Trinitite—the atomic rock

On 16 July 1945, the first atomic bomb was detonated at the Alamogordo Bombing range in New Mexico, USA. Swept up into the nuclear cloud was the surrounding desert sand, which melted to form a green glassy material called ‘trinitite’. Contained within the glass are melted bits of the first atomic bomb and the support structures and various radionuclides formed during the detonation. The glass itself is marvelously complex at the tens to hundreds of micrometre scale, and besides glasses of varying composition also contains unmelted quartz grains. Air transport of the melted material led to the formation of spheres and dumbbell shaped glass particles. Similar glasses are formed during all ground level nuclear detonations and contain forensic information that can be used to identify the atomic device.     

Trace-element study and uranium-lead dating of perovskite from the Afrikanda plutonic complex, Kola Peninsula (Russia) using LA-ICP-MS

The U-Pb geochronology of perovskite is a powerful tool in constraining the emplacement age of silica-undersaturated rocks. The trace-element and U-Pb isotopic compositions of perovskite from clinopyroxenite and silicocarbonatite from the Afrikanda plutonic complex (Kola, Russia) were determined by laser-ablation inductively-coupled mass-spectrometry (LA-ICP-MS). In addition, the Sr isotopic composition of perovskite was measured by isotope-dilution mass-spectrometry to better constrain the relations between its host rocks. Perovskite from the two rock types shows a different degree of enrichment in Na, Mg, Mn, Pb, Fe, Al, V, rare-earth elements, Zr, Hf, Th, U and Ta. The perovskite ⁸⁷Sr/⁸⁶Sr values are within analytical uncertainty of one another and fall within the range of mantle values. The ²⁰⁶Pb/²³⁸U ages (corrected for common lead using ²⁰⁷Pb-method) of perovskite from silicocarbonatite statistically yield a single population with a weighted mean of 371?±?8 Ma (2σ; MSWD?=?0.071). This age is indistinguishable, within uncertainty, to the clinopyroxenite weighted mean ²⁰⁶Pb/²³⁸U age of 374?±?10 Ma (2σ; MSWD?=?0.18). Our data are in good agreement with the previous geochronological study of the Afrikanda complex. The observed variations in trace-element composition of perovskite from silicocarbonatite and clinopyroxenite indicate that these rocks are not related by crystal fractionation. The Sr isotopic ratios and the fact that the two rocks are coeval suggest that they were either produced from a single parental melt by liquid immiscibility, or from two separate magmas derived at different degrees of partial melting from an isotopically equilibrated, but modally complex mantle source.     

Water Flows Toward Power: Socioecological Degradation of Lake Urmia,Iran

Water is an invaluable resource, and equitable access to it is a fundamental human right. Disenfranchised groups often lose access to water resources because their interests are not well represented by decision makers. Excluding these groups from resource management policy often results in myopic decisions that contribute to further ecosystem damage. We describe the ecological degradation of Lake Urmia in Iran, which has recently experienced increased salinity and declining water quantity. The lake is a UNESCO Biosphere Reserve and Ramsar site, and supports unique biodiversity in the region. The lake's decline is driven by the destruction of Zagros forests and the government's water policies, which diverted water to more politically connected agricultural land users, increasing social inequity and prompting more deforestation. The most straightforward restoration solution is to discontinue the diversions and allow critical inflows to recharge Lake Urmia, preserving the lake and wetlands for migratory birds, tourists, and local communities.     

Evaluation of High-Frequency Mean Streamwater Transit-Time Estimates Using Groundwater Age and Dissolved Silica Concentrations in a Small Forested Watershed

Many previous investigations of mean streamwater transit times (MTT) have been limited by an inability to quantify the MTT dynamics. Here, we draw on (1) a linear relation (r ² = 0.97) between groundwater ³H/³He ages and dissolved silica (Si) concentrations, combined with (2) predicted streamwater Si concentrations from a multiple-regression relation (R ² = 0.87) to estimate MTT at 5-min intervals for a 23-year time series of streamflow [water year (WY) 1986 through 2008] at the Panola Mountain Research Watershed, Georgia. The time-based average MTT derived from the 5-min data was ~8.4 ± 2.9 years and the volume-weighted (VW) MTT was ~4.7 years for the study period, reflecting the importance of younger runoff water during high flow. The 5-min MTTs are normally distributed and ranged from 0 to 15 years. Monthly VW MTTs averaged 7.0 ± 3.3 years and ranged from 4 to 6 years during winter and 8–10 years during summer. The annual VW MTTs averaged 5.6 ± 2.0 years and ranged from ~5 years during wet years (2003 and 2005) to >10 years during dry years (2002 and 2008). Stormflows are composed of much younger water than baseflows, and although stormflow only occurs ~17 % of the time, this runoff fraction contributed 39 % of the runoff during the 23-year study period. Combining the 23-year VW MTT (including stormflow) with the annual average baseflow for the period (~212 mm) indicates that active groundwater storage is ~1,000 mm. However, the groundwater storage ranged from 1,040 to 1,950 mm using WY baseflow and WY VW MTT. The approach described herein may be applicable to other watersheds underlain by granitoid bedrock, where weathering is the dominant control on Si concentrations in soils, groundwater, and streamwater.     

Significance of ancient sulfide PGE and Re–Os signatures in the mantle beneath Calatrava,Central Spain

Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO₂ by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and ¹⁸⁷Os/¹⁸⁸Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and ¹⁸⁷Os/¹⁸⁸Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle.     

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.     

Strategy for Applying Neutrino Geophysics to the Earth Sciences Including Planetary Habitability

Antineutrino data constrain the concentrations of the heat producing elements U and Th as well as potentially the concentration of K. Interpretation is similar to but not homologous with gravity. Current geoneutrino physics efficiently asks simple questions taking advantage of what is already known about the Earth. A few measurements with some sites in the ocean basins will constrain the concentration of U and Th in the crust and mantle and whether the mantle is laterally heterogeneous. These results will allow Earth science arguments about the formation, chemistry, and dynamics of the Earth to be turned around and appraised. In particular, they will tell whether the Earth accreted its expected share of these elements from the solar nebula and how long radioactive heat will sustain active geological processes on the Earth. Both aspects are essential to evaluating the Earth as a common or rare habitable planet.     

Characterization of the Sukinda and Nausahi ultramafic complexes,Orissa, India by platinum-group element geochemistry

Samples of 20 chromitite, 14 ultramafic and mafic rock, and 9 laterite and soil samples from the Precambrian Sukinda and Nausahi ultramafic complexes, Orissa, India were analyzed for platinum-group elements (PGE). The maximum concentrations are: palladium, 13 parts per billion (ppb); platinum, 120 ppb; rhodium, 21 ppb; iridium, 210 ppb; and ruthenium, 630 ppb. Comparison of chondrite-normalized ratios of PGE for the chromitite samples of lower Proterozoic to Archean age with similar data from Paleozoic and Mesozoic ophiolite complexes strongly implies that these complexes represent Precambrian analogs of ophiolite complexes. This finding is consistent with the geology and petrology of the Indian complexes and suggests that plate-tectonic and ocean basin developement models probably apply to some parts of Precambrian shield areas.     

Pressure effects on martian crustal magnetization near large impact basins

Abstract— Martian crust endured several large meteoroid impacts subsequent to the demise of an early global magnetic field. Shock pressures associated with these impacts demagnetized parts of the crust, to an extent determined by shock resistance of magnetic materials in the crust. Impacts that form large basins generate pressures in excess of 1 GPa within a few crater radii of their impact sites. Crustal materials near the surface experience significantly reduced impact pressure, which varies with depth and distance from the impact point. We present new demagnetization experiments on magnetite (Fe₃O₄), hematite (α‐Fe₂O₃), and titanohematite (Fe_2‐xTi_xO₃ where x <0.2). Our measurements show that pressures of ?1 GPa are sufficient to partially demagnetize all of these minerals. The efficiency of demagnetization by impact pressure is proportional to the logarithm of the minerals' magnetic coercivity. The impact pressure magnetic response from exsolved titanohematite samples is consistent with the magnetization decay near Prometheus impact basin and may point to an oxidized igneous rock in Terra Sirenum region at the time of acquisition of magnetic remanence. The remaining magnetic anomalies near large impact basins suggest moderate crustal coercivity. These anomalies point to titanomagnetite as a magnetic carrier and more reduced condition during crustal formation.