial Beach,CA

Natural Hazards - Waves overtop berms and seawalls along the shoreline of Imperial Beach (IB), CA when energetic winter swell and high tide coincide. These intermittent, few-hour long events flood...     

A hierarchical approach measures the aerial extent and concentration levels of PAH-contaminated shoreline sediments at historic industrial sites in Prince William Sound, Alaska

A field study was conducted in 2003 to estimate the areal distribution and concentrations of polycyclic aromatic hydrocarbons (PAH) in intertidal sediments at sites of past human and industrial activity (HA sites) in Prince William Sound (PWS), Alaska, the site of the 1989 Exxon Valdez oil spill. More than 50 HA sites, primarily in western PWS, were identified through analysis of historic records and prior field studies, and nine sites were selected for detailed surveys. The areal assessment process consisted of seven steps: (1) identify site from historic records and field surveys; (2) locate visual evidence of surface oil/tar at a site; (3) prepare a site map and lay out a sampling grid over the entire site with 10-m grid spacing; (4) excavate pits to 50 cm depth on the grid; (5) perform a field colorimetric test to estimate total PAH (TPAH) in sediments from the wall of each pit and record the results in the ranges <1 ppm; 1-10 ppm; >10 ppm TPAH; (6) expand grid size if necessary if elevated PAH levels are detected colorimetrically; (7) select 20 samples from each site for same-day shipboard PAH analysis by immunoassay (SDI RaPID PAH) and, based on these results, select sediment samples from each site for full PAH analysis in the laboratory to identify PAH sources. A total of 416 pits were dug at the nine sites. Nine acres of sediments with TPAH >2500 ppb dry wt. were mapped at the nine sites. TPAH concentrations obtained by immunochemical analysis of 181 samples from the nine sites ranged from 20 to 1,320,000 ppb (wet wt.). The contaminants are mixtures of petroleum products (2-3 ring PAH) and combustion products (4-6 ring PAH) unrelated to the 1989 Exxon Valdez oil spill. Mussels and clams collected at these sites have elevated levels of PAH that are compositionally similar to the PAH in the sediments. These findings indicate that at least a portion of the sediment PAH is bioavailable. The PAH sources at these historic industrial sites are chronic. They include relict fuel oil tanks and works located above and within the intertidal zone, with contamination at some locations extending into nearshore sub-tidal sediments. This study shows how a hierarchical approach can be used to quickly and successfully map, quantify, and subsequently, identify sources of PAH in shoreline sediments.     

STAGES: the Space Telescope A901/2 Galaxy Evolution Survey

We present an overview of the Space Telescope A901/2 Galaxy Evolution Survey (STAGES). STAGES is a multiwavelength project designed to probe physical drivers of galaxy evolution across a wide range of environments and luminosity. A complex multicluster system at   z ∼ 0.165  has been the subject of an 80-orbit F606W Hubble Space Telescope (HST) /Advanced Camera for Surveys (ACS) mosaic covering the full     span of the supercluster. Extensive multiwavelength observations with XMM–Newton , GALEX, Spitzer , 2dF, Giant Metrewave Radio Telescope and the 17-band COMBO-17 photometric redshift survey complement the HST imaging. Our survey goals include simultaneously linking galaxy morphology with other observables such as age, star formation rate, nuclear activity and stellar mass. In addition, with the multiwavelength data set and new high-resolution mass maps from gravitational lensing, we are able to disentangle the large-scale structure of the system. By examining all aspects of an environment we will be able to evaluate the relative importance of the dark matter haloes, the local galaxy density and the hot X-ray gas in driving galaxy transformation. This paper describes the HST imaging, data reduction and creation of a master catalogue. We perform the Sérsic fitting on the HST images and conduct associated simulations to quantify completeness. In addition, we present the COMBO-17 photometric redshift catalogue and estimates of stellar masses and star formation rates for this field. We define galaxy and cluster sample selection criteria, which will be the basis for forthcoming science analyses, and present a compilation of notable objects in the field. Finally, we describe the further multiwavelength observations and announce public access to the data and catalogues.