Domestic Combustion of Biomass Fuels in Developing Countries: A Major Source of Atmospheric Pollutants

Biomass burning has important impacts on atmospheric chemistry and climate. Fires in tropical forests and savannas release large quantities of trace gases and particulate matter. Combustion of biofuels for cooking and heating constitutes a less spectacular but similarly widespread biomass burning activity. To provide the groundwork for a quantification of this source, we determined in rural Zimbabwe the emissions of CO₂, CO, and NO from more than 100 domestic fires fueled by wood, agricultural residues, and dung. The results indicate that, compared to open savanna fires, emissions from domestic fires are shifted towards products of incomplete combustion. A tentative global analysis shows that the source strength of domestic biomass burning is on the order of 1500 Tg CO₂–C yr^–1, 140 Tg CO–C yr^–1, and 2.5 Tg NO–N yr^–1. This represents contributions of about 7 to 20% to the global budget of these gases.     

Portfolio screening to support the mainstreaming of adaptation to climate change into development assistance

The need to mainstream adaptation to climate change into development planning and ongoing sectoral decision-making is increasingly recognised, and several bilateral and multilateral development agencies are starting to take an interest. Over the past years at least six development agencies have screened their project portfolios, generally with two goals in mind: (1) to ascertain the extent to which existing development projects already consider climate risks or address vulnerability to climate variability and change, and (2) to identify opportunities for incorporating climate change explicitly into future projects. As each portfolio screening was conducted independently, the broader lessons emerging from the screenings have not been systematically analysed. In this paper we assess the screening activities to date, focusing on both the results and the methods applied. Based on this assessment we identify opportunities for development agencies to expand their current focus on the links between climate and development. Most agencies already consider climate change as a real but uncertain threat to future development, but they have given less thought to how different development patterns might affect vulnerability to climate change. The screenings undertaken have shown the need to take a comprehensive approach to adaptation and its integration into development planning and sectoral decision-making, and a number of policy initiatives have been taken to promote such integration. We provide some initial guidance as to how portfolio screening can be carried out in a way that would allow agencies to assess systematically the relevance of climate change to their ongoing and planned development projects.     

The periodicity of storm surges in the Bering Sea from 1898 to 1993, based on newspaper accounts

Spectral analysis of 96 yr of Bering Sea storm records reported in the Nome News (1899–1903) and Nome Nugget (1901–1993) newspapers indicate regularities in the 11-, 5–7- and 3-yr periods. Statistical tests on the 11-yr period found no statistically significant correlation with sunspot cyclicity despite a tendency toward maximum storminess during low sunspot periods. The 3- and 5–7-yr cycles may correlate with variability in the El Niño Southern Oscillation and easterly shifts in the mean position of North Pacific low pressure anomalies. Storm surges were infrequent from 1916 to 1928 and 1947 to 1959, while the most frequent and intense storms hit during 1900–1913, 1936–1946, 1974–1976 and in 1992.     

The Late Holocene tephra record of the central Mediterranean Sea: Mapping occurrences and new potential isochrons for the 4.4–2.0 ka time interval

Five cores from the southern Tyrrhenian and Ionian seas were studied for their tephra and cryptotephra content in the 4.4–2.0 ka time interval. The chronological framework for each core was obtained by accelerator mass spectrometry ¹⁴C dating, the occurrence of distinct marker tephra and stratigraphic correlation with adjacent records. Tephrochronology allowed us to correlate the analyzed deposits with tephra markers associated with Somma-Vesuvius (79 ad ), Ischia Island (Cretaio), Mt Etna (FG, FL and FS) and Campi Flegrei (Astroni-Agnano Monte Spina) events. For the first time in the marine setting, a large single glass data set is provided for the Late Holocene Etnean marker beds including the FS tephra (ca. 4.3 ka). Moreover, unknown deposits from Lipari (ca. 2.2–2.0 ka) and Vulcano (3.6–3.3 ka) are also recognized at more distal sites than previously reported. These results contribute to improve the high-resolution tephrostratigraphic framework of the central Mediterranean Sea. They also provide new insights into the chemical composition and dispersal pattern of tephras that can be used as inter-archive tools for regional and ‘local’ stratigraphic correlations and for addressing paleoclimate research.     

A Frequency Matching Method: Solving Inverse Problems by Use of Geologically Realistic Prior Information

The frequency matching method defines a closed form expression for a complex prior that quantifies the higher order statistics of a proposed solution model to an inverse problem. While existing solution methods to inverse problems are capable of sampling the solution space while taking into account arbitrarily complex a priori information defined by sample algorithms, it is not possible to directly compute the maximum a posteriori model, as the prior probability of a solution model cannot be expressed. We demonstrate how the frequency matching method enables us to compute the maximum a posteriori solution model to an inverse problem by using a priori information based on multiple point statistics learned from training images. We demonstrate the applicability of the suggested method on a synthetic tomographic crosshole inverse problem.     

Spatial, temporal and geochemical characteristics of Silurian collision-zone magmatism, Newfoundland Appalachians: An example of a rapidly evolving magmatic system related to slab break-off

Silurian plutonic suites in the Newfoundland Appalachians include abundant gabbro, monzogabbro and granite to granodiorite and lesser quartz diorite and tonalite. Most are medium- to high-K, but included are some low-K and shoshonitic mafic compositions. Felsic rocks are of both alkaline (A-type or within-plate granite (WPG)) and calc-alkaline volcanic arc granite (VAG) affinity. Mafic rocks include both arc-like (Nb/Th < 3) calc-alkaline and non-arc-like (Nb/Th > 3) transitional calc-alkaline basalt to continental tholeiitic affinity compositions. ε_Nd(T) values range from − 9.6 to + 5.4 and δ¹⁸O (VSMOW) values range from + 3.1 to + 13.2‰.

A rapid progression from exclusively arc-type to non-arc-like mafic and then contemporaneous WPG plus VAG magmatism has been documented using precise U–Pb zircon dating. Earlier arc-like plutonism indicates subduction, while asthenosphere-derived mafic magmas support slab break-off, due to subduction of a young, warm back-arc basin. Contemporaneous mafic magmas with arc and non-arc geochemical signatures may reflect tapping of asthenospheric and subcontinental lithospheric mantle (SCLM) sources and/or contamination of asthenosphere-derived magmas by SCLM or crust.

The brevity (< 5 Ma) of the mafic magmatic pulse agrees with the transient nature of magmatism associated with slab break-off. The subsequent ca. 1 to 2 m.y. period of voluminous WPG and VAG plutonism likely reflects mafic magma-driven partial melting of both SCLM and crustal sources, respectively. Continuation of VAG-like magmatism for an additional 2 to 5 m.y. may reflect lower solidus temperatures of crustal materials, enabling anatexis to continue after mantle melting ceased. East to west spatial variation of ε_Nd and (La/Yb)_CN in Silurian plutons suggests a transition from shallow melting of juvenile sources proximal to the collision zone to deeper melting of old source materials in the garnet-stability field further inboard.

Previous work has demonstrated that geochemical discriminaton of post-collisional granitoid magmatism (PCGM) is difficult in the absence of other constraints. Our example should contribute to the understanding and identification of PCGM if it can be employed as a ‘fingerprint’ for slab break-off-related PCGM within the Paleozoic geological record.     

Ein Beitrag zur Petrographie Melilith-führender Olivinnephelinite aus dem Gebiet Fritzlar—Naumburg (Nordhessen)

Zusammenfassung Tertiäre Olivinnephelinite aus dem Gebiet zwischen Naumburg und Fritzlar südwestlich des Habichtswaldes bei Kassel wurden optisch, röntgenographisch und chemisch untersucht. Die Basalte gehören dem Stamm der Alkali-Olivin-Basalte an und zeigen bis auf Vorkommen im Nordteil des Untersuchungsgebietes ein in den Hauptgemengteilen petrographisch einheitliches Bild.Im Norden des Gebietes treten Limburgite sowie Basalte mit der Paragenese Analcim + Alkalifeldspat + Nephelin auf.Tuffe Bind nur im mittleren Teil des Untersuchungsgebietes aufgeschlossen, welches infolge seiner Morphologie als ein Haupteruptionszentrum anzusehen ist.In einem Teil der Basalte trio (örtlich im Bereich weniger m) Melilith stellen-Weise mit sanduhrförmig eingelagertem Pyroxen auf. Häufig ist der Melilith pseudomorphosiert zu Karbonat und Zeolith oder einer nicht näher bestimmbaren Tonmineralkomponente.Aus dem einheitlichen Bild dieser Basalte wird geschlossen, daß in sämtlichen Vorkommen außer im nördlichen Teil des Gebietes Melilith hätte gebildet werden können. Eine solche Möglichkeit lassen die in der Literatur angegebenen experimentellen Untersuchungen der jeweiligen Systeme zu. Gegen die Bildung von SiO₂-untersättigten Schmelzen durch Assimilation von Sedimenten werden petrographische und geochemische Beobachtungen angeführt. Die Frage nach der Bildung solcher Schmelzen kann jedoch an Hand des Untersuchungsmaterials nicht beantwortet werden. Es werden Reaktionen von Olivin, Pyroxen und Magnetit mit der Sehmelze beobachtet, die denen in experimentell untersuchten Systemen entsprechen.Für das sporadische Auftreten des Melilithes bzw. seiner Pseudomorphosen werden Reaktionen mit Restschmelzen angenommen. Ein Abquetschen dieser Restschmelzen vom Ort ihrer Entstehung kann für die Bildung von Analeim-Basalten im Norden des Untersuchungsgebietes verantwortlich sein.

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Tertiary olivine-nephelinites from the region between Naumburg and Fritzlar, southwest of the Habichtswald near Kassel were investigated by optical, x-ray, and chemical methods. The basalts belong to the alkali-olivine-type. They are petrographically uniform in terms of major constituents, except a few occurrences of limburgites and analcite-basalts in the northern part of the area. The latter contain the paragenesis analcite + alkali feldspar + nepheline. Pyroclastics are only exposed in the central part of the area. Because of its morphology this part may be considered as the main eruption center. Several of the basalt-masses contain melilite, locally in patches of a few meters in extent. Hour glass-shaped inclusions of pyroxene are observed in some of them. In many rocks melilite is replaced by carbonates and zeolites or a clay mineral which could not be precisely identified. It is concluded from the uniform character of these basalts that in all occurrences except the northern part of the area melilite could have been formed. This assumption is in accordance with the experimental results of the systems related to our problem (literature data). Petrological and geochemical observations in this area do not favour the formation of undersaturated liquids from the assimilation of sediments (hypothesis ofDaly andShand). Reactions are observed between the liquid and the minerals olivine, pyroxene and magnetite corresponding to those in experimentally investigated systems. The sporadic occurrence of melilite and its alteration products is derived from reactions with residual liquids. The analcite-basalts in the northern part of the area may originate from a separated residual liquid squeezed off its place of origin.

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Evolution of a tourmaline-bearing lawsonite eclogite from the Elekdağ area (Central Pontides,N Turkey): evidence for infiltration of slab-derived B-rich fluids during exhumation

An undated high-pressure low-temperature tectonic mélange in the Elekda area (central Pontides, N Turkey) comprises blocks of MORB-derived lawsonite eclogite within a sheared serpentinite matrix. In their outer shells, some of the eclogite blocks contain large (up to 6 cm) tourmaline crystals. Prograde inclusions in poikiloblastic garnet from a well-preserved eclogite block are lawsonite, epidote/clinozoisite, omphacite, rutile, glaucophane, chlorite, Ba-bearing phengite, minor actinolite, winchite and quartz. In addition, glaucophane, lawsonite and rutile occur as inclusions in omphacite. These inclusion assemblages document the transition from a garnet-lawsonite-epidote-bearing blueschist to a lawsonite eclogite with the peak assemblage garnet + omphacite I + lawsonite + rutile. Peak metamorphic conditions are not well-constrained but are estimated approximately 400–430°C and >1.35 GPa, based on Fe–Mg exchange between garnet and omphacite and the coexistence of lawsonite + omphacite + rutile. During exhumation of the eclogite–serpentinite mélange in the hanging wall of a subduction system, infiltration of B-rich aqueous fluids into the rims of eclogite blocks caused retrogressive formation of abundant chlorite, titanite and albite, followed by growth of tourmaline at the expense of chlorite. At the same time, omphacite I (X_Jd=0.24–0.44) became unstable and partially replaced by omphacite II characterized by higher X_Jd (0.35–0.48), suggesting a relatively low silica activity in the infiltrating fluid. Apart from Fe-rich rims developed at the contact to chlorite, tourmaline crystals are nearly homogeneous. Their compositions correspond to Na-rich dravite, perhaps with a small amount of excess (tetrahedral) boron (~5.90 Si and 3.10 B cations per 31 anions). ¹¹ B values range from –2.2 to +1.7. The infiltrating fluids were most probably derived from subducting altered oceanic crust and sediments.     

Stochastic Modelling of Mineral Exploration Targets

Mathematical Geosciences - Mineral deposits are metal enrichment anomalies, occurring as local manifestations of the interplay between various geological processes that operate at a wide range of...