Retrieval of stratospheric O3 and NO2 vertical profiles using zenith scattered light observations

Daily zenith scattered light intensity observations were carried out in the morning twilight hours using home-made UV-visible spectrometer over the tropical station Pune (18‡31′, 73‡51′) for the years 2000–2003. These observations are obtained in the spectral range 462–498 nm for the solar zenith angles (SZAs) varying from 87‡ to 91.5‡. An algorithm has been developed to retrieve vertical profiles of ozone (O₃) and nitrogen dioxide (NO₂) from ground-based measurements using the Chahine iteration method. This retrieval method has been checked using measured and recalculated slant column densities (SCDs) and they are found to be well matching. O₃ and NO₂ vertical profiles have been retrieved using a set of their air mass factors (AMFs) and SCDs measured over a range of 87–91.5‡ SZA during the morning. The vertical profiles obtained by this method are compared with Umkehr profiles and ozonesondes and they are found to be in good agreement. The bulk of the column density is found near layer 20–25 km. Daily total column densities (TCDs) of O₃ and NO₂ along with their stratospheric and tropospheric counterparts are derived using their vertical profiles for the period 2000–2003. The total column, stratospheric column and tropospheric column amounts of both trace gases are found to be maximum in summer and minimum in the winter season. Increasing trend is found in column density of NO₂ in stratospheric, tropospheric and surface layers, but no trend is observed in O₃ columns for above layers during the period 2000–2003     

Patterns in the Turkish reinsurance claim data, 1998–2002: An application of the extreme value theory

The devastating 1999 Marmara and Düzce earthquakes led to a significant increase in the earthquake studies in Turkey in geological, engineering and financial aspects. Extreme Value Theory (EVT) has a range of applications from stock market changes to natural disasters like floods and hurricanes. Here EVT is fitted to the ordinary and earthquake reinsurance claims of Turkey.     

Deterioration of the volcanic kerb and pavement stones in a humid environment in the city centre of Izmir, Turkey

?zmir is the third largest city in Turkey and has being the centre of art, culture, tourism and trade activities throughout the 5,000 years of its history. Natural stones brought from different parts of the world have been widely used for construction of the prestigious buildings, monuments and roads etc., in the past in the city. Renovation of the street pavements and public gathering areas in the city centre has been undertaken by the Metropolitan Municipality in 2000 and continued through the year of 2001. These renovation activities have mainly been carried out in the streets running parallel to the sea shore. Volcanic rocks brought from the Central Anatolia Ankara-Gölba?? (andesites) and Kayseri-?ncesu (tuffs) have been used in the renovation works. These rocks have shown extensive deteriorations within 4 years of their usage between 2001 and 2005 under the influence of different environmental factors. In this study, the deteriorations developed in the recently placed volcanic rocks used as kerb and pavement stones in the city centre of ?zmir in the light of their mineralogical, chemical, physical and mechanical properties, used locations and the environmental factors are presented.     

Integrated radio luminosities of pulsars

The integrated radio luminosities of 311 long-period (P > 0.1 s) and 27 short-period (P < 0.1 s) pulsars have been calculated using a new compilation of radio spectra. The luminosities are in the range 10²⁷ ? 10³⁰ erg/s for 88% of the long-period pulsars and 10²⁸ ? 10³¹ erg/s for 88% of the short-period pulsars. We find a high correlation between the luminosity L and the estimate L ₁ = S ₄₀₀ d ² from the catalog of Taylor et al. The factor η for the transformation of the rotational energy of the neutron star into radio emission increases-decreases with increasing period for long-period and short-period pulsars. The mean value of η is ?3.73 for the long-period and ?4.85 for short-period pulsars. No dependence was found between L and the pulsar’s kinematic age t _k = |z|/〈v _z〉, where |z| and 〈v _z〉 = 300 km/s are the pulsars’ height above the plane of the Galaxy and mean velocity. A dependence of L on the rate of rotational energy losses ? was found for both groups of pulsars. It is shown that L ∝ ? ^1/3 for the entire sample. The pulsar luminosity function is constructed, and the total number and birth rate of pulsars in the Galaxy are calculated.     

The influence of ultrahigh-energy cosmic rays on star formation in the early Universe

The presence of ultrahigh-energy (UHE) cosmic rays results in an increase in the degree of ionization in the post-recombination Universe, which stimulates the efficiency of the production of H₂ molecules and the formation of the first stellar objects. As a result, the onset of the formation of the first stars is shifted to higher redshifts, and the masses of the first stellar systems decrease. As a consequence, a sufficient increase in the ionizing radiation providing the reionization of the Universe can occur. We discuss the possible observational manifestations of these effects and their dependence on the parameters of UHE cosmic rays.     

Isotopic signatures of deposition and transformation of Lower Cambrian saliferous rocks in the Irkutsk amphitheater: Communication 1. Sulfur isotopic composition

New isotope data on Lower Cambrian rocks of the Irkutsk amphitheater are reported in three communications. The first communication is devoted to the sulfur isotopic composition, which is most sensitive to ostsedimentary geochemical transformations of sulfate rocks in saliferous formations. It is shown that δ³⁴S values in Bel’sk and Zhigalovo boreholes are within 22–35‰ The lowest values are close to the sulfur isotopic composition of a halogenic basin, while the highest values are related to epigenetic sulfate reduction. This process was responsible for the elimination of 100 m of anhydrites from the Lower Cambrian section.     

Early Proterozoic syn-and postcollision granites in the northern part of the Baikal fold area

Early Proterozoic granitoids are of a limited occurrence in the Baikal fold area being confined here exclusively to an arcuate belt delineating the outer contour of Baikalides, where rocks of the Early Precambrian basement are exposed. Geochronological and geochemical study of the Kevakta granite massif and Nichatka complex showed that their origin was related with different stages of geological evolution of the Baikal fold area that progressed in diverse geodynamic environments. The Nichatka complex of syncollision granites was emplaced 1908 ± 5 Ma ago, when the Aldan-Olekma microplate collided with the Nechera terrane. Granites of the Kevakta massif (1846 ± 8 Ma) belong to the South Siberian postcollision magmatic belt that developed since ～1.9 Ga during successive accretion of microplates, continental blocks and island arcs to the Siberian craton. In age and other characteristics, these granites sharply differ from granitoids of the Chuya complex they have been formerly attributed to. Accordingly, it is suggested to divide the former association of granitoids into the Chuya complex proper of diorite-granodiorite association ～2.02 Ga old (Neymark et al., 1998) with geochemical characteristics of island-arc granitoids and the Chuya-Kodar complex of postcollision S-type granitoids 1.85 Ga old. The Early Proterozoic evolution of the Baikal fold area and junction zone with Aldan shield lasted about 170 m.y. that is comparable with development periods of analogous structures in other regions of the world.