Serpentinization at Burro Mountain,California

The Burro Mountain ultramafic complex, Monterey County, California, consists of dunites and peridotites which are partially or wholly serpentinized. Primary minerals in both rock types are olivine, enstatite, diopside, and picotite which upon alteration yield chrysotile, lizardite, brucite, magnetite, talc, tremolite, and carbonate. Electron microprobe analyses show that enstatite, En_85.8 to En_90.8, alters to “bastite” composed only of lizardite (5.0–12.0 weight percent FeO), whereas olivine, Fo_90.8 to Fo_91.6, forms lizardite+chrysotile+brucite with or without magnetite. The chrysotile ranges from 3.0 to 5.0 weight percent FeO, the brucite from 16.0 to 43.0 weight percent FeO. As Serpentinization proceeds, the alteration products are enriched in FeO relative to MgO. Serpentinization probably originates in a changing \(P_{O_2 }\)-T environment by two different reactions:

1. (a)
   Olivine+enstatite+H₂O+O₂?Mg, Fe⁺² chrysotile+Mg, Fe⁺³, Fe⁺² lizardite with or without magnetite.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of the eruptive history of Mount Erebus,Antarctica: volcano evolution

Mt. Erebus, a 3,794-meter-high active polygenetic stratovolcano, is composed of voluminous anorthoclase-phyric tephriphonolite and phonolite lavas overlying unknown volumes of poorly exposed, less differentiated lavas. The older basanite to phonotephrite lavas crop out on Fang Ridge, an eroded remnant of a proto-Erebus volcano and at other isolated locations on the flanks of the Mt. Erebus edifice. Anorthoclase feldspars in the phonolitic lavas are large (~10 cm), abundant (~30–40%) and contain numerous melt inclusions. Although excess argon is known to exist within the melt inclusions, rigorous sample preparation was used to remove the majority of the contaminant. Twenty-five sample sites were dated by the ⁴⁰Ar/³⁹Ar method (using 20 anorthoclase, 5 plagioclase and 9 groundmass concentrates) to examine the eruptive history of the volcano. Cape Barne, the oldest site, is 1,311±16 ka and represents the first of three stages of eruptive activity on the Mt. Erebus edifice. It shows a transition from sub-aqueous to sub-aerial volcanism that may mark the initiation of proto-Erebus eruptive activity. It is inferred that a further ~300 ky of basanitic/phonotephritic volcanism built a low, broad platform shield volcano. Cessation of the shield-building phase is marked by eruptions at Fang Ridge at ~1,000 ka. The termination of proto-Erebus eruptive activity is marked by the stratigraphically highest flow at Fang Ridge (758±20 ka). Younger lavas (~550–250 ka) on a modern-Erebus edifice are characterized by phonotephrites, tephriphonolites and trachytes. Plagioclase-phyric phonotephrite from coastal and flank flows yield ages between 531±38 and 368±18 ka. The initiation of anorthoclase tephriphonolite occurred in the southwest sector of the volcano at and around Turks Head (243±10 ka). A short pulse of effusive activity marked by crustal contamination occurred ~160 ka as indicated by at least two trachytic flows (157±6 and 166±10 ka). Most anorthoclase-phyric lavas, characteristic of Mt. Erebus, are less than 250 ka. All Mt. Erebus flows between about 250 and 90 ka are anorthoclase tephriphonolite in composition.Editorial responsibility: J. Donelly-Nolan     

Evaluation of bioremediation strategies of a controlled oil release in a wetland

A controlled petroleum release was conducted to evaluate bioremediation in a wetland near Houston, Texas. The 140-day study was conducted using a randomized, complete block design to test three treatments with six replicates per treatment. The three treatment strategies were inorganic nutrients, inorganic nutrients with an alternative electron acceptor, and a no-action oiled control. Samples were analyzed for petroleum chemistry and inorganic nutrients. These results are discussed in the context of our related research involving toxicology and microbiology at the site during the experiment. To evaluate biodegradation, the targeted compounds were normalized to the conservative compound C3017alpha, 21beta-[H]hopane, thus reducing the effects of spatial heterogeneity and physical transport. The two biostimulation treatments demonstrated statistically-higher rates of biodegradation than the oiled no-action control. For the majority of the experiment, target nutrient levels were maintained. Further research may be warranted to optimize these bioremediation strategies as well as evaluating additional treatment strategies for wetlands and other shoreline systems.     

Three-dimensional outlier detection for GPS networks and their densification via the BLIMPBE approach

This article discusses outlier detection based on Baarda's theory, but applied to three-dimensional GPS baseline vectors, as compared to the traditional approach of investigating the vector components individually (one-dimensional). In addition, Schaffrin's recently proposed estimator of type BLIMPBE is discussed and contrasted with a minimum constrained least-squares adjustment, specifically Partial-MINOLESS. A more detailed discussion of these topics, which includes additional formulas and derivations, can be found in the first author's Master of Science thesis, hereinafter referred to as Report 465.     

Lithostratigraphy of the Mérida (Wisconsinan) glaciation and Pedregal interstade, Mérida Andes, northwestern Venezuela

At Pedregal, more than 40 m of sediments are exposed within a ‘fan complex’ formed between lateral moraines of the adjacent Mucuchache and El Caballo valleys. Early and late Mérida (Wisconsinan) glaciations are represented by till and till plus proglacial sediments, respectively. A middle Wisconsinan interstadial event, here termed the Pedregal interstade, began at the end of the Early Mérida glaciation at approximately 60 ka BP. Following the retreat of ice from the small Pedregal Basin, a lake formed when the local drainage was blocked due to movement of the Mesa de Caballo along the Boconó Fault. Shallow lake or no-lake phases lasted approximately a few hundred to, at most, 2000 years, and each lake phase was marked by peat accumulation. Four of seven peats identified formed during sufficiently long intervals for soil profiles (incipient to mature Spodosols) also to develop. The Spodosol with the strongest development (Eb/Bsb/Coxb/Cub horizons) is found adjacent to the lowest peat and reflects ongoing early Mérida stadial (MIS 3) conditions; the youngest peats, associated with weak podzolic soils (Eb/Bsb horizons), formed under slightly warmer interstadial conditions, presumably with less soil water. Cyclic lacustrine deposition is related to lake level and relative depth fluctuations, due in part to variable shoreline/delta progradation and shallowing as the lake deepened in general. Whereas final drainage of the lake is related to movement of the Boconó Fault and breach of the moraines that form the Mesa de Caballo, earlier lake level fluctuations appear related to climate change. Radiocarbon dating of the peats suggests they are related to warmer periods and may tentatively correlate with small ‘interstadials’ or ‘D-O events’ detected in the oxygen-isotope record of Greenland ice cores and North Atlantic marine sediments.     

Nighttime temperature field in a valley

Summary An analysis of the nighttime near-surface temperature field at 27 stations in a deep mountain valley has been carried out for 5 nights during which drainage winds developed. It was found that a simple exponential function of time and the pressure level of each station accurately represents the temperature evolution during the night. Of particular interest is the fact that above a particular pressure elevation the temperature increases during the night.

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Nächtliches Temperaturfeld in einem Tal

Zusammenfassung Es wurde eine Analyse des nächdichen oberflächennahen Temperaturfeldes an 27 Stationen in einem tiefen Gebirgstal für funf Nächte, in denen Bergwind auftrat, durchgeführt. Es stellte sich heraus, da\ die Temperaturentwicklung während der Nacht exakt durch eine einfache Exponentialfunktion der Zeit und des Druckniveaus jeder Station beschrieben wird. Von besonderem Interesse ist die Tatsache, da\ die Temperatur während der Nacht über einem bestimmten Druckniveau ansteigt.

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With 3 Figures     

Chemical and physical studies of type 3 chondrites—IV: Annealing studies of a type 3.4 ordinary chondrite and the metamorphic history of meteorites

Samples of a type 3.4 chondrite have been annealed at 400–1000°C for 1–200 hours, their thermoluminescence properties determined and analyzed for K, Na, Mn, Sc and Ca by instrumental neutron activation analysis. After annealing at ?900°C, the samples showed a 50% decrease in TL sensitivity, while after annealing at 1000°C it fell to 0.1-0.01 times its unannealed value and loss of Na and K occurred. The TL and compositional changes resemble those observed for the equilibrated Kernouve chondrite after similar annealing treatments, except that the sharp TL decrease, and element loss, occurred at ~ 1100°C; this difference is presumably due to petrographic differences in the feldspar of the two meteorites. The temperature and the width of the TL peak showed a discontinuous increase after annealing at 800°C; peak temperature jumped from 130 to 200°C and peak width increased from 90 to 150°C. The activation energies for these TL changes are 7–10 kcal/mole. Similar increases in the TL peak temperature have been reported in TL studies of Amelia, VA, albite, where they were associated with the low to high-temperature transformation. However, the activation energy for the transformation is ~80 kcal/mole. These changes in TL emission characteristics resemble trends observed in type 3 ordinary chondrites and it is suggested that type 3.3–3.5 chondrites have a low-feldspar as TL phosphor and > 3.5 have high-feldspar as the phosphor. Thermoluminescence therefore provides a means of palaeothermometry for type 3 ordinary chondrites.     

Multichannel analysis of surface wave method with the autojuggie

The shear (S)-wave velocity of near-surface materials and its effect on seismic-wave propagation are of fundamental interest in many engineering, environmental, and groundwater studies. The multichannel analysis of surface wave (MASW) method provides a robust, efficient, and accurate tool to observe near-surface S-wave velocity. A recently developed device used to place large numbers of closely spaced geophones simultaneously and automatically (the ‘autojuggie’) is shown here to be applicable to the collection of MASW data. In order to demonstrate the use of the autojuggie in the MASW method, we compared high-frequency surface-wave data acquired from conventionally planted geophones (control line) to data collected in parallel with the automatically planted geophones attached to steel bars (test line). The results demonstrate that the autojuggie can be applied in the MASW method. Implementation of the autojuggie in very shallow MASW surveys could drastically reduce the time required and costs incurred in such surveys.