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排序方式: 共有417条查询结果,搜索用时 31 毫秒
81.
Peter J. Kelly Nelia W. Dunbar Philip R. Kyle William C. McIntosh 《Journal of Volcanology and Geothermal Research》2008
Six new 40Ar/39Ar and three cosmogenic 36Cl age determinations provide new insight into the late Quaternary eruptive history of Erebus volcano. Anorthoclase from 3 lava flows on the caldera rim have 40Ar/39Ar ages of 23 ± 12, 81 ± 3 and 172 ± 10 ka (all uncertainties 2σ). The ages confirm the presence of a second, younger, superimposed caldera near the southwestern margin of the summit plateau and show that eruptive activity has occurred in the summit region for 77 ± 13 ka longer than previously thought. Trachyte from “Ice Station” on the eastern flank is 159 ± 2 ka, similar in age to those at Bomb Peak and Aurora Cliffs. The widespread occurrences of trachyte on the eastern flank of Erebus suggest a major previously unrecognized episode of trachytic volcanism. The trachyte lavas are chemically and isotopically distinct from alkaline lavas erupted contemporaneously in the summit region < 5 km away. 相似文献
82.
Volcanic emission rates of As, Sb, Pb, Hg, Se, Cl, and F were determined at Erebus volcano, Antarctica and White Island, New Zealand, using chemical traps. The trace metal fluxes were determined by combining the species to S ratios in the solutions with SO2 emission rates measured by correlation spectrometry at the two volcanoes. At Erebus volcano, fluxes for the metals Pb and Hg were 2.0 × 10− 4 and 8.1 × 10− 6 kg s− 11, respectively. Fluxes for Cl, F, As, Sb and Se (0.35, 0.15, 2.5 × 10− 4, 1.2 × 10− 5, and 4.5 × 10− 6 kg s− 1, respectively) agreed within error limits for values determined previously by the LiOH impregnated filter method [Zreda-Gostynska, G., Kyle, P., Finnegan, D., Prestbo, K., 1997. Volcanic gas emissions from Mount Erebus and their impact on the Antarctic environment. Journal of Geophysical Research, 102(B7): 15039–15055.], demonstrating the utility of the chemical trap method. A fall in the As/S ratio from 7 × 10− 4 in 1997/1999 to 3 × 10− 4 in 2000 at Erebus coincided with a change in the frequency and style of eruptive activity that may have been due to injection of magma into the system. At White Island, chemical trap data indicated fluxes of Cl = 0.90, F = 0.0079, Pb = 2.7 × 10− 4, Hg = 1.1 × 10− 5, As = 1.3 × 10− 4, Sb = 1.9 × 10− 5 and Se = 1.5 × 10− 5 kg s− 1. Samples collected 600 m downwind of the active crater were comparable to samples collected adjacent to the main gas vent, showing that this method can still be used at some distance from a degassing vent. 相似文献
83.
Differential developmental toxicity of naphthoic acid isomers in medaka (Oryzias latipes) embryos 总被引:1,自引:0,他引:1
Michael W. Carney Kyle Erwin Ron Hardman Bonny Yuen David C. Volz David E. Hinton Seth W. Kullman 《Marine pollution bulletin》2008,57(6-12):255
Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations. 相似文献
84.
Comparison of flood hazard assessments on desert piedmonts and playas: A case study in Ivanpah Valley, Nevada 总被引:1,自引:0,他引:1
Colin R. Robins Brenda J. Buck Amanda J. Williams Janice L. Morton P. Kyle House Michael S. Howell Maureen L. Yonovitz 《Geomorphology》2009,103(4):520-532
Accurate and realistic characterizations of flood hazards on desert piedmonts and playas are increasingly important given the rapid urbanization of arid regions. Flood behavior in arid fluvial systems differs greatly from that of the perennial rivers upon which most conventional flood hazard assessment methods are based. Additionally, hazard assessments may vary widely between studies or even contradict other maps. This study's chief objective was to compare and evaluate landscape interpretation and hazard assessment between types of maps depicting assessments of flood risk in Ivanpah Valley, NV, as a case study. As a secondary goal, we explain likely causes of discrepancy between data sets to ameliorate confusion for map users. Four maps, including three different flood hazard assessments of Ivanpah Valley, NV, were compared: (i) a regulatory map prepared by FEMA, (ii) a soil survey map prepared by NRCS, (iii) a surficial geologic map, and (iv) a flood hazard map derived from the surficial geologic map, both of which were prepared by NBMG. GIS comparisons revealed that only 3.4% (33.9 km2) of Ivanpah Valley was found to lie within a FEMA floodplain, while the geologic flood hazard map indicated that ~ 44% of Ivanpah Valley runs some risk of flooding (Fig. 2D). Due to differences in mapping methodology and scale, NRCS data could not be quantitatively compared, and other comparisons were complicated by differences in flood hazard class criteria and terminology between maps. Owing to its scale and scope of attribute data, the surficial geologic map provides the most useful information on flood hazards for land-use planning. This research has implications for future soil geomorphic mapping and flood risk mitigation on desert piedmonts and playas. The Ivanpah Valley study area also includes the location of a planned new international airport, thus this study has immediate implications for urban development and land-use planning near Las Vegas, NV. 相似文献
85.
86.
Kyle S. Boodoo Jakob Schelker Nico Trauth Tom J. Battin Christian Schmidt 《水文研究》2019,33(17):2279-2299
Gravel bars (GBs) contribute to carbon dioxide (CO2) emissions from stream corridors, with CO2 concentrations and emissions dependent on prevailing hydraulic, biochemical, and physicochemical conditions. We investigated CO2 concentrations and fluxes across a GB in a prealpine stream over three different discharge‐temperature conditions. By combining field data with a reactive transport groundwater model, we were able to differentiate the most relevant hydrological and biogeochemical processes contributing to CO2 dynamics. GB CO2 concentrations showed significant spatial and temporal variability and were highest under the lowest flow and highest temperature conditions. Further, observed GB surface CO2 evasion fluxes, measured CO2 concentrations, and modelled aerobic respiration were highest at the tail of the GB over all conditions. Modelled CO2 transport via streamwater downwelling contributed the largest fraction of the measured GB CO2 concentrations (31% to 48%). This contribution increased its relative share at higher discharges as a result of a decrease in other sources. Also, it decreased from the GB head to tail across all discharge‐temperature conditions. Aerobic respiration accounted for 17% to 36% of measured surface CO2 concentrations. Zoobenthic respiration was estimated to contribute between 4% and 8%, and direct groundwater CO2 inputs 1% to 23%. Unexplained residuals accounted for 6% to 37% of the observed CO2 concentrations at the GB surface. Overall, we highlight the dynamic role of subsurface aerobic respiration as a driver of spatial and temporal variability of CO2 concentrations and evasion fluxes from a GB. As hydrological regimes in prealpine streams are predicted to change following climatic change, we propose that warming temperatures combined with extended periods of low flow will lead to increased CO2 release via enhanced aerobic respiration in newly exposed GBs in prealpine stream corridors. 相似文献
87.
88.
C. Page Chamberlain John M. Ferry Douglas Rumble III 《Contributions to Mineralogy and Petrology》1990,105(3):322-336
To interpret correctly the isotopic composition of metmorphic rocks and minerals, the effect of nettransfer reactions must be quantitatively evaluated. Such evaluation requires a complete set of linearly independent, net-transfer reactions that fully describe the reacting system. The set of net-transfer reactions is then coupled with mass-balance equations for stable isotopes. Reaction spaces can be contoured with isopleths of °18O, °13C, and D of minerals which allows evaluation of the effect of different reactions and bulk compositions on the stable isotopic composition of minerals and rocks. Using this approach, we examined the effect of fractionation of isotopes due to net-transfer reactions at the biotite and second-sillimanite isograds in northern New England. Our analysis shows that the shift in °13C and °18O at an isograd depends strongly upon the overall net-transfer reaction at the isograd and the bulk composition of the rock. The use of model isograd reactions to determine isotopic shifts, therefore, can lead to serious errors in the interpretation of isotopic data. At the second-sillimanite isograd °18O
qtz
(quartz), °18O
kspar
(K feldsdpar), and °18O
wr
(whole rock) decrease by 0.5, 1.0, and 0.8 per mil, respectively. Quantitative evaluation of the effect of fractionation of isotopes by net-transfer reactions shows that: (1) the relative changes in oxygen isotopes across the isograd could be caused by distillation of fluids during develatilization reactions; (2) the magnitude of the observed isotopic shifts often differs by a factor of 2 from the calculated shifts due to reaction progress alone. The difference between observed and calculated shifts is attributed to either, differences in bulk composition between individual rocks, or, to isotopic exchange between minerals after peak metamorphism. At the biotite isograd the shifts in carbon and oxygen isotope values are different from predicted shifts caused by net-transfer reactions alone. This discrepancy suggests that fluids infiltrated the rocks during the formation of the biotite isograd. 相似文献
89.
Jerry Shannon Kyle Walker 《International journal of geographical information science》2018,32(10):1911-1926
Many scholars have demonstrated growing interest in GIScience in recent years, including use of open data portals, shared code and options for open access publication. These practices have made both research and data more transparent and accessible for a broad audience. This research may be open only in a limited sense for populations without expertise in the technology and methods undergirding these data. Based on two case studies using RStudio’s Shiny web platform, we argue that a process-based approach focusing on how analysis is opened throughout the research process provides a supplementary way to define and reflect upon public facing geographic research. Reflecting upon decisions we made at key points in each case study project, we identify four key tensions inherent to work in open GIScience: standardized vs. flexible tools, expert vs. community-led design, single vs. multiple audiences and established vs. emerging metrics. 相似文献
90.
Ti-in-zircon thermometry: applications and limitations 总被引:16,自引:5,他引:11
Bin Fu F. Zeb Page Aaron J. Cavosie John Fournelle Noriko T. Kita Jade Star Lackey Simon A. Wilde John W. Valley 《Contributions to Mineralogy and Petrology》2008,156(2):197-215
The titanium concentrations of 484 zircons with U-Pb ages of ∼1 Ma to 4.4 Ga were measured by ion microprobe. Samples come
from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons
(32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most
of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon
thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413–433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon
saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (∼15% melt residue
for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous
rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually,
the effects of reduced or , variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low
temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous
melts with significantly lower crystallization temperature for the last 10–15% melt residue than that of the main rock. While
some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included
within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in
Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once.
However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio,
or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and , are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide
overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock
SiO2 and HfO2 for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO2 and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks
average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures
of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons
have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons
from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent
Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration
in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献