Interstitial water chemistry of villefranche bay sediments: Trace metal diagenesis

Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO₂, SO₄, TH₂S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO₂/ΔSO₄ was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.     

Cytochrome P450 differences in normal and imposex-affected female whelk Buccinum undatum from the open North Sea

Normal and imposex-affected female Buccinum undatum were sampled from the open North Sea at three locations, one with low, and two with high shipping densities. Cytochrome P450 components and P450 aromatase activity were determined in the microsomal fractions isolated from pooled digestive gland/gonads. Cytochrome P450 aromatase activity was significantly higher (P < 0.05) in normal females collected in the low shipping density area (1,325 +/- 295 fmol/h/mg protein) than levels from imposex animals from a high shipping density area (620 +/- 287 fmol/h/mg protein). A negative correlation was found between aromatase activity and organotin body burden (r = -0.99). Levels of CYP450, cytochrome b5 and NADPH cytochrome c reductase activity did not show differences among groups. This is the first field evidence of depressed aromatase activity in imposex affected females, although additional research under laboratory controlled conditions is required to fully understand the mechanisms underlying the development of imposex in this species.     

Dynamic response of the leg of a tension leg platform subjected to an axial, suddenly applied load at one end

This paper deals with the solution of the problem of the dynamic response of the leg of a tension leg platform subjected to an axial, suddenly applied load at one end, considering a highly simplified model but taking into account several complicating factors. The problem is solved by means of a non-harmonic Fourier expansion in terms of eigenfunctions obtained from a non-regular Sturm-Liouville system.     

An experimental analysis of spatial competition in a dense infaunal community: The importance of relative effects

A densely populated soft-sediment community was experimentally analysed for interspecific competition for space in laboratory experiments. No interspecific competitive interactions leading to a decrease in survivorship could be documented over a five-week period. The four most abundant species all coexisted in laboratory microcosms. The two tube-buiding species, the tanaid Leptochelia dubia and the polychaete Rhynchospio arenincola, could not exclude the mobile bivalve Transennella tantilla or the burrowing amphipod Paraphoxus spinosus. None of the species increases its emigration frequency when other species are present. Paraphoxus is found to be a browsing predator on Phynchospio but inflicts no detectable mortality. The coexistence of these species is permitted by virtue of the fact that none of the species can alter the soft-sediment habitat sufficiently to make the habitat unsuitable for the other species.     

Interstitial water chemistry of the inner continental shelf sediments off the gironde estuary

The interstitial water composition ( , alkalinity, Ca²⁺, Mg²⁺, Sr²⁺, Na⁺, K⁺) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of and Ca²⁺ and below a 30 cm depth show depletions of Mg²⁺. Inversely, the upper 10 cm an enrichment of Ca²⁺ concentration, and an increase of K⁺ concentration to a 40 cm depth. High values of are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca²⁺ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg²⁺ depletion is accompanied by bicarbonate loss. This proves that Mg²⁺ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg²⁺ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core.