Ion-exchange reactions on clay minerals and cation selective membrane properties as possible mechanisms of economic metal concentration

A series of exploratory experiments on the concentration of base metals through ion exchange reactions on clay minerals show promising results. The extraction of Pb, Zn and Cd from bentonite, illite, kaolinite and montmorillonite was successful and megascopic quantities of PbS, CdS and ZnS could be obtained at specific loci, depending essentially on the flow velocity, and the other cations present. These or similar exchange reactions are tentatively proposed as possible mechanisms of economic metal concentration during diagenesis.

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Zusammenfassung Es werden experimentelle Resultate zur Anreicherung von Schwermetallen durch Tonminerale (Montmorillonite, Illite und Kaolinite) mitgeteilt. Eine erste Anreicherung kann über den Kationenaustausch bewirkt werden. In dem darauffolgenden zweiten, sehr viel wirksameren Schritt werden die Schwermetallionen aus den Tonlagern extrahiert und in deren Nähe als schwerlösliche Sulfide oder Carbonate gefällt. Die Extraktion beruht darauf, daß Tonschichten als Kationen-permeable Membranen wirken können. Sie wird von der Art der Tonminerale und der Kationen, den Lösungsgenossen, den Konzentrationsverhältnissen, dem pH-Wert, der Reaktionstemperatur, dem Porenvolumen und der Porenverteilung im Sediment beeinflußt.

     

Climatic satellite monitoring of the external heat balance of the oceans and Black Sea

The long-wave outgoing radiation, effective cloudiness equal to the product of the total cloud amount by their optical density, and the sea-surface temperature determined from the satellites are used to determine the annual course of the components of external heat balance on the sea surface whose climatic anomalies, parallel with the meridional heat and water transfer in the ocean-atmosphere system, specify the intraannual and interannual large-scale variations of weather in different regions of the Earth. The development of these studies is connected with the progress of satellite hydrophysics because the data obtained from the space become sufficiently exact, regular, and global. The increase in the existing data array on the external heat balance of the oceans from ∼15–20 to 100 yr and more would promote the solution of the problem of oscillations of Earth's climate. We present examples of coordinated numerical analysis of the heat balance of the upper (0–100 m ) layer of the Black Sea performed on the basis of the shipborne and satellite data. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 59–75, November–December, 2007.     

Isotopic variation of fishes in freshwater and estuarine zones of a large subtropical coastal lagoon

We used stable C and N isotope ratios of tissues from 29 fish species from a large subtropical lagoon in southern Brazil to examine spatial variability in isotopic composition and vertical trophic structure across freshwater and estuarine habitats. Nitrogen isotope ratios indicated a smooth gradation in trophic positions among species, with most fishes occupying the secondary and tertiary consumer level. Fish assemblages showed a significant shift in their carbon isotopic signatures between freshwater and estuarine sites. Depleted carbon signatures (from −24.7‰ to −17.8‰) were found in freshwater, whereas more enriched signatures (from −19.1‰ to −12.3‰) were obtained within the estuarine zone downstream. Based on our survey of the C₃ and C₄ plants and isotopic values for phytoplankton and benthic microalgae reported for ecosystems elsewhere, we hypothesized that the observed δ¹³C differences in the fish assemblage between freshwater and estuarine sites is due to a shift from assimilating organic matter ultimately derived from C₃ freshwater marsh vegetation and phytoplankton at the freshwater site (δ¹³C ranging from −25‰ to −19‰), to C₄ salt-marsh (e.g. Spartina) and widgeon grass (Ruppia maritima), benthic microalgae and marine phytoplankton at the estuarine sites (from −18‰ to −12‰). Our results suggested that fish assemblages are generally supported by autochthonous primary production. Freshwater fishes that likely were displaced downstream into the estuary during periods of high freshwater discharge had depleted δ¹³C values that were characteristic of the upper lagoon. These results suggest that spatial foodweb subsidies can occur within the lagoon.     

Observations of a fast burst of the deep western boundary undercurrent and sediment transport in South Wilmington Canyon from DSRVAlvin

On October 3 and 4, 1986, DSRVAlvin dives encountered a strong current at 2,300 m in South Wilmington Canyon. The current, estimated at 1 knot, transported surficial sediment and constructed and modified bedforms. It appears to have been constant in its direction of flow from 30 to 40°. The observed current was probably a burst of fast flow in a region of slow average currents in the Deep Western Boundary Undercurrent. Such episodic events may have a greater influence on the stratigraphic record than the temporally longer more tranquil flow conditions.     

Regulation of Tilapia metallothionein gene expression by heavy metal ions

Tilapia is a common fish species inhabiting inland waters and estuarine regions in Hong Kong and Southeast Asia, and useful for bio-monitoring of metal pollution. Metallothionein (MT) gene expression in fish tissues has been useful to sub-lethal risk assessment as biomarker of exposure to metal ions in fishes inhabiting metal contaminated area. To investigate metal inductions of Tilapia MT gene expression in vivo, Tilapias were injected with different concentrations of heavy metals and tissues were then removed for quantitative PCR assay using mimic PCR methods. All of the metal ions tested (Cu(2+), Cd(2+), Hg(2+), Ni(2+), Pb(2+) and Zn(2+)) were able to induce hepatic MT mRNA levels. Renal MT mRNA levels of Cd(2+) and Zn(2+) treated fish was not induced with significant fold induction, however MT mRNA levels in gills were sensitive to the administrations of these metal ions. These data indicated that Tilapia MT mRNA levels in gills and liver are sensitive biomarker of exposure to various metal ions.     

Response of the suspended sediment transport system to continental shelf dynamics

Surface currents influenced by a wind-driven upwelling event in San Pedro Bay moved total suspended matter (TSM) confined to the inner shelf on 19 April 1978 seaward, so that by 27 April surface TSM had increased over the outer shelf. Near-bottom concentrations of TSM also increased across the shelf during this time. This is explained by sediment resuspended by large surface waves being advected from the inner shelf seaward by the mean flow after this flow had turned from southeasterly to southerly when upwelling ceased on 26 April. These complex shelf dynamics contribute to the off-shelf transport of mud to the slope and deep basins.     

Variations in the Rate of Anaerobic Succinate Accumulation within the Central and Marginal Regions of an Euryoxic Bivalve Mantle

Abstract. Anaerobic metabolism in the central and marginal portions of the mantle of Mercenaria mercenaria was compared. Anaerobic succinate accumulation was more rapid in the central region. This difference may be due to higher phosphoenolpyruvate carboxykinase activity in the central region. Thus, the central region is more specialized for anaerobic metabolism and the marginal region more for net shell growth. The original rate of succinate accumulation in the mantle is similar in isolated mantles and intact clams, suggesting that mantle succinate production does not require translocation of precursors from other tissues. However, in intact clams, the rate of succinate accumulation in the central region of the mantle slows after four hours. The reduced rate is probably caused by reducing the metabolic rate. Succinate accumulation and shell dissolution are slower in freshly collected clams than in clams that had been stored anaerobically. The difference may be due to induction of PEPCK synthesis during storage. Shell derived calcium did not accumulate in the mantle and, therefore did not alter the intracellular calcium concentration in the mantle.