1-Hydroxypyrene as a biomarker of PAH exposure in the marine polychaete Nereis diversicolor

The possibility of using the pyrene metabolite 1-hydroxypyrene as a biomarker of polycyclic aromatic hydrocarbons (PAHs) exposure was investigated by exposure of the marine polychaete Nereis diversicolor to several PAHs in the laboratory. Animals were exposed to pyrene alone and to five different PAHs – phenanthrene, anthracene, pyrene, benzo[a]pyrene and benzo[k]flouranthene. After five days of exposure the concentrations of parent PAHs and 1-hydroxypyrene were identified using three different analytical methods, high-performance liquid chromatography with fluorescence detection (HPLC/F), synchronous fluorescence spectroscopy (SFS) and gas chromatography with mass spectrometric detection (GC/MS). The SFS measurements of 1-hydroxypyrene were validated by the more sensitive method HPLC/F. The positive correlation between total PAHs and 1-hydroxypyrene concentrations in the polychaete tissues observed in experiments, suggests the feasibility of 1-hydroxypyrene as a suitable biomarker for total PAH exposure assessment. Furthermore, the possibility of employment of the simple and rapid SFS method instead of HPLC/F for biomarker analysis has been confirmed by the positive and significant correlation between results achieved by these two analytical methods.     

The DNSC08GRA global marine gravity field from double retracked satellite altimetry

Satellite radar altimetry has been monitoring the earth’s oceans from space for several decades. However, only the GEOSAT and ERS-1 geodetic mission data recorded more than a decade ago provide altimetry with adequate spatial coverage to derive a high-resolution marine gravity field. The original geodetic mission data suffer from degradation in quality and coverage close to the coast and in Polar Regions as well as the occasionally wrongly retracking of these, even in the open ocean. In order to improve the quality of these geodetic mission data and to derive a new improved global marine gravity field called DNSC08GRA, a new double retracking technique for analyzing the waveform data has been developed. Multiple retracking allows the system to retrack more data to increase the spatial coverage of the data. Subsequently, a second retracking run is used to enhance the SSH determination by using information from the first fitting to inform the second set of retrackers about smoothly varying sea state parameters. The development of the new global marine gravity field DNSC08GRA is described in this paper. Besides application of new retracking techniques the radar altimetry has been processed using EGM2008 as reference and augmented with ArcGP gravity data and laser altimetry from ICESat to close the Polar gap. DNSC08GRA is seen to perform significantly better than previous global marine gravity field like KMS02. The improvement in accuracy is better than 20% in general, but in coastal regions, the improvement is in many places of the order of 40–50% compared to older global marine gravity field KMS02.     

Towards a more sustainable process industry: A single case study of restructuring within the Eyde process industry cluster

ABSTRACT

Due to increased attention on environmental issues, industrial sustainable restructuring is high on the research agenda. The article adds to the literature through an analysis of a restructuring process within a Norwegian process industry cluster. By introducing an analytical framework combining the concepts of entrepreneurial discovery process and path dependency theory, the article offers a deeper understanding of the role of various types of actors in processes of restructuring. The authors categorise the actors as either firm-level entrepreneurs or system-level entrepreneurs on the basis of their motivation. While the former are motivated mainly by firm success, the latter find their motivation mainly in developing systemic factors. The analytical framework suggests a stepwise analysis of the restructuring, and in each step, the significance and interplay between the two types of entrepreneurs are discussed. Finally, the authors discuss the potential for new path development following from this process. The case study illustrates the important role of system-level entrepreneurs as facilitators and of firm-level entrepreneurs as utilisers of opportunities. The empirical case demonstrates that the two types of entrepreneurs are highly interactive throughout the restructuring process. The article contributes to existing literature by advancing the actor perspective in new path development.     

First indication of Storegga tsunami deposits from East Greenland

A 2.73 m long sediment sequence from Loon Lake, located at 18 m a.s.l. on outer Geographical Society Ø, East Greenland, was investigated for its chronology and changes in physical and biogeochemical properties, macrofossils, and grain‐size distribution. The predominance of marine fossils throughout the sequence, dated by ¹⁴C AMS to between 8630 and 7535 cal. yr BP, shows that the Loon Lake at that time was a marine basin, which according to existing sea‐level curves was about 15–35 m deep. The sequence mainly consists of fine grained homogeneous sediments, which are interrupted by a 0.72 m thick sandy horizon with erosive basis and distinct fluctuations in the grain‐size distribution and in the physical and biogeochemical properties. According to the radiocarbon dates, this sandy horizon was deposited after 8500–8300 cal. yr BP and is interpreted as originating from the Storegga tsunami. The record from Loon Lake provides the first indication of Storegga tsunami deposits from East Greenland. Copyright © 2006 John Wiley & Sons, Ltd.     

A morphometric analysis of tunnel valleys in the eastern North Sea based on 3D seismic data

A 1250 km² 3D seismic volume is used to provide a detailed spatial and geometrical analysis of fifteen Pleistocene tunnel valleys in the Danish North Sea. All the valleys are buried; they are up to 39 km long, 3–4 km wide and up to 350 m deep. The valleys are part of a vast tunnel valley province covering an area of some 0.5 million km² of the formerly glaciated lowland areas of North West Europe. The valleys consist of non‐branching, non‐anastomosing troughs; they exhibit strongly undulating bottom profiles with numerous sub‐basins and thresholds, and are characterised by adverse end slopes. Cross‐cutting relationships and theoretical considerations suggest the occurrence of seven major episodes of valley incision attributed to ice marginal oscillations within a few glacials. Calculations considering the valley end gradients and theoretical ice‐surface profiles suggest that the valleys were formed by pressurised subglacial meltwater erosion. Given a range of theoretical ice‐surface profiles, the adverse end slopes are well beyond the supercooling threshold, which suggests that the water was not in thermal equilibrium with the basal ice and that flow was concentrated in substantial conduits with sufficient mass and flux to maintain water temperature well above the freezing point. Copyright © 2007 John Wiley & Sons, Ltd.     

Palaeoecology of two lake basins from Disko,West Greenland

The macrofossils, lithology and chronology of two lake basins on Disko in central West Greenland have been investigated. Both lakes were isolated from the sea in the mid-Holocene as a result of relative land uplift. A marine-brackish-limnic sequence was recovered from the Qivittut Lake. The marine fauna is unusually diverse, whereas the brackish water fauna consists only of few species. Immediately after isolation the lake passed through a short-lived eutrophic phase, after which stable, mesotrophic conditions were established. From the second lake basin, the Fortunebay Lake, only limnic sediments were recovered. This lake record demonstrates that rather stable conditions have persisted since mid-Holocene times. Both lakes show anomalously high accumulation rates.     

Holocene climate changes in southern Greenland: evidence from lake sediments

A Holocene lake sediment record is presented from Lake N14 situated on Angissoq Island 15 km off the main coast of southern Greenland. The palaeoclimatic development has been interpreted on the basis of flux and percentage content of biogenic silica, clastic material, organic material and sulphur as well as sedimentation rate, moss content and magnetic susceptibility. A total of 43 radiocarbon dates has ensured a reliable chronology. It is argued that varying sediment composition mainly reflects changing precipitation. By analogy with the present meteorological conditions in southern Greenland, Holocene climate development is inferred. Between 11 550 and 9300 cal. yr BP temperature and precipitation increase markedly, but this period is climatically unstable. From 9300 yr BP conditions become more stable and a Holocene climatic optimum, characterised by warm and humid conditions, is observed from 8000 to 5000 cal. yr BP. From 4700 cal. yr BP the first signs of a climatic deterioration are observed, and from 3700 cal. yr BP the climate has become more dry and cold. Superimposed on the climatic long‐term trend is climate variability on a centennial time‐scale that increases in amplitude after 3700 cal. yr BP. A climatic scenario related to the strength and position of the Greenland high‐pressure cell and the Iceland low‐pressure cell is proposed to explain the Holocene centennial climate variability. A comparison of the Lake N14 record with a terrestrial as well as a marine record from the eastern North Atlantic Ocean suggests that the centennial climate variability was uniform over large areas at certain times. Copyright © 2004 John Wiley & Sons, Ltd.     

Relationships between morphological and sedimentological parameters in source‐to‐sink systems: a basis for predicting semi‐quantitative characteristics in subsurface systems

The study of source‐to‐sink systems relates long‐term variations in sediment flux to morphogenic evolution of erosional–depositional systems. These variations are caused by an intricate combination of autogenic and allogenic forcing mechanisms that operate on multiple time scales – from individual transport events to large‐scale filling of basins. In order to achieve a better understanding of how these mechanisms influence morphological characteristics on different scales, 29 submodern source‐to‐sink systems have been investigated. The study is based on measurements of morphological parameters from catchments, shelves and slopes derived from a ∼1 km global digital elevation model dataset, in combination with data on basin floor fans, sediment supply, water discharge and deposition rates derived from published literature. By comparing various morphological and sedimentological parameters within and between individual systems, a number of relationships governing system evolution and behaviour are identified. The results suggest that the amount of low‐gradient floodplain area and river channel gradient are good indicators for catchment storage potential. Catchment area and river channel length is also related to shelf area and shelf width, respectively. Similarly to the floodplain area, these parameters are important for long‐term storage of sediment on the shelf platform. Additionally, the basin floor fan area is correlative to the long‐term deposition rate and the slope length. The slope length thus proves to be a useful parameter linking proximal and distal segments in source‐to‐sink systems. The relationships observed in this study provide insight into segment scale development of source‐to‐sink systems, and an understanding of these relationships in modern systems may result in improved knowledge on internal and external development of source‐to‐sink systems over geological time scales. They also allow for the development of a set of semi‐quantitative guidelines that can be used to predict similar relationships in other systems where data from individual system segments are missing or lacking.     

Tertiary tectonic evolution along the Arne-Elin Trend in the Danish Central Trough

Tertiary sequence boundaries are mapped on reflection seismic sections in the northern part of the Danish Central Trough, North Sea. The geometry of the sequence boundaries and the isopach maps of the sequences are used as indicators of differential subsidence. The Tertiary tectonic evolution is subdivided into: (i) Late Palaeocene and Early Oligocene episodes of inversion along the NNW–SSE striking Arne–Elin Trend (ii) Early Oligocene to Pliocene episodes of differential subsidence across pre-Tertiary fault trends. The observed differential subsidence and inversion is related to pre-Tertiary faults and fault trends, and dating of the sequences shows that the tectonic phases were contemporaneous with tectonic events in NW Europe. It is suggested that the differential subsidence-inversion is controlled by reactivation of pre-Tertiary faults/fault-trends by block movements due to an interaction of the Alpine collision and the opening of the Atlantic.