Stable (C,O) and radiogenic (Sr,Nd) isotopes of carbonates as indicators of magmatic and post-magmatic processes of phoscorite-series rocks and carbonatites from Catalão I,central Brazil

The Late-Cretaceous Catalão I contains stockworks of thin dykes of phoscorite-series rocks, which can be subdivided into P1 (olivine-bearing, phoscorites) and P2/P3 (olivine-lacking, nelsonites). Dolomite carbonatites (DC) are intimately associated with nelsonites, as pockets and dykes. The P2 apatite nelsonite, the P3 magnetite nelsonite, and, to a lesser extent DC, host the Catalão I niobium mineralization. C–O isotopes signatures in carbonates reveal several distinct magmatic and post-magmatic processes. Limpid carbonates with stable isotopic mantle-like composition show Rayleigh fractionation and are interpreted as primary, while those with brittle-turbid aspect, and higher oxygen isotope composition, probably underwent recrystallization by interaction with H₂O-rich fluids. A group of samples shows higher oxygen compositions and lower carbon values, which could be explained by degassing of carbonatite magma during cooling. A degassing pattern, parallel to magmatic degassing but at higher oxygen and lower carbon compositions, observed in carbonate veins, may indicate degassing of fracture filling fluids. Furthermore, C–O isotopes of carbonate from monazite-bearing carbonatite have a positive correlation, indicating a distinct, late-stage carbo-hydrothermal event. Though the Catalão I nelsonites and phoscorites are of igneous origin, they underwent several post-magmatic events, which sometimes overprinted partially or entirely the magmatic isotope signature.     

Zeta potential of single and polymer-coated microbubbles using an adapted microelectrophoresis technique

The zeta potential of microbubbles, generated by injecting pressurised air into water and then releasing the pressure, was determined in the absence and presence of different polyacrylamides. Air was dissolved in either water or solutions of cationic, anionic, amphoteric or nonionic polymers at a constant pressure of four atmospheres. The charge of the bubbles at the shear-zeta plane was measured using a modified microelectrophoresis glass cell, held at a stationary level, at varying pH (2.0–12.0). Known practical problems with this technique were solved, and these solutions are described in detail. The anionic, amphoteric and nonionic polymers increased the negative charge of the bubbles, but the isoelectric point (iep) remained constant at about pH 2.0. Conversely, in the presence of the cationic polymer, the bubbles exhibited positive surface charges between pH 2.0 and 8.0 and an iep of pH 8.0. The results revealed the existence of an important interaction mechanism between air bubbles and polymeric macromolecules; neither this mechanism nor its practical implications have been reported in the literature to date, especially in the treatment of wastewater by flocculation followed by dissolved air flotation (DAF).     

An integrated approach to assess the origins of black films on a granite monument

In the present study, samples arising from the scaling of a Portuguese granite building were examined in an attempt to understand the mechanisms of surface blackening and detachment. The building, the Third Order of St. Francis Church, is located in the city centre of Porto which is an area characterised by moderate motor traffic. The Mediterranean climate and the façade orientation favoured the proliferation of microorganisms on the Third Order of St. Francis Church, in Porto. The scientific approach carried out in the South façade revealed that these coloured layers are essentially of biological origin. Subsequent chemical analysis confirmed microscope observations and pointed out to the presence of organic matter synthesised by cyanobacteria, algae and lichens. Numerous biological marker compounds indicated a significant presence of biogenically derived material, suggesting that biological activity was playing a major role in the development of coloured layers and in the detachment processes in this historic building.     

The Rio Capim volcanic–plutonic–sedimentary belt,São Francisco Craton,Brazil: Geological,geochemical and isotopic evidence for oceanic arc accretion during Palaeoproterozoic continental collision

The collision of oceanic arcs with continents is a common plate tectonic process in the Phanerozoic, but its recognition in the Precambrian is hampered by deformation and metamorphism. The Rio Capim volcanic–plutonic–sedimentary belt lies in sharp tectonic contact with Archaean rocks of the Uauá block in the northern part of the São Francisco craton. Field relationships and high-precision geochronology indicated that the Rio Capim basalts, gabbros, diorites, and dacites were emplaced approximately at 2148–2143 Ma, and later intruded by 2128 Ma-old diorite to tonalite plutons. All rocks were metamorphosed under amphibolite to granulite facies conditions mainly between 2080 Ma and 2070 Ma, but deformation may have lasted until about 2040 Ma as estimated from syn-deformation zircon and titanite grains. The association of basalt, andesite, dacite, and their plutonic counterparts, combined with their positive ε_Nd(t) values and incompatible trace element geochemical signatures similar to island arc magmas, support the proposition that the Rio Capim belt was a Palaeoproteorozoic intra-oceanic arc sequence that collided with a continent, of which the Mesoarchaean Uauá block is a remnant. The implications for the regional evolution and metallogenesis are also discussed.     

Risk in stability evaluation for floating offshore units

During the useful life of a vessel it undergoes various changes that lead to uncertainties in determining the displacement and center of gravity. Besides upgrading work, the very operation of the platform itself involving constant ballast and oil loading and unloading or the use of maintenance equipment can generates uncertainties concerning the displacement and center of gravity. These, therefore, are the parameters that present uncertainties inherent to the vessel's operations. Taking this into account, one example of the application of uncertainties on the displacement and transversal and vertical center of gravity positions will be presented in the analysis of the static stability of a converted FPSO tanker. Another question raised in this work is the deterministic treatment of certain criteria for the parameters that depend on random factors, such as wind, currents and waves. This paper will present a probabilistic approach for the calculation of the roll angle according to resolution IMO A.562 (environment criteria). The two chosen criteria for this analysis were resolutions IMO A.167 (general criteria) and A.562 (weather criterion).     

Engineering geological investigations for the foundations of large structures-examples of a concrete dam and a long bridge in Portugal

The safety of large structures requires adequate foundations, which implies a good knowledge of the geological and geotechnical conditions of the respective ground. In general, that is only possible through engineering geological studies which include proper site investigation techniques, adapted to the nature of the ground (rock mass or soil) and to the associated engineering problems. The paper illustrates the studies carried out for the design of the foundations of Ribeiradio 76 m high concrete gravity dam in a difficult rock mass and of Vasco da Gama Bridge, 13 km long, crossing the Tagus River in Lisbon, Portugal, through piles 75 m deep.     

Pedo‐Geochemical Signatures of Archeological Sites in the Tapirapé‐Aquiri National Forest in Marabá, Amazonia,Brazil

The present study aims to interpret the occupation of terra firme (nonflooded uplands) archeological sites located at Tapirapé‐Aquiri National Forest in the Brazilian state of Pará, through an integrated analysis of pedological, archeological, and geochemical data. We focus on seven archaeological sites, selected among 22 identified in the region. Radiocarbon and thermoluminescence dating indicate distinct periods of occupation over the past ∼6000 years, and the pedo‐geochemical data identify intra‐ and inter‐site differences in soil. Archaeological, chronometric, and pedo‐geochemical data provide a basis for the functional classification of archeological sites found in the region and help to identify specific human activity areas. The results lead us to infer that many of the archeological sites were the result of multiple occupations that left a persistent pedological signature on the landscape.     

Shatter cones and planar deformation features confirm Santa Marta in Piauí State,Brazil, as an impact structure

A total of 184 confirmed impact structures are known on Earth to date, as registered by the Earth Impact Database . The discovery of new impact structures has progressed in recent years at a rather low rate of about two structures per year. Here, we introduce the discovery of the approximately 10 km diameter Santa Marta impact structure in Piauí State in northeastern Brazil. Santa Marta is a moderately sized complex crater structure, with a raised rim and an off‐center, approximately 3.2 km wide central elevated area interpreted to coincide with the central uplift of the impact structure. The Santa Marta structure was first recognized in remote sensing imagery and, later, by distinct gravity and magnetic anomalies. Here, we provide results obtained during the first detailed ground survey. The Bouguer anomaly map shows a transition from a positive to a negative anomaly within the structure along a NE–SW trend, which may be associated with the basement signature and in parts with the signature developed after the crater was formed. Macroscopic evidence for impact in the form of shatter cones has been found in situ at the base around the central elevated plateau, and also in the interior of fractured conglomerate boulders occurring on the floor of the surrounding annular basin. Planar deformation features (PDFs) are abundant in sandstones of the central elevated plateau and at scattered locations in the inner part of the ring syncline. Together, shatter cones and PDFs provide definitive shock evidence that confirms the impact origin of Santa Marta. Crystallographic orientations of PDFs occurring in multiple sets in quartz grains are indicative of peak shock pressures of 20–25 GPa in the rocks exposed at present in the interior of the crater. In contrast to recent studies that have used additional, and sometimes highly controversial, alleged shock recognition features, Santa Marta was identified based on well‐understood, traditional shock evidence.     

Visual analytics for diagnosing spatial interpolation models

The development and widespread use of statistical learning models have brought the need for tools that help analysts diagnose, build, and refine those models. In this work, in particular, we focus on interpolation models, which spatially predict the value of a variable based on the values of its neighborhood. Investigating these results spatially or comparing them with other models at different levels of granularity is still a challenge for the analysts trying to understand and refine their models. To deal with that, we propose a visual analytics model-agnostic tool for facilitating the comparison and refinement of spatial models at different levels of granularity using interactive visualization techniques. The tool was built in collaboration with specialists who used it to diagnose and improve a spatial model for predicting residential real estate prices.     

Tidal dwarf galaxies in the Stephan's Quintet?

We present kinematics and photometric evidence for the presence of seven candidate tidal dwarf galaxies in Stephan's Quintet. The central regions of the two most probable parent galaxies, NGC 7319 and NGC 7318B, contain little or no gas whereas the intragroup medium and, in particular, the optical tails that seem to be associated with NGC 7318B are rich in cold and ionized gas. Two tidal dwarf candidates may be located at the edge of a tidal tail, another located within a tail, and for the four others there is no obvious stellar/gaseous bridge between them and the parent galaxy. Two of the candidates are associated with H I clouds, one of which is, in addition, associated with a CO cloud. All seven regions have low continuum fluxes and high Hα luminosity densities [F(Hα) = (1-60) × 10-14 ergs s^-1 cm^-2]. Their magnitudes (M_B = –16.1 to –12.6), sizes (∼ 3.5 h₇₅ ^-1 kpc), colors (typically B – R = 0.7), and gas velocity gradients (∼ 8 –26 h₇₅ km s^-1 kpc^-1) are typical for tidal dwarf galaxies. In addition, the ratios between their star formation rates determined from Hα and from the B-band luminosity are typical of other tidal dwarf galaxies. The masses of the tidal dwarf galaxies in Stephan's Quintet range from ∼ 2 × 10⁸ to 10¹⁰ M_⊙, and the median value for their inferred mass-to-light ratios is 7 (M/L)_⊙. At least two of the systems may survive possible ‘fallbacks’ or disruption by the parent galaxies and may already be, or turn into, self-gravitating dwarf galaxies, new members of the group. This revised version was published online in September 2006 with corrections to the Cover Date.