A sidelight on long range forecasting

Summary A gradually cumulative error due to the use of the hydrostatic approximation is examined through consideration of a simple mathematical model taken from the classical theory of gravity waves. Two cases are chosen which differ solely in the circumstance that in one the hydrostatic assumption is made while in the other it is not. A large divergence of the results present in the later stages is then to be referred to the neglect of terms contained in the exact equation of motion for the vertical direction in one of the solutions. The inference is drawn that comparable phenomena might arise in the integration of the atmospheric equations over long time periods.     

Phase Equilibria in the Metamorphic Rocks of St. Paul Island and Cape North, Nova Scotia

A suite of schists—one from the garnet zone, 19 from thestaurolite zone, 2 from the kyanite isograd, and one from thekyanite zone—were separated into their constituent minerals.Chemical analyses of one chlorite and of 23 sets of coexistingbiotites and garnets were carried out by photometric and titrametricprocedures. Plots of garnet-biotite tie-lines from divariantassemblages on appropriate phase diagrams result in intersectingtie-lines which cannot be ascribed to experimental error. Theoreticalconsiderations argue that at equilibrium, at the same pressureand temperature or at constant pressure and varying temperature,tie-lines of divariant assemblages should not intersect. Possibleexplanations require that diffusion equilibrium of Fe and Mgbe restricted to volumes smaller than that of a hand specimenor that P as well as T varies considerably. Emission spectrographicdeterminations of Fe and Mg in biotite indicate that the Fe/Mgratio varies among biotites little more than a centimeter apart.Such a variation would argue more in favor of a lack of diffusionequilibrium.     

Structure and petrology of an alpine peridotite on Cypress Island,Washington, U.S.A

A study of the structural petrology of a peridotite exposed on Cypress Island in Skagit Co., Washington, U.S.A. has been carried out. The Cypress peridotite is, by virtue of its composition, structure and associations, typical of ultramafics of the alpine type. It contains relict layering and accumulative textures which show it to have originated by crystal settling from a magma of unknown initial composition. Parallelism of lineations and b-axes of folds in the layering with well-developed [100]-maxima in the fabrics of olivine crystals is considered to have arisen through a penetrative deformation of the mass accompanied by plastic flow or recrystallization of the olivine. An indication of the minimum temperature of the deformation is provided by cross-cutting veins of pyroxenite which have not participated in the folding. The most satisfactory interpretation of the overall fabric of the peridotite is that it was deformed, possibly during intrusion, as a crystal mush, and that filter pressing due to compaction of the solid particles by plastic flow or recrystallization removed all but a small percentage of the magmatic fraction which then crystallized following cessation of the movements.     

Note on the propagation of waves from a spherical cavity in an infinite solid

Summary The present note, as its title implies, is concerned with the investigation of disturbances in an infinite elastic medium containing an initial magnetic field in the axial direction. The equations ofMaxwell, those of elasticity have been effectively made use of to solve the problem.     

Ion-exchange reactions on clay minerals and cation selective membrane properties as possible mechanisms of economic metal concentration

A series of exploratory experiments on the concentration of base metals through ion exchange reactions on clay minerals show promising results. The extraction of Pb, Zn and Cd from bentonite, illite, kaolinite and montmorillonite was successful and megascopic quantities of PbS, CdS and ZnS could be obtained at specific loci, depending essentially on the flow velocity, and the other cations present. These or similar exchange reactions are tentatively proposed as possible mechanisms of economic metal concentration during diagenesis.

---

Zusammenfassung Es werden experimentelle Resultate zur Anreicherung von Schwermetallen durch Tonminerale (Montmorillonite, Illite und Kaolinite) mitgeteilt. Eine erste Anreicherung kann über den Kationenaustausch bewirkt werden. In dem darauffolgenden zweiten, sehr viel wirksameren Schritt werden die Schwermetallionen aus den Tonlagern extrahiert und in deren Nähe als schwerlösliche Sulfide oder Carbonate gefällt. Die Extraktion beruht darauf, daß Tonschichten als Kationen-permeable Membranen wirken können. Sie wird von der Art der Tonminerale und der Kationen, den Lösungsgenossen, den Konzentrationsverhältnissen, dem pH-Wert, der Reaktionstemperatur, dem Porenvolumen und der Porenverteilung im Sediment beeinflußt.

     

Isotopic variation of fishes in freshwater and estuarine zones of a large subtropical coastal lagoon

We used stable C and N isotope ratios of tissues from 29 fish species from a large subtropical lagoon in southern Brazil to examine spatial variability in isotopic composition and vertical trophic structure across freshwater and estuarine habitats. Nitrogen isotope ratios indicated a smooth gradation in trophic positions among species, with most fishes occupying the secondary and tertiary consumer level. Fish assemblages showed a significant shift in their carbon isotopic signatures between freshwater and estuarine sites. Depleted carbon signatures (from −24.7‰ to −17.8‰) were found in freshwater, whereas more enriched signatures (from −19.1‰ to −12.3‰) were obtained within the estuarine zone downstream. Based on our survey of the C₃ and C₄ plants and isotopic values for phytoplankton and benthic microalgae reported for ecosystems elsewhere, we hypothesized that the observed δ¹³C differences in the fish assemblage between freshwater and estuarine sites is due to a shift from assimilating organic matter ultimately derived from C₃ freshwater marsh vegetation and phytoplankton at the freshwater site (δ¹³C ranging from −25‰ to −19‰), to C₄ salt-marsh (e.g. Spartina) and widgeon grass (Ruppia maritima), benthic microalgae and marine phytoplankton at the estuarine sites (from −18‰ to −12‰). Our results suggested that fish assemblages are generally supported by autochthonous primary production. Freshwater fishes that likely were displaced downstream into the estuary during periods of high freshwater discharge had depleted δ¹³C values that were characteristic of the upper lagoon. These results suggest that spatial foodweb subsidies can occur within the lagoon.     

Reduction of hydroelastic responses of a very-long floating structure by a floating oscillating-water-column breakwater system

The hydroelastic responses of a very-long floating structure (VLFS) placed behind a reverse T-shape freely floating breakwater with a built-in oscillating water column (OWC) chamber are analyzed in two dimensions. The Bernoulli–Euler beam equation is coupled with the equations of rigid and elastic motions of the breakwater and the VLFS. The interaction of waves between the floating rigid breakwater and the elastic VLFS is formulated in a consistent manner. It has been shown numerically that the structural deflections of the VLFS can be reduced significantly by a suitably designed reverse T-shape floating breakwater.