Petrology and geochemistry of post-collisional Middle Eocene volcanic units in North-Central Turkey: Evidence for magma generation by slab breakoff following the closure of the Northern Neotethys Ocean

The Eocene volcano-sedimentary units of Northern Anatolia are confined into a narrow zone trending parallel to the Intra Pontide and İzmir–Ankara–Erzincan sutures, along which the northern branch of the Neotethys Ocean was closed during a period between Late Maastrichtian and Paleocene. The Middle Eocene formations overlie both the imbricated and highly deformed units of the suture zone, which are Paleocene or older in age, as well as the formations of adjacent continental blocks with a regional disconformity. Therefore, they can be regarded to be post-collisional. These units are composed of subaerial to shallow marine sedimentary beds (i.e. the Örencik formation) at the base and a subaerial volcanic unit (i.e. the Hamamözü formation) in the middle and at the top. This sudden facies change from marine to subaerial environment in the Middle Eocene is a common phenomenon across northern Turkey, implying that a regional uplift event occurred possibly across the suture zone before the initiation of the volcanism during Lutetian. The Middle Eocene lavas span the whole compositional range from basalts to rhyolites and display a calc-alkaline character except for alkaline to mildly-alkaline lavas from the top of the sequence. All lavas display a distinct subduction signature. Our geochemical data indicate that calc-alkaline lavas were derived from a subduction-modified source, whereas alkaline to mildly-alkaline lavas of the late stage were possibly sourced by an enriched mantle domain. Magmas evolved in magma chambers emplaced possibly at two different crustal levels. Magmas in deeper (> 13 km) and possibly larger chambers fractionated hydrous mafic minerals (e.g. amphibole and biotite), two pyroxenes and plagioclase and assimilated a significant amount of crustal material. Intermediate to acid calc-alkaline lavas and pyroclastics were derived from these chambers. Magmas in the shallower chambers, on the other hand (~ < 12 km), crystallized anhydrous mineral assemblages, assimilated little or no crustal material and fed basic to intermediate lavas in the region. Both deep and shallow chambers were periodically replenished by mafic magmas. We argue that a slab breakoff model explains better than any alternative model (i) why the volcanism during the Middle Eocene was confined into a rather narrow belt along the suture zone, (ii) why it initiated almost contemporaneous with a regional uplift after the continental collision event, (iii) why it postdated arc volcanism along the Pontides in the north by 15–20 My, (iv) why it assimilated significant amount of crustal material, and (v) why alkalinity of lavas increased in time.     

Investigation of the Possibility of Copper Removal from Industrial Leachate by Raw and Calcined Phosphogypsum: D‐Optimal and Taguchi Designs

In the present study, the removal of Cu(II) was evaluated by raw and calcined phosphogypsum (PG) as an industrial product. The role of experimental factors on the removal of Cu(II) was examined by using D‐optimal and Taguchi designs. The experimental factors and their related levels were selected as initial pH of 3–6–8, adsorbent content of 5, 10, and 25 g L^?1, contact time of 5, 10, and 20 min, and temperature of 20, 40, and 60°C. The results are evaluated by ANOVA test to extract important experimental factors and their levels. The performances of the suggested factorial designs were then compared and regression models that took into account the significant main and interaction effects were suggested. Taguchi design was found as a reliable solution with less number of experiments for adsorption studies with the optimized values. The resultant removal efficiency is calculated as 78.34%. The results revealed that calcined PG is an appropriate adsorbent for Cu(II) removal from leachate of industrial waste.     

Hydrogeochemical and isotopic investigation of the Kolan geothermal field, southeastern Turkey

The Kolan geothermal field is located 24 km northwest of the Karakoçan area of Elaz city in southeastern Turkey. The Keban crystallized limestone of Permo-Carboniferous age is the oldest unit in the area. This unit is overlain by the middle-upper Eocene Krkgeçit formation consisting of conglomerate, sandstone, limestone and marl alternations. The youngest unit in the area is the Upper Miocene-Lower Pliocene Karabakr formation consisting of basalt, andesite and tuffs. Thermal Springs in the Kolan field issue along two major fault zones. The temperature of the hot springs is between 38°C and 45°C. Thermal waters in the area are heated by the geothermal gradient. The waters are classified as hot or very hot and as brackish waters. On the basis of International Association of Hydrogeologists Classification (IAH), waters are grouped as Ca–Na-HCO₃–CO₂-bearing thermal and mineral waters. Chemical analyses indicate a chemical composition of Ca>(Na+K)>Mg - HCO₃>SO₄>Cl. Saturation calculations reveal that the waters are oversaturated with respect to calcite, dolomite and aragonite while undersaturated with respect to gypsum, anhydrite and halite minerals. On the basis of ¹⁸O, ²H and ³H isotope data, Kolan waters are of meteoric origin, recharged from high elevations and then circulated deeply.     

Absolute and geometric parameters of W UMa type contact binary TYC 1174-344-1

We present the results of our investigation on the geometrical and physical parameters of W UMa-type binary TYC1174-344-1 from analyzed CCD (BVRI) light curves and radial velocity data. The photometric data were obtained in 2009 at Ankara University Observatory (AUO) and the spectroscopic observations were made in 2008 at Astrophysical Observatory of Asiago (Italy). Light and radial velocity observations were analyzed simultaneously by using the well-known Wilson–Devinney (2007 revision) code to obtain absolute and geometrical parameters. According to our solutions, the system is found to be a low mass-ratio A-type W UMa system. Combining our photometric solution with the spectroscopic data, we derived mass and radii of the eclipsing system as M₁ = 1.381 M_⊙, M₂ = 0.258 M_⊙, R₁ = 1.449 R_⊙ and R₂ = 0.714 R_⊙. We finally discussed the evolutionary condition of the system.