Mercury,Trace Elements and Organic Constituents in Atmospheric Fine Particulate Matter,Shenandoah National Park,Virginia, USA: A Combined Approach to Sampling and Analysis

Compliance with U.S. air quality regulatory standards for atmospheric fine particulate matter (PM_2.5) is based on meeting average 24 hour (35 μ m^?3) and yearly (15 μg m^?3) mass‐per‐unit‐volume limits, regardless of PM_2.5 composition. Whereas this presents a workable regulatory framework, information on particle composition is needed to assess the fate and transport of PM_2.5 and determine potential environmental/human health impacts. To address these important non‐regulatory issues an integrated approach is generally used that includes (1) field sampling of atmospheric particulate matter on filter media, using a size‐limiting cyclone, or with no particle‐size limitation; and (2) chemical extraction of exposed filters and analysis of separate particulate‐bound fractions for total mercury, trace elements and organic constituents, utilising different USGS laboratories optimised for quantitative analysis of these substances. This combination of sampling and analysis allowed for a more detailed interpretation of PM_2.5 sources and potential effects, compared to measurements of PM_2.5 abundance alone. Results obtained using this combined approach are presented for a 2006 air sampling campaign in Shenandoah National Park (Virginia, USA) to assess sources of atmospheric contaminants and their potential impact on air quality in the Park. PM_2.5 was collected at two sampling sites (Big Meadows and Pinnacles) separated by 13.6 km. At both sites, element concentrations in PM₂₅ were low, consistent with remote or rural locations. However, element/Zr crustal abundance enrichment factors greater than 10, indicating anthropogenic input, were found for Hg, Se, S, Sb, Cd, Pb, Mo, Zn and Cu, listed in decreasing order of enrichment. Principal component analysis showed that four element associations accounted for 84% of the PM_2.5 trace element variation; these associations are interpreted to represent: (1) crustal sources (Al, REE); (2) coal combustion (Se, Sb), (3) metal production and/or mobile sources (Mo, Cd, Pb, Cu, Zn) and (4) a transient marine source (Sr, Mg). Concentrations of Hg in PM_2.5 at background levels in the single pg m^?3 were shown by collection and analysis of PM_2.5 on filters and by an automated speciation analyser set up at the Big Meadows air quality site. The speciation unit revealed periodic elevation of reactive gaseous mercury (RGM) that co‐occurred with peaks in SO₂, indicating an anthropogenic source. GC/MS total ion current chromatograms for the two sites were quite similar indicating that organic signatures were regional in extent and/or that the same compounds were present locally at each site. Calculated carbon preference index values for n‐alkanes indicated that plant waxes rather than anthropogenic sources, were the dominant alkane source. Polycyclic aromatic hydrocarbons (PAHs) were detected, with a predominance of non‐alkylated, and higher molecular weight PAHs in this fraction, suggestive of a combustion source (fossil fuel or forest fires).     

Phytoplankton growth, microzooplankton herbivory and community structure in the southeast Bering Sea: insight into the formation and temporal persistence of an Emiliania huxleyi bloom

Using the seawater dilution technique, we measured phytoplankton growth and microzooplankton grazing rates within and outside of the 1999 Bering Sea coccolithophorid bloom. We found that reduced microzooplankton grazing mortality is a key component in the formation and temporal persistence of the Emiliania huxleyi bloom that continues to proliferate in the southeast Bering Sea. Total chlorophyll a (Chl a) at the study sites ranged from 0.40 to 4.45 μg C l⁻¹. Highest phytoplankton biomass was found within the bloom, which was a mixed assemblage of diatoms and E. huxleyi. Here, 75% of the Chl a came from cells >10 μm and was attributed primarily to the high abundance of the diatom Nitzschia spp. Nutrient-enhanced total phytoplankton growth rates averaged 0.53 d⁻¹ across all experimental stations. Average growth rates for >10 μm and <10 μm cells were nearly equal, while microzooplankton grazing varied among stations and size fractions. Grazing on phytoplankton cells >10 μm ranged from 0.19 to 1.14 d⁻¹. Grazing on cells <10 μm ranged from 0.02 to 1.07 d⁻¹, and was significantly higher at non-bloom (avg. 0.71 d⁻¹) than at bloom (avg. 0.14 d⁻¹) stations. Averaged across all stations, grazing by microzooplankton accounted for 110% and 81% of phytoplankton growth for >10 and <10 μm cells, respectively. These findings contradict the paradigm that microzooplankton are constrained to diets of nanophytoplankton and strongly suggests that their grazing capability extends beyond boundaries assumed by size-based models. Dinoflagellates and oligotrich ciliates dominated the microzooplankton community. Estimates of abundance and biomass for microzooplankton >10 μm were higher than previously reported for the region, ranging from 22,000 to 227,430 cells l⁻¹ and 18 to 164 μg C l⁻¹. Highest abundance and biomass occurred in the bloom and corresponded with increased abundance of the large ciliate Laboea, and the heterotrophic dinoflagellates Protoperidinium and Gyrodinium spp. Despite low grazing rates on phytoplankton <10 μm within the bloom, the abundance and biomass of small microzooplankton (<20 μm) capable of grazing E. huxleyi was relatively high at bloom stations. This body of evidence, coupled with observed high grazing rates on large phytoplankton cells, suggests the phytoplankton community composition was strongly regulated by herbivorous activity of microzooplankton. Because grazing behavior deviated from size-based model predictions and was not proportional to microzooplankton biomass, alternate mechanisms that dictate levels of grazing activity were in effect in the southeastern Bering Sea. We hypothesize that these mechanisms included morphological or chemical signaling between phytoplankton and micrograzers, which led to selective grazing pressure.     

Work schedules on lowland farms in southern New Zealand from the late colonial period to the 1930s

Details of two‐way flows of primary products, implements, labour, information and finance drawn from runs of farm diaries, stock and station agents’ records, and newspaper articles were used to analyse work schedules on three comparable properties between 1874 and 1930, and to track the development of mixed cropping and livestock farming in southern New Zealand when draught horses were giving way to either steam or internal combustion engines as the prime source of motive power. The earliest records are for two farms in the late 19th century, and the most recent are for a third property in the 1920s.     

Grain‐size variability within a mega‐scale point‐bar system,False River,Louisiana

Point bars formed by meandering river systems are an important class of sedimentary deposit and are of significant economic interest as hydrocarbon reservoirs. Standard point‐bar models of how the internal sedimentology varies are based on the structure of small‐scale systems with little information about the largest complexes and how these might differ. Here a very large point bar (>25·0 m thick and 7·5 × 13·0 km across) on the Mississippi River (USA) was examined. The lithology and grain‐size characteristics at different parts of the point bar were determined by using a combination of coring and electrical conductivity logging. The data confirm that there is a general fining up‐section along most parts of the point bar, with a well‐defined transition from massive medium‐grained sands below about 9 to 11 m depth up into interbedded silts and fine–medium sand sediment (inclined heterolithic strata). There is also a poorly defined increase in sorting quality at the transition level. Massive medium sands are especially common in the region of the channel bend apex and regions upstream of that point. Downstream of the meander apex, there is much less evidence for fining up‐section. Finer sediment accumulated more readily after the establishment of a compound bar in the later stages of construction, at the terminal apex and in the bar tail. This work implies that the best reservoir sands are likely to be located in the centre of the point bar, deposited in a simple bar system. Reservoir quality decreases towards the bar edge. The early‐stage channel plug is largely composed of coarsening‐upward cycles of silt to clay and is dominated by clay and clayey silt material with poor reservoir characteristics.     

Evaluation of reliquefaction resistance using shaking table tests

Cases of modern and prehistoric liquefaction illustrate that sand deposits can be liquefied again (or “reliquefied”) by a subsequent earthquake after initially liquefying during seismic shaking. In order to test the validity of two postulates regarding reliquefaction mechanisms and to examine the role of gradational characteristics on reliquefaction resistance, 1 g shaking table tests were performed using five sands with differing gradation characteristics. The test results demonstrate that the number of cycles required to reliquefy each sand decreased significantly following the 1st liquefaction event as a result of destroying the “aged” sand fabric developed prior to the 1st shaking event via secondary compression of the initially loose sands. Reliquefaction resistance correlated reasonably well with a proxy for c_v (∝D₁₀²D_r^2.8), illustrating that both the permeability and compressibility of the sand play significant roles in the post-liquefaction fabric (and hence reliquefaction resistance) formed by a sand. While the initial decrease in reliquefaction resistance supports both the Oda et al. [8] and the Olson et al. [5] reliquefaction postulates, only the Olson et al. [5] postulate reasonably explains the subsequent, large increase in reliquefaction resistance observed during the 3rd through 5th shaking events. These tests suggest that the coefficient of consolidation, c_v=k_v/γ_wm_v (or proxy values such as D₁₀²D_r^2.8 or D₁₀/C_U) may be a useful tool for evaluating reliquefaction potential in forward and inverse (i.e., paleoliquefaction) analysis.     

Agrobiodiversity and Shade Coffee Smallholder Livelihoods: A Review and Synthesis of Ten Years of Research in Central America

We used households as the primary unit of analysis to synthesize agrobiodiversity research in small-scale coffee farms and cooperatives of Nicaragua and El Salvador. Surveys, focus groups, and plant inventories were used to analyze agrobiodiversity and its contribution to livelihoods. Households managed high levels of agrobiodiversity, including 100 shade tree and epiphyte species, food crops, and medicinals. Small farms contained higher levels of agrobiodiversity than larger, collectively managed cooperatives. Households benefited from agrobiodiversity through consumption and sales. To better support agrobiodiversity conservation, our analysis calls for a hybrid approach integrating bottom-up initiatives with the resources from top-down projects.     

Assessment of excess nitrate development in the subtropical North Atlantic

Geochemical estimates of N₂ fixation in the North Atlantic often serve as a foundation for estimating global marine diazotrophy. Yet despite being well-studied, estimations of nitrogen fixation rates in this basin vary widely. Here we investigate the variability in published estimates of excess nitrogen accumulation rates in the main thermocline of the subtropical North Atlantic, testing the assumptions and choices made in the analyses. Employing one of these previously described methods, modified here with improved estimates of excess N spatial gradients and ventilation rates of the main thermocline, we determine a total excess N accumulation rate of 7.8 ± 1.7 × 10¹¹ mol N yr^− 1. Contributions to excess N development include atmospheric deposition of high N:P nutrients (adding excess N at a rate of 3.0 ± 0.9 × 10¹¹ mol N yr^− 1 for  38% of the total), high N:P dissolved organic matter advected into and mineralized in the main thermocline (adding excess N at 2.2 ± 1.1 × 10¹¹ mol N yr^− 1 for  28% of the total), and, calculated by mass balance of the excess N field, N₂ fixation (adding excess N at 2.6 ± 2.2 × 10¹¹ mol N yr^− 1 for  33% of the total). Assuming an N:P of 40 and this rate of excess N accumulation due to the process, N₂ fixation in the North Atlantic subtropical gyre is estimated at  4 × 10¹¹ mol N yr^− 1. This relatively low rate of N₂ fixation suggests that i) the rate of N₂ fixation in the North Atlantic is greatly overestimated in some previous analyses, ii) the main thermocline is not the primary repository of N fixed by diazotrophs, and/or iii) the N:P ratio of exported diazotrophic organic matter is much lower than generally assumed. It is this last possibility, and our uncertainty in the N:P ratios of exported material supporting excess N development, that greatly lessens our confidence in geochemical measures of N₂ fixation.     

A boundary layer model for mantle convection with surface plates

Summary. A simple, analytical model for mantle convection with mobile surface plates is presented. Our aim is to determine under what conditions free convection can account for the observed plate motions, and to evaluate the thermal structure of the mantle existing under these conditions. Boundary layer methods are used to represent two-dimensional cellular convection at large Rayleigh and infinite Prandtl numbers. The steady-state structure consists of cells with isentropic interiors enclosed by thermal boundary layers. Lithospheric plates are represented as upper surfaces on each cell free to move at a uniform speed. Buoyancy forces are concentrated in narrow rising and decending thermal plumes; torques imparted by these plumes drive both the deformable mantle and overlying plate. Solutions are found for a comprehensive range of cell sizes. We derive an expression for the plate speed as a function of its length, the mantle viscosity and surface heat flux. Using mean values for these parameters, we find that thermal convection extending to 700 km depth can move plates at 1 cm yr^-1, while convection through the whole mantle can move plates at 4–5 cm yr^-1. Analysis of the steady-state temperature field, for the case of heating from below, shows that the upper thermal boundary layer develops a complex structure, including an 'asthenosphere' defined by a local maximum in the geotherm occurring at depths of 50–150 km.