Quantitative measures of textural anisotropy resulting from magmatic compaction illustrated by a sample from the Palisades sill, New Jersey

Early in the crystallization of many tholeiitic basaltic magmas, plagioclase crystals cluster together into a 3-D cellular network, which forms a passive marker capable of recording the deformation that accompanies compaction of crystal mush. Although irregular in detail, the overall network is initially isotropic and only becomes anisotropic as a result of compaction. We have developed four independent methods to quantify the 3-D textural anisotropy of a basalt sample using at least three non-parallel thin sections. Three of the methods are based on the geometrical properties of digitized maps of the feldspar chain networks. One approach focuses on the angular variation of the mean intercept along parallel traverses through the network, another examines the orientation and size distribution of individual links, and the third considers the average shape of interstitial regions outlined by the plagioclase network. The fourth technique approximates the textural anisotropy by the variogram anisotropy of a scanned thin section image. We illustrate the methods using five oriented non-parallel thin sections from a sample of diabase 146 m above the base of the 300-m-thick Palisades sill of New Jersey. Compaction of crystal mush in this sill has previously been postulated on the basis of chemical evidence. The 3-D feldspar network anisotropy based on the first three approaches suggests nearly uniaxial compaction on the order of 8.6% in a direction within 3° of the intersection of the columnar joints at the sample site. A rigorous statistical test based on the statistics of elliptically contoured non-normal multivariate distributions documents that the link-vector distribution in vertical sections are statistically anisotropic at a 95% confidence level and that the overall compaction is 7.9±2.6%. The orientation and magnitude of the 3-D textural anisotropy determined by the image variogram of the non-opaque minerals is almost identical to the mean feldspar network anisotropy; 8.5% compaction in a direction 10° from the columnar joint intersections. The major silicate textural and feldspar network anisotropy axes both plunge almost directly down dip of the sill. On the other hand, the major axis of the variogram anisotropy of the opaque minerals is approximately parallel to the strike of the sill and to the major axis of the anisotropic magnetic susceptibility. The anisotropy of the silicate mineral fabric may reflect down-dip flow of a deformable melt-rich crystal mush, whereas the AMS and opaque textural anisotropy reflects the influence of gravitational stresses during the growth of magnetite in the final stages of melt crystallization. Evidently the Palisades sill was not originally horizontal but was intruded in an orientation close to its present attitude.     

Empirical attenuation relationship for Arias Intensity

Arias Intensity is a ground motion parameter that captures the potential destructiveness of an earthquake as the integral of the square of the acceleration–time history. It correlates well with several commonly used demand measures of structural performance, liquefaction, and seismic slope stability. A new empirical relationship is developed to estimate Arias Intensity as a function of magnitude, distance, fault mechanism, and site category based on 1208 recorded ground motion data from 75 earthquakes in active plate‐margins. Its functional form is derived from the point‐source model, and the coefficients are determined through non‐linear regression analyses using a random‐effects model. The results show that for large magnitude earthquakes (M > 7) Arias Intensity was significantly overestimated by previous relationships while it was underestimated for smaller magnitude events (M ? 6). The average horizontal Arias Intensity is not significantly affected by forward rupture directivity in the near‐fault region. The aleatory variability associated with Arias Intensity is larger than that of most other ground motion parameters such as spectral acceleration. However, it may be useful in assessing the potential seismic performance of stiff engineering systems whose response is dominated by the short‐period characteristics of ground motions. Copyright © 2003 John Wiley & Sons, Ltd.     

Trace-metal content of the Pueblo Viejo precious-metal deposits and their relation to other high-sulfidation epithermal systems

We provide here information on the distribution of copper, zinc, lead, gold, silver, barium, arsenic, antimony, mercury, selenium and tellurium in the Moore and Monte Negro high-sulfidation epithermal deposits in the Pueblo Viejo district, Dominican Republic. Moore and Monte Negro are funnel-shaped zones of advanced argillic alteration and precious-metal mineralization which extend to depths of about 350 m below the present surface. The uppermost part of the Moore deposit has been removed by erosion, whereas the Monte Negro deposit is covered by rocks containing low, but still anomalous gold grades. At Moore, concentrations of all elements except copper increase upward through the deposit. At Monte Negro, all elements except barium and zinc show a similar upward increase in concentration to a point near the top of the deposit from which they decrease upward. This difference reflects the fact that the top of the Moore deposit has been removed by erosion. Because the deposits are funnel-shaped and average metal concentrations increase by almost an order of magnitude upward, most of the metals are concentrated in the upper parts of the deposits. The upward increase in concentration of most metals is gradual and similar in magnitude to the prograde temperature dependence in solubilities of many metal complexes, suggesting that the metals were deposited by cooling. By contrast, concentrations of mercury and, to a lesser extent, tellurium increase more abruptly in the upper part of the deposits. This change probably reflects boiling of the hydrothermal solutions and partitioning of mercury and tellurium into a rising vapor phase, and it suggests that host rocks overlying the deposits will be anomalous in mercury and tellurium. Comparison to the Broadlands, New Zealand, hydrothermal system supports these inferred depositional processes. It shows that the behavior of arsenic and antimony at Broadlands was different from that at Pueblo Viejo, possibly because the elements were complexed differently in the two ore fluids. Comparison of trace-element abundances at Pueblo Viejo to other high-sulfidation epithermal systems shows differences in base-metal, arsenic and mercury abundances which may be related to the depths at which the deposits formed. The results of this study highlight the application and need for quantitative trace-element data from epithermal deposits.     

Hazards Risk Assessment Methodology for Emergency Managers: A Standardized Framework for Application

The public and the decision and policy makers who serve themtoo often have a view of community risks that is influenced and distorted significantlyby media exposure and common misconceptions. The regulators and managers, responsible forplanning and coordination of a community's mitigation, preparedness, response and recoveryefforts, are originated from a variety of disciplines and levels of education. Not only mustthese individuals deal with the misconceptions of their communities, but also frequently lacka basic methodology for the assessment of risks. The effective planning of mitigation andresponse are, however, directly dependent upon the understanding of the complexities, types,and nature of risks faced by the community, determining the susceptible areas, and conceptualizinghuman vulnerability.In this study, a review of the existing literature on both theconceptual underpinnings of risk and its assessment is attempted. A standardized framework is proposedfor use by all emergency managers, regardless of training or education. This frameworkconsists of the numerical ranking of the frequency of the event in the community, multiplied bya numerical ranking of the severity or magnitude of an event in a given community, based upon thepotential impact characteristics of a `worst-case' scenario. This figure is then multipliedby a numerical ranking indicating the Social Consequence; a combination of community perception ofrisk level and collective will to address the problem. The resulting score, which is notstrictly scientific, would permit emergency managers from a variety of backgrounds to comparelevels of community exposure to such disparate events as hazardous materials spills andtornadoes, and to set priorities for both mitigation efforts and for the acquisition of response needs,within the availability of community resources.     

Stable isotope evidence for multiple fluid regimes during carbonate cementation of the Upper Tertiary Hazeva Formation, Dead Sea Graben, southern Israel

Stable carbon- and oxygen-isotope compositions of calcite and dolomite cements have been used to understand porewater evolution in the Upper Tertiary Hazeva Formation within the Dead Sea Graben, southern Israel. Sandstone samples were obtained from four boreholes in three tectonic blocks of the graben over depths of 253–6448 m, a variation that largely reflects differential subsidence of individual fault-bounded blocks. Early carbonate cements dominate diagenesis. Calcite occurs at <1600 m, but was replaced by dolomite at greater depths. Dolomite at 1600–2700 m is Fe-poor (<0.8 mol% FeCO₃), and at 4700–6200 m, Fe-rich (0.5–7.2 mol% FeCO₃). Magnesite, anhydrite and halite are the final diagenetic phases. Calcite has positively correlated δ¹⁸O (+21‰ to +25‰) and δ¹³C (−6‰ to −2‰) values that generally decrease with depth. Dolomite has a wider variation in δ¹⁸O (+18‰ to +30‰) and δ¹³C (−8‰ to −1‰) values, which also generally are lower with increasing depth. However, the δ¹³C and δ¹⁸O values of dolomite from the uppermost 400 m of the Hazeva Formation in the Sedom Deep-1 borehole are anomalous in spanning the entire range of stable carbon and oxygen isotopic compositions over this relatively small interval.The decreasing dolomite δ¹³C values likely indicate an increased contribution of carbon from organic sources with increasing depth. Except for the uppermost 400 m, Hazeva Formation dolomite in the Sedom Deep-1 borehole has stable carbon-isotope compositions that imply initial dolomitization at much shallower levels, prior to the preferential subsidence of this tectonic block. The oxygen isotopic compositions of the calcite cement are best explained by equilibration at present burial temperatures (≤55 °C) with porewater of meteoric origin. Its δ¹⁸O values increased from −5‰ at the shallowest depths to 0‰ at 1600 m. The dolomite oxygen isotopic compositions also reflect equilibration at present burial temperatures with porewaters ranging from 0‰ at 1600 m to +7‰ at 3600 m (100 °C). In the deepest fault block (Sedom Deep-1 borehole), however, increasingly Fe-rich dolomite has (re)equilibrated with porewater whose δ¹⁸O values decreased from +9‰ at 4750 m (120 °C) to +1‰ to +2‰ by 6200 m (150 °C).Much of the dolomite likely formed at relatively shallow depths from saline brines derived from precursors to the Dead Sea. These infiltrated the Hazeva Formation, mixing with and largely displacing meteoric water, and dolomitizing calcite. Rock–water ratios tended to be high during these processes. However, the upper 400 m of the Hazeva Formation in the deepest fault block were likely deposited during its rapid tectonic subsidence, and largely escaped the initial style of dolomitization pervasive elsewhere in the study area. These sediments were also capped by evaporites. This relatively thin interval likely became a preferential conduit for brines that escaped underlying and overlying strata, including the Fe-rich, lower ¹⁸O fluids (evolved seawater?) present in the deepest part of the graben. These rocks present the most promising target for the passage and accumulation of hydrocarbons in the study area.     

Melting and metasomatism in the continental lithosphere: laser ablation ICPMS analysis of minerals in spinel lherzolites from eastern Australia

Olivine, low-Ca pyroxene, diopside, and spinel from a suite of protogranular lherzolite xenoliths from southeastern Australia have been analysed for their major and trace element compositions using electron microprobe and laser ablation ICPMS. Bulk compositions of the lherzolites range from fertile (12–13% modal diopside) to depleted (2–3% modal diopside), with equilibration temperatures of 850–900 °C indicating entrainment of these lherzolites from relatively shallow depths (probably ≤ 35 km) within the lithosphere. Mineral compositions and abundances indicate a primary control by partial melting, with decreasing abundance of modal diopside accompanied by increasing Mg# of olivine and pyroxene, decreasing Al and Ti contents of diopside, increasing Ni contents of olivine, and increasing Cr/Al of spinel. HREE, Y, and Ga in diopside also follow melting trends, decreasing in concentration with increasing Mg#. In contrast, highly incompatible elements such as LREE, Nb, and Th reveal divergent behaviour that cannot be ascribed entirely to partial melting. Diopsides from the fertile lherzolites have mantle-normalized patterns that are depleted in Th, Nb, and the LREE relative to Y and the HREE, whereas, diopsides from the cpx-poor samples are strongly enriched in Th, Nb and the LREE, and have elevated Sm/Hf and Zr/Hf, and low Ti/Nb. All diopsides have strongly negative Nb anomalies relative to Th and the LREE. Trace element patterns of diopside in the fertile lherzolites can be reproduced by ≤ 5% batch melting of a primitive source. The negative Nb anomalies are a consequence of this melting, and do not require special conditions or tectonic environments. The low concentrations of Y and HREE in diopside from the cpx-poor lherzolites cannot be produced by realistic degrees of batch melting, but can be accomplished by up to ∼20% fractional melting, suggesting multiple episodes of melt depletion. Os isotopic compositions of these lherzolites show that the melt depletion events occurred in the middle and late Proterozoic, demonstrating the long-term stability of lithospheric mantle beneath regions of eastern Australia. The LREE-enriched diopsides are well equilibrated and record metasomatic enrichment events that pre-date the magmatism that entrained these xenoliths. Trace element patterns of these pyroxenes suggest a carbonatitic melt as the metasomatic agent. Received: 24 September 1996 / Accepted: 12 August 1997     

Archaean quartz arenites in the Canadian Shield: examples from the Superior and Churchill Provinces

Units of remarkably pure Archaean quartz arenite occur in the northwestern part of the Superior Province and in the northern terrane of the Western Churchill Province (Rae Province) of the Canadian Shield. In the Superior Province, silica-cemented quartz arenites of Archaean age are well preserved in several greenstone belts. The example from the Keeyask Lake sedimentary assemblage displays tabular–planar and trough cross-beds, ripple marks, reactivation surfaces and pebble lag deposits. In spite of penetrative deformation and greenschist-grade metamorphism, primary textures are extremely well preserved, showing framework grains to be very well rounded and sorted. The succession of Keeyask Lake quartz-arenite beds is overlain by siltstones containing small-scale stratiform, domal and columnar stromatolites. A shallow-marine environment of deposition is inferred. Detrital heavy minerals include pyrite, magnetite, zircon, tourmaline, apatite, sphene and topaz. In the northern part of the Western Churchill Province (Rae Province), Archaean quartz arenites occur in northeasterly trending belts where intense structural deformation has in most places obscured or obliterated primary textures and structures. This has led to speculation that some of these units are metachert or recrystallized vein quartz, but local preservation of primary textures and structures provides clear evidence of epiclastic origin. In the example described herein, quartz arenites of the Woodburn Lake Group display sparse occurrences of trough and tabular–planar cross-beds, channels, ripple marks and pebble lag deposits. Probable environments of deposition for these quartz arenites include fluvial systems and shallow-marine shelf settings. The occurrence of unequivocal quartz-arenite clasts in beds of intercalated conglomerate provides direct evidence of at least two episodes of accumulation of almost pure quartz sand. Thin sections and polished slabs reveal frameworks of clastic quartz grains with little to no matrix (now mainly muscovite), and rare detrital grains of accessory heavy minerals, predominantly zircon and opaque iron oxides. Pyrite and other sulphides have been introduced along fractures, but some intergranular sulphide grains may be of detrital origin. The principal source for the quartz arenites in both areas must have been quartz-rich granitoid rocks. Conditions of intense chemical weathering are indicated. The widespread occurrence of extremely mature quartz arenites throughout Archaean terranes of the Canadian Shield, and in other shields of the world, are suggestive of crustal stability during early Earth history. The association of quartz arenites and ultramafic rocks, uncharacteristic of younger terranes, is now recognized in many Archaean greenstone belts of the Canadian Shield.     

Volume estimation of the 1998 flank collapse at Casita volcano,Nicaragua: a comparison of photogrammetric and conventional techniques

In October 1998 a precipitation‐triggered flank collapse occurred at Casita volcano, Nicaragua, leading to a devastating lahar. In this paper the failure volume was calculated using a range of methods. Several pre‐ and post‐failure digital elevation models (DEMs) were created, based on photogrammetric, cartometric and surveying data. The wide range in resulting volumes prompted an assessment of the accuracies and potential problems associated with each of the datasets and techniques used. The best estimate for the failure volume is 1·6 × 10⁶ m³. It is based on a vegetation‐corrected pre‐failure DEM, generated using automated digital photogrammetry, and a post‐failure surface based on a field survey carried out with a Total Station. The volume figure is approximately an order of magnitude higher than values reported in previous publications, all of which are based solely on field estimates. This demonstrates that values reported in the literature, if they are not based on rigorous quantitative analysis, must be regarded with caution. Copyright © 2002 John Wiley & Sons, Ltd.     

The abundance of volatiles in Hawaiian tholeiitic submarine basalts

High-temperature mass spectrometric studies have been made to determine the distribution of volatiles within glassy rims of submarine pillow basalts dredged from the east rift zone of Kilauea volcano, Hawaii. The CO₂/H₂O mole ratio for glass-vapor inclusions within olivine phenocrysts in the glassy rims is greater than 30 : 1 compared to 0.06 for matrix glasses. Enclosing matrix glasses contain 0.53–0.74 wt.% H₂O, 0.02–0.04 wt.% carbon, 0.08–0.12 wt.% sulfur, 0.012–0.028 wt.% chlorine and 0.012–0.077 wt.% fluorine.