Sulfides in mantle peridotites from Penghu Islands, Taiwan: Melt percolation, PGE fractionation, and the lithospheric evolution of the South China block

Major elements, highly siderophile elements (HSE) and Re-Os isotope ratios were analysed in situ on individual sulfide grains in spinel peridotite xenoliths hosted by Miocene intraplate basalts from the Penghu Islands, Taiwan. The xenoliths represent texturally and compositionally different mantle domains, and the geochemical characteristics of the sulfides show changes in HSE distribution and Re-Os isotope systematics, produced as their host rocks were metasomatised by percolating fluids/melts. In prophyroclastic and partly metasomatised peridotites from the Kueipi (KP) locality, the sulfides have subchondritic to superchondritic ¹⁸⁷Re/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios. Many of these sulfides reflect fluid/melt interaction with residual MSS and/or crystallization of fractionated sulfide melts, which produced high contents of Cu and PPGEs and high Re/Os; inferred melt/rock ratios are low. In contrast, sulfides in equigranular and extensively metasomatised peridotites from the Tungchiyu (TCY) locality are mainly more sulfur-rich Ni-(Co)-rich MSS, with subchondritic to chondritic ¹⁸⁷Os/¹⁸⁸Os and subchondritic ¹⁸⁷Re/¹⁸⁸Os. These sulfides are interpreted as products of interaction between pre-existing MSS and percolating silicate melts. Melt/rock ratios were high and the percolating melt was less differentiated than the melt that percolated the KP peridotites. Sulfides in a TCY pyroxenite are mainly MSS; they have the lowest HSE contents, subchondritic to superchondritic ¹⁸⁷Os/¹⁸⁸Os and subchondritic ¹⁸⁷Re/¹⁸⁸Os, and may have precipitated from sulfide melts that segregated from basaltic melts under S-saturated conditions. In most sulfides melt percolation appears to have induced fractionation among the HSEs and disturbed Re-Os isotope compositions. Despite the metasomatic effects, rare residual MSS, sulfides that from crystallised sulfide melts and sulfides modified by addition of Re (with no evidence for Os addition) can still provide useful chronological information. Such sulfides yield T_RD age peaks of 1.9, 1.7-1.6, 1.4-1.3 and 0.9-0.8 Ga, which may record the timing of melt extraction and/or metasomatic events in the mantle. These periods are contemporaneous with the major crustal events recorded by U-Pb dates and Nd and Hf model ages in the overlying crust. This close correspondence indicates that the sulfide T_RD ages reflect the timing of lithosphere-scale tectonothermal events (such as melting and metasomatism) that affected both the lithospheric mantle and the overlying crust. The sulfide T_RD ages, taken together with the crustal data, suggest that most of the Cathaysia block had formed at least by Paleo-Proterozoic time, and that some domains are Archean in age.     

Thallium isotopes as a potential tracer for the origin of cratonic eclogites

Cratonic eclogites are inferred to originate either from subducted ocean crust or mantle melts accreted onto the roots of continents. These models have different implications for the growth of continents, but it is currently difficult to determine the origin of individual eclogite suites.Upper ocean crust altered at low temperatures and marine sediments both display high thallium (Tl) concentrations and strongly fractionated Tl isotope signatures relative to the ambient upper mantle. In this study we carry out the first examination of the suitability of Tl isotopes as a tracer for an ocean-crust origin of cratonic eclogites. We have analysed the Tl isotope composition of clinopyroxene and garnet in six eclogites from the Kaalvallei and Bellsbank kimberlite pipes in South Africa. Minerals were pre-cleaned with an HCl leaching technique and the leachates display variably light Tl isotope ratios. These most likely reflect low-temperature hydrothermal alteration occurring after eruption of the kimberlite that carried the eclogites to the surface.The leached mineral pairs all display identical Tl isotope ratios, strongly suggesting that the source of the analysed Tl is identical for each mineral pair. It is, however, not possible to exclude the possibility that the analysed Tl originates from kimberlitic material that was not removed by the cleaning procedure.Only one of the six samples exhibits a Tl isotope composition different from ambient mantle. Assuming that the Tl isotope signatures indeed represent the eclogite minerals and not any form of contamination, the Tl isotope composition in this sample is consistent with containing a minor component (<3%) of ocean crust altered at low temperatures.Thallium isotopes may become one of the most sensitive indicators for the presence of low-T altered ocean crust because of the stark contrast in Tl concentration and isotopic composition between the mantle and altered ocean crust. In fact, no other chemical or isotopic tracer could have provided an indication that any of the samples studied here had a subduction origin. However, much work is still required before it becomes clear if Tl isotope measurements are a viable means to establish the origin of cratonic eclogites.     

Neutralino annihilations and the gas temperature in the dark ages

Assuming that the dark matter is entirely made up of neutralinos, we re-visit the role of their annihilation on the temperature of diffuse gas in the high-redshift universe  ( z > 10)  , before the formation of luminous structures. We consider neutralinos of particle mass 36 and 100 GeV. The former is able to produce  ∼7  e ⁻ e ⁺  particles per annihilation through the fremionic channel, and the latter ∼53 particles assuming a purely bosonic channel. High-energy   e ⁻ e ⁺  particles up-scatter the cosmic microwave background (CMB) photons into higher energies via the inverse-Compton scattering. The process produces a power-law   e ⁻ e ⁺  energy spectrum of index −1 in the energy range of interest, independent of the initial energy distribution. The corresponding energy spectrum of the up-scattered photons is a power law of index −1/2, if absorption by the gas is not included. The scattered photons photoheat the gas by releasing electrons which deposit a fraction (14 per cent) of their energy as heat into the ambient medium. For uniformly distributed neutralinos, the heating is insignificant. The effect is greatly enhanced by the clumping of neutralinos into dense haloes. We use a time-dependent clumping model which takes into account the damping of density fluctuations on mass-scales smaller than  ∼10⁻⁶ M_⊙  . With this clumping model, the heating mechanism boosts the gas temperature above that of the CMB after a redshift of   z ∼ 30  . By   z ≈ 10  , the gas temperature is nearly 100 times its temperature when no heating is invoked. Similar increase is obtained for the two neutralino masses considered.     

Low‐accommodation and backwater effects on sequence stratigraphic surfaces and depositional architecture of fluvio‐deltaic settings (Cretaceous Mesa Rica Sandstone,Dakota Group,USA)

The adequate documentation and interpretation of regional‐scale stratigraphic surfaces is paramount to establish correlations between continental and shallow marine strata. However, this is often challenged by the amalgamated nature of low‐accommodation settings and control of backwater hydraulics on fluvio‐deltaic stratigraphy. Exhumed examples of full‐transect depositional profiles across river‐to‐delta systems are key to improve our understanding about interacting controlling factors and resultant stratigraphy. This study utilizes the ~400 km transect of the Cenomanian Mesa Rica Sandstone (Dakota Group, USA), which allows mapping of down‐dip changes in facies, thickness distribution, fluvial architecture and spatial extent of stratigraphic surfaces. The two sandstone units of the Mesa Rica Sandstone represent contemporaneous fluvio‐deltaic deposition in the Tucumcari sub‐basin (Western Interior Basin) during two regressive phases. Multivalley deposits pass down‐dip into single‐story channel sandstones and eventually into contemporaneous distributary channels and delta‐front strata. Down‐dip changes reflect accommodation decrease towards the paleoshoreline at the Tucumcari basin rim, and subsequent expansion into the basin. Additionally, multi‐storey channel deposits bound by erosional composite scours incise into underlying deltaic deposits. These represent incised‐valley fill deposits, based on their regional occurrence, estimated channel tops below the surrounding topographic surface and coeval downstepping delta‐front geometries. This opposes criteria offered to differentiate incised valleys from flood‐induced backwater scours. As the incised valleys evidence relative sea‐level fall and flood‐induced backwater scours do not, the interpretation of incised valleys impacts sequence stratigraphic interpretations. The erosional composite surface below fluvial strata in the continental realm represents a sequence boundary/regional composite scour (RCS). The RCS’ diachronous nature demonstrates that its down‐dip equivalent disperses into several surfaces in the marine part of the depositional system, which challenges the idea of a single, correlatable surface. Formation of a regional composite scour in the fluvial realm throughout a relative sea‐level cycle highlights that erosion and deposition occur virtually contemporaneously at any point along the depositional profile. This contradicts stratigraphic models that interpret low‐accommodation settings to dominantly promote bypass, especially during forced regressions. Source‐to‐sink analyses should account for this in order to adequately resolve timing and volume of sediment storage in the system throughout a complete relative sea‐level cycle.     

Edge-to-Stem Variability in Wet-Canopy Evaporation From an Urban Tree Row

Evaporation from wet-canopy (\(E_\mathrm{C}\)) and stem (\(E_\mathrm{S}\)) surfaces during rainfall represents a significant portion of municipal-to-global scale hydrologic cycles. For urban ecosystems, \(E_\mathrm{C}\) and \(E_\mathrm{S}\) dynamics play valuable roles in stormwater management. Despite this, canopy-interception loss studies typically ignore crown-scale variability in \(E_\mathrm{C}\) and assume (with few indirect data) that \(E_\mathrm{S}\) is generally \({<}2\%\) of total wet-canopy evaporation. We test these common assumptions for the first time with a spatially-distributed network of in-canopy meteorological monitoring and 45 surface temperature sensors in an urban Pinus elliottii tree row to estimate \(E_\mathrm{C}\) and \(E_\mathrm{S}\) under the assumption that crown surfaces behave as “wet bulbs”. From December 2015 through July 2016, 33 saturated crown periods (195 h of 5-min observations) were isolated from storms for determination of 5-min evaporation rates ranging from negligible to 0.67 \(\hbox {mm h}^{-1}\). Mean \(E_\mathrm{S}\) (0.10 \(\hbox {mm h}^{-1}\)) was significantly lower (\(p < 0.01\)) than mean \(E_\mathrm{C}\) (0.16 \(\hbox {mm h}^{-1}\)). But, \(E_\mathrm{S}\) values often equalled \(E_\mathrm{C}\) and, when scaled to trunk area using terrestrial lidar, accounted for 8–13% (inter-quartile range) of total wet-crown evaporation (\(E_\mathrm{S}+E_\mathrm{C}\) scaled to surface area). \(E_\mathrm{S}\) contributions to total wet-crown evaporation maximized at 33%, showing a general underestimate (by 2–17 times) of this quantity in the literature. Moreover, results suggest wet-crown evaporation from urban tree rows can be adequately estimated by simply assuming saturated tree surfaces behave as wet bulbs, avoiding problematic assumptions associated with other physically-based methods.     

Coastal sea level variability in the US West Coast Ocean Forecast System (WCOFS)

Sea level variability along the US West Coast is analyzed using multi-year time series records from tide gauges and a high-resolution regional ocean model, the base of the West Coast Ocean Forecast System (WCOFS). One of the metrics utilized is the frequency of occurrences when model prediction is within 0.15 m from the observed sea level, F. A target level of F?=?90% is set by an operational agency. A combination of the tidal sea level from a shallow water inverse model, inverted barometer (IB) term computed using surface air pressure from a mesoscale atmospheric model, and low-pass filtered sea level from WCOFS representing the effect of coastal ocean dynamics (DYN) provides the most straightforward approach to reaching levels F>80%. The IB and DYN components each add between 5 and 15% to F. Given the importance of the DYN term bringing F closer to the operational requirement and its role as an indicator of the coastal ocean processes on scales from days to interannual, additional verification of the WCOFS subtidal sea level is provided in terms of the model-data correlation, standard deviation of the band-pass filtered (2–60 days) time series, the annual cycle amplitude, and alongshore sea level coherence in the range of 5–120-day periods. Model-data correlation in sea level increases from south to north along the US coast. The rms amplitude of model sea level variability in the 2–60-day band and its annual amplitude are weaker than observed north of 42 N, in the Pacific Northwest (PNW) coast region. The alongshore coherence amplitude and phase patterns are similar in the model and observations. Availability of the multi-year model solution allows computation and analysis of spatial maps of the coherence amplitude. For a reference location in the Southern California Bight, relatively short-period sea level motions (near 10 days) are incoherent with those north of the Santa Barbara Channel (in part, due to coastal trapped wave scattering and/or dissipation). At a range of periods around 60 days, the coastal sea level in Southern California is coherent with the sea surface height (SSH) variability over the shelf break in Oregon, Washington, and British Columbia, more than with the coastal SSH at the same latitudes.     

First encounter with a live male blanket octopus: The world's most sexually size‐dimorphic large animal

The first encounter with a live male blanket octopus, Tremoctopus violaceus Chiaie, 1830, illustrates the most extreme example of sexual size‐dimorphism in a non‐microscopic animal. Females attain sizes of up to 2 m long—almost 2 orders of magnitude larger than the 2.4‐cm‐long male. Weight ratios between the sexes are at least 10 000:1 and are likely to reach 40 000:1. Sexual selection and the unique defensive strategy of carrying cnidarian stinging tentacles may both have contributed to the evolution of this extreme size‐dimorphism. Such dimorphism is not seen in any other animal remotely as large.     

Seismic demand models for probabilistic risk analysis of near fault vertical ground motion effects on ordinary highway bridges

The influence of vertical ground motions on the seismic response of highway bridges is not very well understood. Recent studies suggest that vertical ground motions can substantially increase force and moment demands on bridge columns and girders and cannot be overlooked in seismic design of bridge structures. For an evaluation of vertical ground motion effects on the response of single‐bent two‐span highway bridges, a systematic study combining the critical engineering demand parameters (EDPs) and ground motion intensity measures (IMs) is required. Results of a parametric study examining a range of highway bridge configurations subjected to selected sets of horizontal and vertical ground motions are used to determine the structural parameters that are significantly amplified by the vertical excitations. The amplification in these parameters is modeled using simple equations that are functions of horizontal and vertical spectral accelerations at the corresponding horizontal and vertical fundamental periods of the bridge. This paper describes the derivation of seismic demand models developed for typical highway overcrossings by incorporating critical EDPs and combined effects of horizontal and vertical ground motion IMs depending on the type of the parameter and the period of the structure. These models may be used individually as risk‐based design tools to determine the probability of exceeding the critical levels of EDP for pre‐determined levels of ground shaking or may be included explicitly in probabilistic seismic risk assessments. Copyright © 2011 John Wiley & Sons, Ltd.