A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

Possible creep-related tilt precursors obtained in the Central Apennines (Italy) and in the Southern Caucasus (Georgia)

Daily averaged tilt component data from two sites of the Central Apennines (Italy) and of the Southern Caucasus (Georgia), respectively, revealed intermediate-term tilts as possible precursors to earthquakes (M=3.0÷4.7) which occurred in the above-mentioned seismic areas within a distance of 50 km from the sites. A good temporal correlation as well as a fair spatial correspondence between these residual tilts (with amplitude and duration of some microradians and months, respectively) and main shocks were pointed out, by removing both secular trends and seasonal thermoelastic effects from the raw tilts. An attempt was made to justify the above-mentioned results, based on the assumption that the observed intermediate-term preseismic tilts are the manifestation of aseismic creep episodes of comparable duration in the fault materials of thrust faults close to the tilt sites. The mechanism refers to a strain field slowly propagating from the preparation focal area to the tilt site, through crustal blocks separated by weak transition zones. This propagation is thought to be the cause of the local aseismic fault slip recorded by the tiltmeters. Previously, both discrete structures and strain propagation effects were revealed in the Central Apennines and are thought also to exist in the Southern Caucasus. As in the past, the rheological properties of fault materials are revealed as viscoelastic ones. In fact, creep equations obtained by applying several viscoelastic models on our data, proved to fit quite well some of the observed tilt precursors, producing viscosity and rigidity values very similar to those reported in literature.Professor Petr Viktorovich Manjgaladze died during the writing of this paper     

Hydrodynamic and dynamic analysis to determine the directional stability of an underwater vehicle near a free surface

A theoretical methodology to determine the open-loop directional stability of a near-surface underwater vehicle is presented. It involves a solution of coupled sway and yaw equations of motion in a manner similar to that carried out for surface ships. The stability derivatives are obtained numerically through simulation of motions corresponding to planar motion mechanism (PMM) model tests. For the numerical simulation, a boundary-integral method based on the mixed Lagrangian-Eulerian formulation is developed. The free-surface effect on the vehicle stability is determined by comparing the results with that obtained for vehicle motion in infinite fluid. The methodology was used to determine the stability of the Florida Atlantic University’s Ocean EXplorer (OEX) AUV. The presence of the free surface, through radiation damping, is found to suppress unsteady oscillations and thereby enhance the directional stability of the vehicle. With effects of free surface, forward speed, location and geometry of rudders, location of the center of gravity etc. all being significant factors affecting stability, a general conclusion cannot be drawn on their combined effect on the vehicle stability. The present computational methodology is therefore a useful tool to determine an underwater vehicle’s stability for a given configuration and thus the viability of an intended mission a priori.     

Correcting systematic effects in a large set of photometric light curves

We suggest a new algorithm to remove systematic effects in a large set of light curves obtained by a photometric survey. The algorithm can remove systematic effects, such as those associated with atmospheric extinction, detector efficiency, or point spread function changes over the detector. The algorithm works without any prior knowledge of the effects, as long as they linearly appear in many stars of the sample. The approach, which was originally developed to remove atmospheric extinction effects, is based on a lower rank approximation of matrices, an approach which has already been suggested and used in chemometrics, for example. The proposed algorithm is especially useful in cases where the uncertainties of the measurements are unequal. For equal uncertainties, the algorithm reduces to the Principal Component Analysis (PCA) algorithm. We present a simulation to demonstrate the effectiveness of the proposed algorithm and we point out its potential, in the search for transit candidates in particular.     

Preliminary Results from the Magnetic Field Measurements Using MAGDAS at Ilorin, Nigeria

MAGDAS, the Magnetic Data Acquisition System, was successfully installed at the University of Ilorin, Nigeria—an equatorial station—in August 2006. MAGDAS is an important component of the International Heliophysical Year, IHY. We examined the preliminary results obtained from the analysis of the geomagnetic data obtained from the MAGDAS measurement. Diurnal variations of the solar quiet daily variation in the three geomagnetic elements, H, D, Z were studied. The obtained signatures of the magnetic field variations were discussed in the context of the literature. The day-to-day variability of the horizontal and vertical intensities as well as the declination of the geomagnetic field were examined. The study justified the need for a partner magnetic field observatory along same meridian as Ilorin, north or south of it, to facilitate synthesis of the equatorial electrojet effect.     

Distribution of Ixodes ricinus L., 1758 and Ixodes persulcatus Shulze, 1930 (Parasitoformes,Ixodidae) in Russia and adjacent countries in view of observable climate changes

Possible changes in the area inhabited by the ticks Ixodes ricinus and Ixodes persulcatus, the main transmitters of tick-borne encephalitis and Lyme disease in Russia, caused by temperature changes in 1976–2005 compared to 1946–1975 are discussed. It is shown that these changes could result in some areal expansion of these species. In the European part of Russia, I. ricinus expanded its areal boundaries to the east 100–300 km. I. persulcatus expanded its areal in the Asian part of Russia. Its boundary moved to the north and northeast 100–300 km. Areal expansion both of species has not been observed.     

Photometric and spectroscopic investigation of the B2E Herbig star HD52721: First results

We present first results of the photometric and spectroscopic investigation of the B1/B2 Herbig star HD52721 performed in 2009–2010 at three observatories: Mountain Astronomical Station (Kislovodsk)—photometry, CrAO (Crimea, Ukraine)—spectroscopy, Observatory San Pedro Martyr (Ensenada, Mexico)—high-resolution echelle-spectroscopy. We have also used photometric data from the ASAS survey for 2003–2009. Our analysis has shown that a) the object is a close binary system with the orbital period of 1.610 days composed of two components of similar spectral type (B1–B2); b) the system is surrounded by the common disk-like envelope containing azimuthal inhomogeneity rotating with the orbital period of the system. We present preliminary estimates of the system parameters and discuss its possible nature.     

Pressure dependence of nickel partitioning between forsterite and aluminous silicate melts

Nickel partitioning between forsterite and aluminosilicate melt of fixed bulk composition has been determined at 1300°C to 20 kbar pressure. The value of the forsterite-liquid nickel partition coefficient is lowered from >20 at pressures equal to or less than 15 kbar to <10 at pressures above 15 kbar.Published data indicate that melts on the join Na₂O-Al₂O₃-SiO₂ become depolymerized in the pressure range 10–20 kbar as a result of Al shifting from four-coordination at low pressure to higher coordination as the pressure is increased. This coordination shift results in a decreasing number of bridging oxygens in the melt. It is suggested that the activity coefficient of nickel decreases with this decrease in the number of bridging oxygens. As a result, the nickel partition coefficient for olivine and liquid is lowered.Magma genesis in the upper mantle occurs in the pressure range where the suggested change in aluminum coordination occurs in silicate melts. It is suggested, therefore, that data on nickel partitioning obtained at low pressure are not applicable to calculation of the nickel distribution between crystals and melts during partial melting in the upper mantle. Application of high-pressure experimental data determined here for Al-rich melts to the partial melting process indicates that the melts would contain about twice as much nickel as indicated by the data for the low-pressure experiments. If, as suggested here, the polymerization with pressure is related to the Al content of the melt, the difference in the crystal-liquid partition coefficient for nickel at low and high pressure is reduced with decreasing Al content of the melt. Consequently, the change ofD_Ni^{ol-andesite melt} is greater than that ofD_Ni^{ol-basalt melt}, for example.     

Turbulent flow over a dune: Green River,Colorado

Detailed echo‐sounder and acoustic Doppler velocimeter measurements are used to assess the temporal and spatial structure of turbulent flow over a mobile dune in a wide, low‐gradient, alluvial reach of the Green River. Based on the geometric position of the sensor over the bedforms, measurements were taken in the wake, in transitional flow at the bedform crest, and in the internal boundary layer. Spatial distributions of Reynolds shear stress, turbulent kinetic energy, turbulence intensity, and correlation coefficient are qualitatively consistent with those over fixed, two‐dimensional bedforms in laboratory flows. Spectral and cospectral analysis demonstrates that energy levels in the lee of the crest (i.e. wake) are two to four times greater than over the crest itself, with minima over the stoss slope (within the developing internal boundary layer). The frequency structure in the wake is sharply defined with single, dominant peaks. Peak and total spectral and cross‐spectral energies vary over the bedform in a manner consistent with wave‐like perturbations that ‘break’ or ‘roll up’ into vortices that amalgamate, grow in size, and eventually diffuse as they are advected downstream. Fluid oscillations in the lee of the dune demonstrate Strouhal similarity between laboratory and field environments, and correspondence between the peak frequencies of these oscillations and the periodicity of surface boils was observed in the field. Copyright © 2005 John Wiley & Sons, Ltd.