The Appinite-Migmatite Complex of Sanabria, NW Iberian Massif, Spain

The Sanabria appinitic rocks and host migmatites form an unusual,non-peri-batholithic complex in which all the typical membersof the appinite suite are present. It differs from most appiniticcomplexes in the deeper level of emplacement and the close temporaland spatial association with migmatites. Consequently, manyin situ relationships that resulted from the invasion of maficmagma into a crustal anatectic zone are extremely well preserved.The complex shows unequivocal relations between members of theappinitic suite and between these and migmatites derived byanatexis of a gneissic formation (Ollo de Sapo gneiss). Theserelations point to derivation of monzodiorites and biotite dioritesby hydrous basalt fractionation combined with fluid-assistedmelting of the crustal rocks surrounding the appinitic intrusions.This hydrous basic magma may be derived from an enriched regionof the mantle associated with subduction. Petrogenetic modelshave been tested using a combination of field relations andgeochemical data. Despite the complexity of the processes involved,it is concluded that water played an important role in the petrogenesisof the intermediate and mafic magmas. Reaction between monzodioritemelts and the host migmatites was responsible for the generationof a range of intermediate rocks within the complex. The needfor water to facilitate magma generation in both the mantleand the crust suggests that melting is linked with subduction.This interpretation has important implications because appiniticmagmatism may be considered as indicative of subduction processesinvolved not only in the generation of the mafic end-membersof the suite, but also in the generation of batholiths withwhich the appinitic rocks are spatially and temporally associated. KEY WORDS: appinite; monzodiorite; migmatite; Variscan orogen; Iberian massif     

A Quaternary Solution Model for White Micas Based on Natural Coexisting Phengite-Paragonite Pairs

A thermodynamic model for the quaternary white mica solid solutionwith end-members muscovite–Mg-celadonite–paragonite–Fe-celadonite(Ms–MgCel–Pg–FeCel) is presented. The interactionenergies for the MgCel–Pg join, the FeCel–Pg joinand the ternary interactions were obtained from natural coexistingphengite–paragonite pairs. Phengite–paragonite pairswere selected based on the criteria that their chemical compositionsmay be represented as a linear combination of the model end-membercompositions and that the respective formation conditions (350–650°C,4–21 kbar) are accurately known. Previously publishedexcess free energy expressions were used for the Ms–Pg,Ms–MgCel and Ms–FeCel binaries. The suggested mixingmodel was tested by calculating multicomponent equilibrium phasediagrams. This proved to be particularly well suited to reproducecompositional variations of white micas from amphibolite-faciesmetapelites. KEY WORDS: white mica; solution model; equilibrium phase diagrams     

Phase Relations and Chemical Composition of Phengite and Paragonite in Pelitic Schists During Decompression: a Case Study from the Monte Rosa Nappe and Camughera-Moncucco Unit, Western Alps

The metamorphic evolution of metapelites from the eastern partof the Monte Rosa nappe and the Camughera–Moncucco unit,both situated in the upper Penninic units SW of the Simplonline, were investigated using microstructural relationshipsand equilibrium phase diagrams. The units under considerationexperienced pre-Alpine amphibolite-facies conditions and underwenta complex metamorphic evolution during the Alpine orogeny. Peakpressures during an early Alpine high-pressure stage of 12·5–16kbar were similar in the Monte Rosa nappe and Camughera–Moncuccounit. A pronounced thermal gradient is indicated during decompressionleading to an amphibolite-facies overprint, as the decompressionpaths went through the chlorite, biotite and plagioclase stabilityfields in most of the Monte Rosa nappe, through the staurolitefield in the easternmost Monte Rosa nappe and in the Camughera–Moncuccounit, and through the sillimanite field in the easternmost Camughera–Moncuccounit. In high-Al metapelites the initial formation of stauroliteis related to continuous paragonite breakdown and associatedformation of biotite. In the course of this reaction phengitebecomes successively sodium enriched. In low-Al metapelites,in contrast, the initial staurolite formation occurs via thecontinuous breakdown of sodium-rich phengite. In both low- andhigh-Al metapelites the largest volume of staurolite is formedduring the continuous breakdown of sodium-rich phengite belowP–T conditions of about 9·5 kbar at 600–650°C.During this reaction phengite becomes successively potassiumenriched as sodium from phengite is used to form the albitecomponent in plagioclase. For ‘normal’ pelitic chemistries,phengite becomes Na enriched during decompression through thebreakdown of paragonite along a near-isothermal decompressionpath. The Na content in phengite reaches its maximum when paragoniteis entirely consumed. During further decompression the paragonitecomponent in phengite decreases again because Na is preferentiallyincorporated into the albite component of plagioclase. KEY WORDS: metapelites; white mica; high pressure; equilibrium diagrams; Western Alps     

Numerical analysis of the interaction of soil-structure under earthquake loading

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Diagenesis of a mixed siliciclastic/evaporitic sequence of the Middle Muschelkalk (Middle Triassic), the Catalan Coastal Range, NE Spain

The Middle Muschelkalk (Middle Triassic) of the Catalan Coastal Range (north-east Spain) comprises sandstone, mudstone, anhydrite and minor carbonate layers. Interbedded sandstones and mudstones which are dominant in the north-eastern parts of the basin are terminal alluvial fan deposits. South-westward in the basin, the rocks become dominated by interbedded evaporites and mudstones deposited in sabkha/mudflat environments. The diagenetic and pore water evolution patterns of the Middle Muschelkalk suggest a strong facies control. During eodiagenesis, formation of microdolomite, anhydrite, baryte, magnesite, K-feldspar and mixed-layer chlorite/smectite was favoured within and adjacent to the sabkha/mudflat facies, whereas calcite, haematite, mixed-layer illite/smectite and quartz formed mainly in the alluvial facies. Low δ¹⁸O_SMOW values for microdolomite (+23.7 to +28.4%) and K-feldspar overgrowths (+17.3 to +17.7%) suggest either low-temperature, isotopic disequilibrium or precipitation from low-¹⁸O porewaters. Low-¹⁸O waters might have developed, at least in part, during low-temperature alteration of volcanic rock fragments. During mesodiagenesis, precipitation of quartz overgrowths and coarse dolomite occurred in the alluvial sandstones, whereas recrystallization of microdolomite was dominant in the sabkha/mudflat facies. The isotopic compositions of these mesogenetic phases reflect increasing temperature during burial. Upon uplift and erosion, telogenetic calcite and trace haematite precipitated in fractures and replaced dolomite. The isotopic composition of the calcite (δ¹⁸O_SMOW=+21.5 to +25.6%o; δ¹³C= 7.7 to - 5.6%o) and presence of haematite indicate infiltration of meteoric waters.     

Diagenesis and formation water chemistry of Triassic reservoir sandstones from southern Tunisia

The fluvial Triassic reservoir subarkoses and arkoses (2409·5–2519·45 m) of the El Borma oilfield, southern Tunisia, were subjected to cementation by haematite, anatase, infiltrated clays, kaolinite and K-feldspar at shallow burial depths from meteoric waters. Subsequently, basinal brines controlled the diagenetic evolution of the sandstones and resulted initially in the precipitation of quartz overgrowths, magnesian siderite, minor ferroan magnesite and anhydrite. The enrichment of siderite in ¹²C isotope (δ¹³C_PDB= - 14·5 to - 9‰) results from derivation of carbon from the thermal decarboxylation of organic matter. During further burial, the precipitation of dickite and pervasive transformation of kaolinite into dickite occurred, followed by the formation of microcrystalline K-feldspar and quartz, chlorite and illite, prior to the emplacement of oil. Present day formation waters are Na-Ca-Cl brines evolved by the evaporation of seawater and water/mineral interaction and are in equilibrium with the deep burial (≤ 3·1 km) minerals. These waters are suggested to be derived from the underlying Silurian and Devonian dolomitic mudstones.     

Sedimentation at the margins of a late Pleistocene ice-lobe terminating in shallow marine environments, Dundalk Bay, eastern Ireland

Late Pleistocene morainic sequences around Dundalk Bay, eastern Ireland, were deposited in a variety of shallow, glaciomarine environments at the margins of a grounded ice lobe. The deposits are essentially ice-proximal delta-fan and -apron sequences and are divided into two lithofacies associations. Lithofacies association 1 occurs as a series of morainal banks formed at the southern margin of the ice lobe in a body of water open to influences from the Irish Sea. The morainal banks consist mainly of diamictic muds deposited from turbid plumes and by ice-rafting with minor occurrences of turbidites, cross-bedded gravels (subaqueous outwash) and massive boulder gravels (high-density debris flows). Lithofacies association 2 was deposited in a narrow arm of the sea at the north-eastern margin of the ice lobe. The deposits consist mainly of a series of coalescing, ice-proximal Gilbert-type fan deltas which are interbedded distally with tabular and lens-shaped subaqueous deposits. The latter are mainly ice-rafted diamictons, debris-flow deposits and subaqueous sands and gravels. Both lithofacies associations are draped by diamictons formed by a combination of rain-out, debris flow and traction-current activity. At a few localities the upper parts of the sequence have been sheared by minor oscillations of the ice sheet margin. These sequences form part of an extensive belt of glaciomarine deposits which border the drumlin swarms of east-central Ireland. Lithostratigraphic variability is partially related to the arrival of large volumes of debris at the ice lobe margin when the main lowland ice sheet surged during drumlin formation. Complex depositional continua of this type lack any major erosional breaks and should not be used either as climatic proxies or for stratigraphic correlations.     

A long Upper Pleistocene pollen record from Les Echets, near Lyon, France

Analysis of 732 samples through 39 m of sediments from the ancient lake of Les Echets, 15 km northeast of Lyon, France, resulted in a long, continuous pollen diagram covering the interval from the Late Rissian to the Holocene. Above a complete Ecmian sequence, there are two Early Wiirmian temperate cycles (the older one including two climatic optima separated by a brief deterioration) with forest successions characterized by the spread of Carpinus at the end of the early temperate phase. These episodes, whose exact equivalents are found at Grande Pile in the Vosges area, are correlated with the Early Wiirmian trilogy Amersfoort-Brorup-Odderade of northern Europe. The absolute dates proposed for the Grande Pile sequence arc accepted, whereas those for the three northern European stratotypes are rejected. The Early Wiirmian is thus placed between 115,000 and 70,000 years B.P. In the Middle Wiirm, three undated intcrstadials arc characterized by a sparse forest cover. The long Late Wiirmian section is a characteristic feature of the sediment history at Les Echets. Very cold and arid conditions prevailed during this interval, without any unequivocal indications of intcrstadial episodes. A rise in Artemisia around 15,000 B.P. marks the transition from the Pleniglacial to the Oldest Dryas.     

Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples

Quantification of discrete pressure–temperature domains in deformed chlorite + white mica‐bearing metapelites was undertaken on mineral compositions derived by two‐dimensional microprobe compositional mapping of selected areas of rock thin sections. In order to achieve compositional information at sufficient analytical precision, spatial resolution and sample coverage within a typical analysis time of 1 day, an optimization of measurement methods was necessary. The method presented here allows collection of raw counts for eight different element concentrations at an analytical precision of ～1–2 wt%. X‐ray intensity multiplane maps (one map per measured chemical element) are translated into concentration multiplane maps, utilizing selected conventionally measured spot analyses combined with the Castaing approximation for each mineral. As this step requires identification of the different minerals present in the mapped area, a statistical clustering technique to identify different groups of composition was developed, guided by simple petrographic inspection of the thin section, to delineate the important minerals in the mapped area. Finally, the compositions of each pixel are translated into a mineral structural formula thus yielding a new kind of image with a high content of petrological information. The reliability of the mineral composition images was emphasized by carrying out precision tests on the analytical data. The possible use of chemical maps to infer the P–T–deformation history of metamorphic rocks is illustrated with two samples from the Spitzbergen and the Sambagawa blueschist facies belts. In both samples, a strong correlation between structures and chemistry is observed. Qualitative estimates of P–T conditions from the Si‐content of mica and chlorite are in good agreement with their location in microstructures that formed at different times. Therefore, the combination of chemical maps with microstructural observations is a very powerful approach to understand both the evolution of complex metamorphic rocks and the control by deformation of mineral reactivity.